探討純鈦在不同微弧氧化時間對耐腐蝕性質之研究｜國立臺灣科技大學博碩士論文系統

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研究生：	楊尊越 Tsun-Yueh Yang
論文名稱：	探討純鈦在不同微弧氧化時間對耐腐蝕性質之研究 Effect of oxidation time on corrosion resistance of pure Ti in micro-arc oxidation treatment
指導教授：	黃崧任 Song-Jeng Huang
口試委員:	陳復國汪俊延王丞浩黃崧任
學位類別：	碩士 Master
系所名稱：	工程學院 - 機械工程系 Department of Mechanical Engineering
論文出版年：	2018
畢業學年度：	106
語文別：	中文
論文頁數：	112
中文關鍵詞：	鈦、微弧氧化、生物活性
外文關鍵詞：	titanium, micro-arc oxidation, biological activities
相關次數：	點閱：229 下載：3
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生物醫學級的鈦合金高其耐腐蝕性通常是可被接受的。但有一些報導指出當使用鈦合金作為植入物時由於鈦在體內的溶解和釋放金屬離子會積聚在組織周圍。金屬離子如 Al、Zr 和 V，從而引起不希望
的反應和過度的組織退化。另一方面，鈦的表面與活體骨組織之間的結合性非常差，因此造成癒合期需更長的時間。
微弧氧化技術為表面改質新興技術之一，其技術特色在於生成氧化膜於閥金屬 (valve metal) 如鎂、鋁、鈦之表面，並提升其抗腐蝕和耐磨耗特性。因此本研究係利用微弧氧化技術在純鈦表層上來製備含鈣和磷之孔洞氧化膜，並探討其氧化膜之物理化學特性和抗腐蝕性質。透過 SEM、XRD、EDS 和三極電化學試驗等方式以分析不同微弧氧化之表面形貌、鍍膜厚度、抗腐蝕性之差異。
由本實驗結果得知，隨著微弧氧化時間增長，氧化膜之厚度、孔洞大小與硬度也隨之成長。而時間較長的微弧氧化之氧化膜具有較優異的硬度，與透過 EDS 和 Mapping 成份分析可以得知鈣和磷離子伴隨著微弧氧化時間增長而增加並分佈均勻。氧化膜的表面形貌、緻密性皆為影響抗腐蝕能力的因素。

The high corrosion resistant property of biomedical grade titanium alloys is commonly accepted. However, there are some reports indicated that titanium tends to accumulate in surrounding tissues due to dissolution and release of metallic ions in vivo. The use of Ti-based implants always brings out these concerns. Metallic ions such as Al, Zr and V would cause the undesirable reactions and excessive tissue degradation. On the other hand, the bonding between titanium surface and living bone tissue is very weak results in longer healing period.
As one of the novel technologies in surface treatment field, micro–arc oxidation process is capable to produce oxide layers on surface of valve metal including magnesium, aluminum, titanium, etc., which improves the wear and corrosion resistant properties of metal. Porous oxide layers containing calcium and phosphorus were fabricated on titanium surface in this research. The object is to observe the physical, chemical and corrosion resistant properties of these porous oxide layers. The difference of surface morphology, layer thickness and corrosion resistance between various samples are examined by SEM, XRD, EDS and polarization curve.
The result shows that the thickness, pore size and hardness increased by extending the process time. The observation by EDS and Mapping indicate that the amount and distribution of calcium and phosphorus ions were improved. Surface morphology and density of oxide layers are also important factor to affect corrosion resistance.

第一章 緒論......................................................................... 1
1 前言 ........................................................................... 1
2 文獻回顧 .................................................................. 2
2.1 微弧氧化技術之簡介 ............................................................................ 2
2.2 影響氧化陶瓷膜生成之參數介紹 ............................................. 3
2.3 生物活性離子 ........................................................................... 18
3 文獻整理心得 ............................................................................ 21
4 研究動機與目的 ............................................................................ 23
第二章 研究理論基礎 ............................................................................ 24
1 純鈦及鈦合金的簡介[28] ............................................................................ 24
1.1 純鈦及鈦合金之基本性質 .................................................. 24
1.2 鈦的晶體結構與性質 ............................................................................. 32
2 電化學腐蝕 ............................................................................. 34
2.1 腐蝕的定義   ............................................................................. 34
2.2 影響金屬腐蝕的因素....................................................... 35
3 金屬表面處理技術 .............................................................................. 38
3.1 機械表面處理 .............................................................................. 38
3.2 化成處理  .............................................................................. 38
3.3 電子束合金化處理 .............................................................................. 39
3.4 雷射合金化處理 .............................................................................. 40
3.5 物理氣相沉積法  .............................................................................. 41
3.6 化學氣相沉積法  .............................................................................. 43
3.7 無電鍍表面處理  .............................................................................. 43
3.8 電鍍  .............................................................................. 44
3.9 陽極處理  .............................................................................. 44
3 微弧氧化技術之介紹 .............................................................................. 45
3.1 微弧氧化技術發展 .............................................................................. 46
3.2 微弧放電工作原理  .............................................................................. 47
3.3 影響膜層特性之控制因子 ................................................... 52
4 複合電鍍之機制 .............................................................................. 52
第三章 實驗方法與步驟 .............................................................................. 55
1 實驗流程 .............................................................................. 55
2 試片製備 .............................................................................. 56
3 微弧氧化步驟及參數 .............................................................................. 57
4 陶瓷氧化層宏觀分析 .............................................................................. 61
4.1 粗糙度分析 .............................................................................. 61
5 微觀結構觀察分析 .............................................................................. 62
5.1 SEM 顯微組織觀察 .............................................................................. 62
5.2 XRD 繞射分析 .............................................................................. 63
6 機械性質分析 .............................................................................. 64
6.1 維氏硬度 .............................................................................. 64
7 腐蝕分析 .............................................................................. 66
7.1 極化曲線分析 .............................................................................. 66
第四章 結果與討論 .............................................................................. 69
1 電壓與氧化時間曲線 .............................................................................. 69
2 表面粗糙度 .............................................................................. 72
3 微觀結構 .............................................................................. 74
4 成分分析 .............................................................................. 85
4.1 XRD .............................................................................. 85
5 機械性質 .............................................................................. 86
5.1 維氏硬度 .............................................................................. 86
6 腐蝕分析 .............................................................................. 86
6.1 極化曲線 .............................................................................. 86
第五章 結論
............................................................................. 90
參考文獻 .............................................................................. 92 
                                

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