研究生: |
Bernadeta Niken Kartika Dewi Bernadeta - Niken Kartika Dewi |
---|---|
論文名稱: |
以二甲基聯胺/三甲基銦/三乙基鎵有機金屬
化學氣相沉積系統低溫成長氮化銦鎵
一維奈米線之研究 Low Temperature Growth of InGaN Nanowires by TEGa/TMIn/DMHy MOCVD System |
指導教授: |
洪儒生
Lu-Sheng Hong |
口試委員: |
林麗瓊
Li-Chyong Chen 戴龑 Yian Tai |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2010 |
畢業學年度: | 98 |
語文別: | 英文 |
論文頁數: | 75 |
中文關鍵詞: | 氮化銦鎵 、奈米線 、有機金屬化學氣相沉積 |
外文關鍵詞: | InGaN, Nanowires, MOCVD |
相關次數: | 點閱:309 下載:1 |
分享至: |
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關鍵字;氮化銦鎵、奈米線、有機金屬化學氣相沉積
本研究選用在低溫即具有分解能力的聯胺系列化合物-二甲基聯胺(DMHy)來取代反應性低的氨氣(NH3),同時以分解溫度較低之鎵源-三乙基鎵(TEGa)來與三甲基銦(TMIn)反應成長一維之氮化銦鎵奈米線,期望以TEGa-DMHy兩種較低溫度即可分解的先驅物組合,來大幅降低氮化銦鎵奈米線成長的溫度。由實驗結果發現,TEGa-TMIn-DMHy 系統可在450~600℃範圍內成功成長出氮化銦鎵奈米線於矽基板上,奈米線之銦(indium)含量及結晶品質明顯受到成長溫度、成長壓力、氣體氛圍與TMIn氣體流量之影響。經由TEM影像觀察證實奈米線為核殼(core-shell)結構,其成長方法為氣液固(VLS)的成長機制。進一步由TEM-EDX分析結果顯示,內部的核心組成為氮化銦鎵,外部包覆層組成為氮化鎵。光激發螢光光譜(PL)測量觀察到在467nm處和400nm處的發光分別對應氮化銦鎵-氮化鎵的核殼結構,核心的銦含量約為20%。預期此TEGa-TMIn-DMHy 系統應有機會能將氮化銦鎵奈米線成長在導電玻璃基板上,以利太陽能電池相關研究工作進行。
InGaN nanowires were synthesized on Si (111) by metalorganic vapor deposition (MOCVD) at temperatures lower than 600oC. Trimethylgallium, trimethylindium and dimethylhydrazine were employed as precursor which offer low temperature growth due to low thermal decomposition characteristics. This newly proposed reaction system has a great promise for energy application on soft substrates (such as ITO, AZO). Moreover, the effect of growth temperature, growth pressure, hydrogen gas ambient, and trimethylindium flow rate in InGaN growth were investigated.
InGaN nanowires were obtained at 450oC under hydrogen ambient with a TMIn flow rate of 1.42 µmol/min. TEM results show that the synthesized nanowires have core-shell structure. Indium localizes in the core and gallium in the shell was confirmed by EDX. PL spectra show emission at 467 and 400 nm corresponding to InGaN-GaN nanowires core-shell structures. The results also suggested that an indium content as ca. 20%. Further effort on looking for detailed phenomena in the formation of InGaN nanowires core-shell structure was also proposed.
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