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研究生: 黃志鴻
Jhih-Hong Huang
論文名稱: 混料式射出成形螺桿對聚乳酸添加有機蒙脫土複合材料機械性質影響之研究
Effect of Mixing Screw on Mechanical Properties of Injection Molded Polylactic Acid / Organic-Montmorillonite Composites
指導教授: 陳炤彰
Chao-Chang Chen
口試委員: 楊申語
Sen-Yeu Yang
黃招財
Chiau-Tsai Huang
劉顯光
Hsien-Kuang Liu
吳昌謀
Chang-Mou Wu
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2017
畢業學年度: 105
語文別: 中文
論文頁數: 195
中文關鍵詞: 混料式射出成形螺桿生物可降解材料聚乳酸高分子有機蒙脫土機械性質試驗
外文關鍵詞: Mixing screw of injection molding, Bio-degradable materials, Polylactic Acid, Organic Montmorillonite, Mechanical properties
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  • 本研究探討混料式射出成形螺桿對聚乳酸(Polylactic Acid, PLA)和聚乳酸添加有機蒙脫土(Organic Montmorillonite, OMMT)複合材料的機械性質影響,以直接射出製程對複合材料進行混料成形;利用氨基矽烷偶合劑(Amino-Silane coupling agent)進行有機蒙脫土二次改質,探討聚乳酸添加商用有機蒙脫土(PLA/M)及二次改質蒙脫土之複合材料(PLA/S/M)性質差異性。利用混料式螺桿進行不同蒙脫土比例之複合材料成形,探討雙螺桿押出造粒後由單節距螺桿射出成形試片及直接以混料式螺桿射出成形試片分子結構與機械強度差異性。研究方法首先利用以Flow2000與ANSYS-CFD模組對設計之混料特徵進行流場與混料能力驗證並製造。以實驗設計與迴歸分析方法找出射出成形複材拉伸強度與衝擊強度影響最大之製程參數,並探討兩種製程方法成型試片之機械性質差異性。由實驗結果PLA添加3wt%之商用有機蒙脫土(Cloisite 25A)有較佳機械性質,影響複合材料機械性質為最大因子為料溫;高料溫成形時,混料式螺桿試片抗拉強度與耐衝擊強度相較單節距螺桿試片下降約0.9~12.7%;低料溫進行PLA添加二次改質蒙脫土之成形時,相較於單節距螺桿試片,混料式螺桿試片機械性質上升約7.0~70.6%。本研究之混料式射出形螺桿對PLA添加有機蒙脫土複材研究成果可應用於食品用具與醫用輔具一次性複合材料混料與射出成形。


    This study is devoted to design a new type of mixing screw in injection molding to investigate mechanical properties influence of polymer composites by injection molding process. Polylactic Acid (PLA) and PLA composites with Organic Montmorillonite (PLA/M) have been selected to be investigated by regular and mixing screw performed by injection molding. Relation between tensile strength, impact strength, hardness of PLA and PLA/M composites have been tested and discussed. The amino silane coupling agent is selected as interface improving agent of PLA and Organic Montmorillonite (PLA/S/M). Design of injection molding experiment is adopted to find the most significant factor for tensile strength and impact strength of composites sample. Design of such mixing screw has been Flow2000 / ANSYS-CFD simulation for mixing characteristics. Results of shear rate and flow velocity simulation with three feature designs of mixing characteristics. For the best to be fabricated. From experimental results, the better mechanical properties of PLA composites have been obtained by the PLA composites of PLA/M3.0 group. The regression analysis has been used to find the significant factor as melt temperature of injection molding parameter. The processing with low level melt temperature can achieve better mechanical results. With such two types of screw tests, the mechanical properties of PLA composite including tensile strength and impact strength by mixing screw are 0.9~12.7% lower than that of regular screw. Furthermore, process in low level melt temperature, the mechanical properties of tensile strength and impact strength of PLA/S/M composites by mixing screw are higher 7.0~70.6% than those of the single pitch screw. Result of this study can be futher applied on food tableware or medical aids in the one-time molding process in future.

    摘要 Abstract 致謝 目錄 圖表目錄 符號表 第一章 緒論 1.1 研究背景 1.2 研究目的與方法 1.3 論文架構 第二章 文獻回顧 2.1 射出成形混料式單螺桿設計相關文獻回顧 2.2 單螺桿模擬分析相關文獻回顧 2.3 聚乳酸與黏土複合材料相關文獻回顧 2.4 矽烷偶合劑表面改質蒙脫土文獻回顧 2.5 混料式單螺桿相關專利回顧:美國 2.6 聚乳酸射出成形相關專利回顧:中華民國 2.7 文獻回顧總結 第三章 混料式螺桿設計與複合材料製備. 3.1 射出成形介紹 3.2 混料式射出成形螺桿模擬與設計 3.3 實驗材料 3.4 複合材料雙螺桿混煉造粒製備 3.5 複合材料性質分析 第四章 模流分析 4.1 拉伸衝擊射出成形模具設計 4.2 拉伸衝擊模具模流分析 第五章 實驗設備與規劃 5.1 實驗規劃 5.2 實驗儀器與量測設備 5.3 實驗設計與取樣模式 第六章 實驗結果與討論 6.1 A. Ex-IM與Ms-IM純材料試片機械性質 6.2 B. Ex-IM與Ms-IM複材試片機械性質 6.3 C. Ex-IM與Ms-IM試片微結構 6.4 D. 綜合結果討論 第七章 結論與建議 7.1 結論 7.2 建議 參考文獻 附錄A Fanuc-Robotshot α15-ia單節距螺桿設計圖 附錄B 混料式螺桿設計圖 附錄C 混料式螺桿可視化模型設計圖 附錄D 聚乳酸物性表資料表 附錄E 有機蒙脫土物性資料表 附錄F 矽烷偶合劑物性資料表 附錄G X-Ray繞射分析原理 附錄H 熱性質分析 附錄I 毛細管流變儀 附錄J 拉伸與衝擊試片模具圖 附錄K 實驗設備與儀器 附錄L 射出成形機規格 附錄M 變異數分析 附錄N 拉伸試驗結果圖 附錄O 純PLA/PLA複材添加物分佈觀測

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