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研究生: 蔡東逸
Dong-yi Tsai
論文名稱: 退火條件對以離子束濺鍍法沈積氧化鋅薄膜之特性研究
Study of annealing effects on the properties of ZnO thin films deposited by ion beam sputtering deposition
指導教授: 趙良君
Liang-chiun Chao
口試委員: 黃鶯聲
Ying-sheng Huang
黃柏仁
Bohr-ran Huang
李奎毅
Kuei-yi Lee
學位類別: 碩士
Master
系所名稱: 電資學院 - 電子工程系
Department of Electronic and Computer Engineering
論文出版年: 2008
畢業學年度: 96
語文別: 中文
論文頁數: 83
中文關鍵詞: 氧化鋅離子束濺鍍法
外文關鍵詞: zinc oxide, ion beam sputter deposition
相關次數: 點閱:216下載:6
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使用毛細式離子源濺鍍氧化鋅靶,沉積氧化鋅薄膜於晶向(100)矽基板上,隨後於氧與氮氣氛下退火,討論不同退火條件對氧化鋅薄膜特性之影響。
XRD顯示未退火之氧化鋅薄膜無任何繞射峰值,ZnO(002)繞射峰值在800°C時退火後為最強。600°C以上退火時膜面存在拉應力,是由熱應力所造成。薄膜未退火時,PL光譜顯示無任何峰值,於700°C以上退火時,近能隙(Near-band-edge)發光在380 nm,在800°C氧氣氛下退火時,其PL光譜經由線性擬合其缺陷/UV面積比為最低。1000℃退火後缺陷造成的近紅外光極強。晶粒尺寸隨退火溫度提高而變大,粗糙度因而明顯變差,當1000°C退火後,其均方根表面粗糙度約10 nm。
以毛細式離子源濺鍍氧化鋅薄膜,在氧氣氛下800°C退火,薄膜有較佳的結晶品質,薄膜當中的鋅與氧的鍵結率最高,缺陷發光最少,成份比佳,其均方根表面粗造度(Root mean square surface roughness)在5 nm以下。


ZnO thin films were deposited on (100) silicon substrates by capillaritron ion beam sputtering deposition. ZnO thin films were annealed in oxygen, nitrogen and in atmospheric condition at various temperatures. Effects of annealing on the properties of ZnO thin films are presented.
Annealing at 600°C causes residual tensile stress, which is caused by thermal stress. XRD results show that the as-deposited film has no preferential crystallographic orientations, while annealing at 800°C gives the strongest (002) diffraction peak. The as-deposited ZnO film does not show any PL emission. After annealing at 700˚C and higher, near-band-edge emission near 380 nm becomes discernable.
Annealing at 800°C in oxygen gives the lowest defect related deep level emission. As annealing temperature reaches 900°C and higher, NIR emission increases as annealing temperature increases, indicating the decomposition of ZnO. Grain size also increases as annealing temperature increases. However, as annealing temperature is higher than 1000˚C, surface roughness increases significantly.
ZnO thin films were prepared by capillaritron ion beam sputtering deposition. Post-growth annealing at 800°C in oxygen gives the highest percentage of oxygen incorporated into fully oxidized stoichiometric ZnO matrixes, lowest defect related deep level emission, and better crystalline quality, while an root mean square surface roughness less than 5 nm is achieved.

第一章 緒論 1 1-1 前言與實驗動機 1 1-2 氧化鋅的特性與結構 4 1-3 氧化鋅薄膜的發光機制 6 第二章 基礎理論 10 2-1 離子束濺鍍法(Ion Beam Sputtering Deposition, IBSD) 10 2-2 原理與應用 11 2-3 離子源(Ion source) 14 A. Gridded ion source 16 B. Gridless closed drift ion source 19 C. Capillaritron ion source 21 第三章 實驗方法與儀器設備 24 3-1 實驗步驟與樣品分析流程 24 3-2 實驗方法與設備 25 3-3 薄膜分析儀器 26 A. 場發射掃描式電子顯微鏡(Field Emission Scanning Electron Microscopy, FESEM) 27 B. X光電子儀(X-ray Photoelectron Spectroscopy, XPS) 27 C. X光繞射(X-Ray Diffraction, XRD)分析 28 D. 光致螢光光譜儀 (Photoluminescency, PL) 30 E. 原子力顯微鏡(Atomic Force Microscopy, AFM) 31 第四章 實驗結果與討論 34 4-1 薄膜側面結構 34 4-2 光電子儀(X-ray Photoelectron Spectroscopy, XPS) 40 4-3 X光繞射(X-Ray Diffraction, XRD) 50 4-4 光致螢光光譜儀(Photoluminescence, PL) 57 4-5 原子力顯微鏡(Atomic Force Microscopy, AFM) 63 第五章 結論與未來展望 71 參考文獻 72

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