本研究一系列開發了具有可染、遠紅外線放射、遠紅外線溫升及抗靜電等多機能奈米石墨烯改質聚丙烯和奈米石墨烯改質聚酯保暖織物，本研究之開發分為三個部分：
第一部分，本研究主要開發具有分散染料可染聚丙烯(PP)酯粒。最佳可染色聚丙烯酯粒的製程使用低熔點改質共聚己二酸對苯二甲酸丁二醇酯 (Co-PBAT)作為混合共聚物。目的是為了克服聚酯材料熔點與聚丙烯熔點之間相差過大的問題。低熔點改質共聚己二酸對苯二甲酸丁二醇酯的開發是關鍵點。使用低熔點改質Co-PBAT通過雙螺桿混鍊加工將聚丙烯(PP)與聚丙烯接枝馬來酸酐相容劑製成複合材料。分散染料的可染性是透過 Co-PBAT鏈段的分子特性達到的。製備的材料探討低熔點改質共聚己二酸對苯二甲酸丁二醇酯酯粒的熱性能，並經過傅立葉紅外光譜驗證其官能基團。本研究採用田口法(Taguchi method)和主成份分析法（Principal component analysis, PCA)對聚合物熔体熔融指数（Melt flow index,MFI）及染色力度等两項品質特性的製程參數進行最佳化設計。根據實驗結果，酯粒的多品質最佳化包括改質Co-PBAT熔點170°C、改質Co-PBAT含量9 wt%、相容劑含量3 wt%、模頭温度205°C。常规聚丙烯聚合物的熔融指數為28.1 g/10 min，染色力度為100 K/S。對於最佳化，可染改質聚丙烯酯粒的熔融指數為37.88 g/10 min，染色力强度為121.31 K/S。顯示所開發的聚合物具有良好流動之加工性和染色力度。
第二部分，本研究開發了一種具有遠紅外線特性的奈米石墨烯改質可染色聚丙烯紗線，使其適用於冬季服裝面料。以第一部分開發的可染色聚丙烯為基材，加入石墨烯奈米粉體，熔融混合及熔融紡絲製作75d/24f全延伸絲（FDY）。研究了紗線的物理性能，即紗線丹尼、拉伸強度、斷裂伸長率、遠紅外線放射率和遠紅外線溫升，以及確定熔融紡絲製程參數如奈米石墨烯粉體含量、模頭溫度、熔體溫度、齒輪泵速度、熱羅拉速度和捲取速度對紗線的品質的影響。採用田口方法與灰關聯分析 (Grey relational analysis, GRA)相結合，進行實驗設計，透過實驗獲得一組最佳化熔紡製程參數，最佳化提高紗線的多品質特性。這種經過最佳化的奈米石墨烯改質可染聚丙烯紗，抗拉強度3.5g/d，斷裂伸長率41.0%，紗線為75.3丹尼，遠紅外發射率為82%，遠紅外溫升為21.0℃，水洗牢度為3-4級和表面電阻為 3×108 。
第三部分，本研究開發具有遠紅外線及抗靜電性能等多機能聚酯纖維，以紡絲級聚酯為基材、添加奈米石墨烯粉體及分散劑(聚丙烯蠟接枝馬來酸酐)進行雙軸混煉，使聚酯具有遠紅外線機能，纖維能吸收太陽光中之遠紅外線，達到溫度上升之效果。改質後之聚酯材料透過熔融紡絲製作75d/72f 之加工絲，本研究採用田口法將奈米石墨烯粉體添加量比例、模頭溫度、熔體溫度、齒輪泵轉速、羅拉速度和捲取速度等製程參數進行實驗規劃，結合灰關聯度分析法探討最佳化聚酯纖維之多品質紗線的丹尼數、拉伸強度、斷裂伸長率、遠紅外線放射率及遠紅外線溫升等性質。結果顯示，熱重量分析(TGA) 最佳化改質聚酯紗線的熱裂解溫度高於未改質聚酯，證明最佳化改質紗線具有更高的耐熱性。示差掃描分析(DSC)最佳化改質酯紗線的結晶溫度高於未改質聚酯﹐證明石墨烯奈米粉體的加入可以提高聚酯的結晶溫度。本研究之最佳化聚酯纖維的物性紗線為76.5丹尼，斷裂伸長率為26.3%，拉伸強度為3.3 g/d，遠紅外線放射率為83%，遠紅外線溫升為22.0°C，表面電阻為3x108 。最佳化改質紗線性能優於未改質聚酯紗線。

This study is a series of development of multi-functional nano-graphene polypropylene and nano-graphene polyester thermal fabrics with dyeability, far-infrared radiation, far-infrared temperature rise and antistatic. This study is divided into three parts:
In Part I, this study aimed to develop dyeable modified polypropylene (PP) granules with disperse dye. The optimal dyeable PP granule process used a low melting modified co-polybutylene adipate terephthalate (Co-PBAT) as a mixed copolymer. The purpose was to overcome the excessive difference between the polyester material melting point and PP melting point. The development of a low melting modified co-polybutylene adipate terephthalate (Co-PBAT) was the key point. Using the low melting modified Co-PBAT , PP and a PP grafting maleic anhydride compatibilizer were made into a composite by dual-screw mixing process. The disperse dye dyeability was reached by the molecular behavior of Co-PBAT chain segment. The prepared material applied to explore the thermal properties of modified polyester pellets and the functional group was verified by Fourier infrared spectroscopy. In this study, the Taguchi method and Principal component analysis (PCA) were used to optimize the process parameter design of two quality characteristics, namely, the color strength and the polymer melt flow index (MFI). According to experiment results, the multi-quality optimization of the polyester pellets consisted of a modified Co-PBAT melting point of 170 oC, the modified Co-PBAT content of 9 wt%, the compatibilizer content of 3 wt%, and the mixing temperature of 205 oC. The MFI of the regular PP polymer was 28.1 g/10 min, the color strength was 100 K/S. For the optimization, the MFI of the PP/Co-PBAT dyeable granules was 37.88 g/10 min and the color strength was 121.31 K/S. It could be observed that the developed polymer had good flowability and color strength.
Part II, this study developed a nanographene modified dyeable polyproplylene (PP) yarn with far-infrared properties making it suitable for winter clothing fabrics. The dyeable PP granules developed in Part I are used as base material , and with the addition of graphene nanopowder, melt-mixed and melt-spun to produce 75d/24f fully drawn yarn (FDY). The physical properties of the yarn, namely, denier, tensile strength, elongation at break, far-infrared emissivity, and far-infrared temperature rise, are investigated, and the impact of the melt spinning process parameters, namely, graphene nanopowder content, mold temperature, melt temperature, gear pump speed, hot roller speed and take-up speed on the quality of the yarn, is determined. The Taguchi method, combined with grey relational analysis (GRA), is used to design experiments through which an optimal set of melt-spinning process parameters maximizing the multi-characteristic quality of the yarn is obtained. This optimized nanographene modified dyeable PP yarn has a tensile strength of 3.5 g/d, elongation at break of 41.0%, yarn count of 75.3 denier, far-infrared emissivity of 82%, far-infrared temperature rise of 21.0°C, washing fastness grade of 3-4 and surface resistance of 3 x 108 .
Part III, thisstudy develops multi-functional polyester fibers with far-infrared rays and antistatic properties, using spinning-grade polyester as the base material, adding nano-graphene powder and dispersant (polypropylene wax grafted with maleic anhydride) for biaxial mixing, so that the polyester has a far-infrared function, and the fiber can absorb the far-infrared rays in sunlight to achieve the effect of temperature rise. The modified polyester material is melt-spun to produce 75d/72f processed yarn. In this study, the Taguchi method was used to design the experimental planning of the process parameters such as the proportion of nano-graphene powder addition, mold temperature, melt temperature, gear pump speed, roller speed, and take up speed. Optimize the denier number, tensile strength, elongation at break, far-infrared emissivity and far-infrared temperature rise of multi-quality polyester yarns. Test results showed that the Pyrolysis temperature of the optimized modified polyester yarn was higher than that of unmodified polyester by thermogravimetric analysis (TGA), proving that the optimized modified yarn had higher heat resistance. The differential scanning analysis (DSC) optimized the crystallization temperature of the modified ester yarn is higher than that of the unmodified polyester, which proves that the addition of nano-graphene powder can increase the crystallization temperature of polyester. This optimized nanographene modified polyester yarn has a tensile strength of 3.3 g/d, elongation at break of 26.3%, yarn count of 76.5 denier, far-infrared emissivity of 83%, far-infrared temperature rise of 22.0°C, and surface resistance of 3 x 108 . Optimized modified yarn performance is better than unmodified polyester yarn.

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