研究生: |
黃義仁 Yi-Jen Huang |
---|---|
論文名稱: |
分子束磊晶系統成長三五族氮化物奈米結構於光電化學產氫之研究 Photoelectrochemical properties of III-V Nitride Based Semiconductors grown by plasma-assisted molecular beam epitaxy system |
指導教授: |
黃柏仁
Bohr-Ran Huang |
口試委員: |
陳貴賢
Kuei-Hsien Chen 林麗瓊 Li-Chyong Chen 陳瑞山 Ruei-San Chen |
學位類別: |
碩士 Master |
系所名稱: |
電資學院 - 光電工程研究所 Graduate Institute of Electro-Optical Engineering |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 86 |
中文關鍵詞: | 電漿輔助式分子束磊晶 、氮化鎵 、氮化銦鎵 、太陽能產氫 |
外文關鍵詞: | PA-MBE, GaN, InGaN, Solar hydrogen applications |
相關次數: | 點閱:294 下載:3 |
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本研究中,利用電漿輔助式分子束磊晶系統在矽基板上成長氮化鎵奈米柱及氮化銦鎵薄膜結構,並將其運用在光電化學產氫的研究上。首先在氮化鎵奈米柱部份,成長不同長度的奈米柱(長度大約在120~720nm、直徑大約在30~50nm),並且將其運用到光電化學產氫的實驗上,從實驗中發現,隨著長度增加至720nm時,經由吸收光譜的量測中接近UV範圍(250~360nm) 的吸收值可達到98%,並且在入射光轉換電流效率的量測更可達到近60%的轉換效率。而在光電化學產氫的量測中,其兩極式零偏壓下的光電流可達到0.73mA/cm2,比起商業用之氮化鎵薄膜更增加了3~4倍之多。最後在氮化銦鎵薄膜部份,經由光電化學產氫的量測發現,隨著銦含量增加(20%~50%),由於吸收更多的可見光而達到更高的光電轉換效率,尤其當銦含量為34%時之氮化銦鎵薄膜,最高的飽和光電流可成功提升至1.5 mA/cm2。實驗結果我們可以知道,氮化鎵奈米柱和氮化銦鎵薄膜具有良好的光電化學產氫特性,在未來將會是氫能源的研究方向之一。
Hydrogen production from solar energy is a promising technology as a future renewable energy source. In this study, we performed high performance photoelectrochemical (PEC) hydrogen generation by using catalyst-free GaN nanorod arrays (GaN NRs). The directly grown, vertical aligned GaN NRs on Si(111) substrates was synthesized by plasma-assisted molecular beam epitaxy. The geometry of GaN NRs with rod diameter and lengths measuring 30~50 nm and 120~720 nm, respectively, were controlled by various growth times. The optical properties of GaN NRs (Eg of GaN = ~3.4 eV) with length = 720 nm exhibited high light absorption of up to ~98% covering all UV region from 250 to 360 nm without any need of anti-reflection coating. From the PEC results, longer GaN NRs exhibited a photocurrent density of 0.73 mA/cm2 at VCE = 0 V (VCE is the applied external bias versus the platinum counter electrode) in 1M HCl solution under irradiation by Xenon lamp and showed an incident photon conversion efficiency (IPCE %) of about 60% at VCE = 0 V in the ultraviolet light region. This result was higher than traditional GaN thin film. We also investigated the different In composition (from 20% to 50%) of InGaN films for solar hydrogen production. InGaN shows higher saturation current density of 1.5 mA/cm2 than traditional GaN thin film. This work showed that GaN NRs and InGaN TFs can be the good candidates as the photoanode for photoelectrochemical hydrogen generation application due to high light trapping efficiency and photocatalytic activity.
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