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研究生： 黃子庭
Tzu-Ting Huang
論文名稱： 以CALPHAD方法預測Cu-Ni-Zr三元系統金屬玻璃形成區域
Prediction of Metallic Glass Formation Region for the Cu-Ni-Zr Ternary System by Using CALPHAD Method
指導教授： 顏怡文
Yee-wen Yen
口試委員: 飯久保智
Iikubo Satoshi
陳志銘
Chih-ming Chen
朱瑾
Jinn Chu
林士剛
Shih-kang Lin
學位類別： 碩士
Master
系所名稱： 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年： 2016
畢業學年度： 104
語文別： 英文
論文頁數： 98
中文關鍵詞： 金屬玻璃 、Cu-Ni-Zr三元系統 、熱力學模型 、非晶區域
外文關鍵詞： bulk metallic glass, Cu-Ni-Zr ternary system, thermodynamic assessment, samorphous region
相關次數： 點閱：234  下載：3 
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  •  上一筆

    • 金屬玻璃擁有優異的機械性質使得近年來人們對於金屬玻璃的研究愈加多元。然而探討多元成分的金屬玻璃需要大量的人力物力的投入，因此在本研究盼以熱力學預測之方式獲得多元成分下金屬玻璃的形成區域。
    本研究以CALPHAD方法進行研究，收先建立出符合實驗相圖的熱力學模型，再以亞穩定相圖預測金屬玻璃形成區域。銅基及鋯基金屬玻璃具有非常大的過冷液態區以及低成本、製成簡易等等優點而被選作實驗目標，另一方面鎳基非晶和金則有特殊的磁導性。本研究同時進行Cu-Ni-Zr的等溫平衡相圖以及計算相圖，並建立起熱力學模型應用於預測金屬玻璃形成區域上。
    在未來此熱力學模型可以推廣到更多元的系統，並提供學術及業界良好的研究基礎。

    Metallic glasses have outstanding mechanical properties which attract people sight on the application. Nowadays, investigations about metallic glasses are almost focus on multicomponent systems that require amount of resource to explore the formation region of metallic glasses.
    Therefore, the main purpose in this study is to predict the formation region of metallic glasses by thermodynamic method, CALPHAD. First, the reasonable thermodynamic database will be constructed in comparison of experimental data. Metastable phase diagram is established to predict formation of metallic glasses region after all. Cu-based amorphous alloy is highly value of low-cost and large supercooled liquid region and same as Zr-based alloy allow them to produce in simple equipment. Ni-based amorphous alloys have good corrosion resistance, mechanical properties, thermal stability and magnetic properties. In this study, Cu-Ni-Zr ternary system is discussed thermodynamically for constructing isothermal phase diagram and predicted region of metallic glasses.
    Furthermore, with the thermodynamic database, the multicomponent system could be established by the previous work as foundation. The expense and time of metallic glasses researches would be saved and promote the development of metallic glasses application in industries.

    Abstract List of Figure List of Table Chapter 1 Introduction Chapter 2 Literature Review 2.1 Metallic Glasses 2.1.1 Properties of Metallic Glasses 2.1.2 Application 2.1.3 Cu-, Ni- and Zr-Based Amorphous Alloys 2.2 Equilibrium of Phase Diagrams 2.2.1 Binary System 2.2.2 Cu-Ni-Zr Ternary System Chapter 3 Experimental 3.1 Experimental Phase Diagram 3.1.1 Isothermal Phase Diagram 3.1.2 Forming Region of Cu-Ni-Zr Bulk Metallic Glasses 3.2 Calculation of Phase Diagram 3.2.1 CALPHAD Method 3.2.2 Thermodynamic modeling Chapter 4 Results and Discussion 4.1 Cu-Ni-Zr experimental ternary phase diagram 4.2 Cu-Ni-Zr Calculated Ternary Phase Diagram 4.3 Prediction of Bulk Metallic Glasses Chapter 5 Conclusion Appendix Reference

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