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研究生: 白景文
Ching-Wen Pai
論文名稱: 多孔性基材上之薄膜體聲波元件研製
Fabrication of a Thin Film Bulk Acoustic Wave Resonator on a Porous Substrate
指導教授: 周賢鎧
Shyan-kay Jou
口試委員: 鄭偉鈞
Wei-Chun Cheng
胡毅
Yi Hu
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2005
畢業學年度: 93
語文別: 中文
論文頁數: 84
中文關鍵詞: 薄膜體聲波元件C-軸擇優取向氧化鋅薄膜多孔性基材
外文關鍵詞: FBAR, porous substrate, (002) ZnO thin film
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  本論文研製以具有C軸(002)擇優取向的氧化鋅為壓電材料及以多孔性二氧化矽做為基材取代現今氣隙型的薄膜體聲波振盪器,其結構分別為上電極/氧化鋅壓電薄膜/下電極/多孔性基材。多孔性基材以球磨、混粉、壓碇和燒結等程序製作而成。再搭配微影製程和射頻磁控式濺鍍法在多孔性基材上製作上、下金電極及氧化鋅壓電薄膜。材料分析使用X光繞射儀來鑑定薄膜結晶方向,並輔以掃描式電子顯微鏡來觀察薄膜表面和截面形貌。
  由實驗的結果得知,多孔性二氧化矽粉末經球磨、混粉、壓碇和燒結等程序製作而成之多孔性二氧化矽基材具有22%的孔隙率。而以2”的ZnO靶材、射頻功率50W、鍍膜壓力4.0×10-2-6.0×10-2 torr、氬氣流量22 sccm、靶材與基材間距離8 cm、基板不加溫的情況下,能成功的在Au/Si基材及Au/多孔性二氧化矽基材上成長(0002)擇優取向的氧化鋅薄膜。並且在多孔性二氧化矽基材上結合微影製程及射頻磁控式濺鍍法濺鍍上、下電極、氧化鋅薄膜,製作出薄膜體聲波元件。


  This study uses perfect C-axis preferred orientated zinc oxide as a piezoelectricity material and porous silica substrate as air gap for thin film bulk acoustic wave resonator. Structure of the resonator is composed of upper electrode / zinc oxide piezoelectric thin film / lower electrode / porous substrate. The porous substrate is fabricated by ball milling and powder mixing of silica followed by pressing into bulk and sintering. The upper and lower golden electrodes and zinc oxide piezoelectric thin film are deposited by RF magnetron sputtering. Patterns of electrodes and piezoelectric layer are formed by lithographic and lift-off processes. Structure and orientation of the thin film are characterized by X-ray diffraction and the surface and cross-section are observed by SEM.
  We find the porous silica powder have 22% porosity after the procedure of above process. We can grow perfect C-axis preferred orientated zinc oxide on Au / Si substrate and Au / porous silica substrate by RF magnetron sputtering using 2” ZnO target, RF power 50 W, sputtering pressure 4.0X10-2 – 6.0X10-2 torr, Argon flow 22 sccm, the distance between the target and the substrate 8 cm without heating the substrate. At final, we combine lithography technique and RF sputtering system to grow upper, lower electrode and zinc oxide thin film to fabricate the thin film bulk acoustic wave device.

中文摘要……Ⅰ 英文摘要…Ⅱ 誌謝……Ⅲ 目錄……Ⅳ 圖目錄…Ⅶ 表目錄…Ⅹ 第一章 前言 1 第二章 文獻回顅…3 2-1 壓電效應理論 …3 2-1-1 正壓電效應理論 …3 2-1-2 逆壓電效應理論 …4 2-2 各種聲波元件介紹 …5 2-3 薄膜體聲波元件之工作原理 …10 2-3-1 薄膜體聲波元件氣隙之功用 …12 2-3-2 薄膜體聲波元件氣隙之替代 …12 2-4 氧化鋅結構與特性 …15 2-5 電漿理論 …17 2-5-1 電漿原理 ……17 2-5-2 直流電漿 …18 2-5-3 射頻濺鍍 …20 2-5-4 磁控式濺鍍原理 …21 2-6 薄膜成長機制 …23 2-7 成長晶向薄膜之機制 …25 第三章 實驗方法與步驟……26 3-1 實驗材料與藥品規格 ……26 3-2 實驗裝置 ……27 3-3 實驗步驟 ……28 3-4 多孔性基材研製 ……29 3-5 微影製程 …32 3-5-1 掀離法製程 ……34 3-6 薄膜濺鍍製程 …35 3-6-1 矽基板清潔 …36 3-6-2 以磁控濺鍍機成長氧化鋅壓電薄膜簡介 …37 3-7 FBAR製程介紹 ……39 3-8 薄膜分析 ……41 3-8-1 場發射掃描式電子顯微鏡分析……41 3-8-2 X光繞射簡介…41 第四章 實驗結果與討論……44 4-1 多孔性基材分析……44 4-1-1 多孔性二氧化矽粉末粒徑分析 …44 4-1-2 多孔性基材FESEM結果分析…45 4-2 Au電極 47 4-2-1 Au電極之XRD繞射分析……48 4-2-2 Au電極鍍膜速率 …48 4-3 ZnO成長在Au/Si基材上之分析…50 4-3-1 ZnO成長在Au/Si基材上之XRD繞射分析 …50 4-3-2 ZnO成長在Au/Si基材上表面形態之SEM分析 …52 4-3-3 ZnO成長在Au/Si基材上截面形態之SEM分析 55 4-3-4 不同射頻功率之氧化鋅薄膜鍍膜速率 …58 4-3-5 ZnO成長在Au/Si基材上之結果討論60 4-4 ZnO成長在Au/多孔性二氧化矽基材上之分析…61 4-4-1 ZnO成長在Au/多孔性二氧化矽基材上之XRD繞射分析 …62 4-4-2 以50W功率濺鍍氧化鋅在Au/多孔性基材上之表面形態SEM分析…63 4-4-3 以50W功率濺鍍氧化鋅在Au/多孔性基材上之截面形態 SEM分析…64 4-4-4 薄膜體聲波元件 …66 第五章 結論…67 參考文獻……68

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