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研究生： 李維江
Yossafat - Wiedji Anggoro Sentosa
論文名稱： Thermodynamic Assessment of the Au-Cu-Sn Ternary System
Thermodynamic Assessment of the Au-Cu-Sn Ternary System
指導教授： 李嘉平
Chiapyng Lee
顏怡文
Yee-wen Yen
口試委員: 高振宏
Kao, C Robert
吳子嘉
Wu, Albert T.
饒建中
Chien-chung Jao
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2007
畢業學年度： 95
語文別： 英文
論文頁數： 61
中文關鍵詞： CALPHAD 、Au-Cu-Sn 、ternary intermetallic compound
外文關鍵詞： CALPHAD, Au-Cu-Sn, ternary intermetallic compound
相關次數： 點閱：206  下載：4 
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  •  上一筆

    • The Au-Cu-Sn system was thermodynamically assessed with CALPHAD method in order to obtain an optimized and consistent thermodynamic description. It was found that the resulting thermodynamic optimization is in good agreement with the limited experimental data available, except for the Au rich part of the ternary isothermal section at 360 oC.

    The Gibbs energy of formation for the three ternary compounds A, B, and C were obtained, and the ternary interaction parameters for fcc and hcp phases were assessed. All of the calculations were performed using PANDAT software.

    The Au-Cu-Sn system was thermodynamically assessed with CALPHAD method in order to obtain an optimized and consistent thermodynamic description. It was found that the resulting thermodynamic optimization is in good agreement with the limited experimental data available, except for the Au rich part of the ternary isothermal section at 360 oC.

    The Gibbs energy of formation for the three ternary compounds A, B, and C were obtained, and the ternary interaction parameters for fcc and hcp phases were assessed. All of the calculations were performed using PANDAT software.

    1. Introduction 1.1 The Importance of This Study 1.2 The Objective of This Study 2. Literature Review 2.1 CALPHAD Method 2.1.1. Collecting Phase Equilibria Experimental Data 2.1.2. Gibbs Energy Model 2.1.3 Model Parameters Optimization 2.1.4 Calculation of Phase Equilibria 2.2 Phase Diagram Experimental Data 2.2.1 Au-Sn Binary System 2.2.2 Cu-Sn Binary System 2.2.3 Au-Cu Binary Systems 2.2.4 Au-Cu-Sn Ternary System 3. Thermodynamic Parameters 3.1 Unary Systems Parameters 3.2 Binary Systems Parameters 3.2.1 Au-Sn Binary System 3.2.2 Cu-Sn Binary System 3.2.3 Au-Cu Binary System 3.3 Ternary Systems Parameters 3.3.1 δ-AuSn and η-Cu6Sn5 Phase 3.3.2 A, B, and C Ternary Compound Phases 3.3.3 Ternary Interaction Parameters 4. Calculated Binary Constituents 4.1 Au-Sn Binary System 4.2 Cu-Sn Binary System 4.3 Au-Cu Binary System 5. Calculated Ternary Phase Diagram System 5.1 Isothermal Section of 200 oC 5.2 Isothermal Section of 360 oC 6. Conclusions References Appendix I - TDB File for Au-Cu-Sn Ternary System Appendix II - Comparison between the Original Parameters and the Amended Parameters Curriculum vitae

    [1] Official Journal of the European Union, p. L 37/19-L 37/23, 13.2.(2003)
    [2] U.R. Kattner, C.A.Handwerker, Z. Metallkd. 92 (2001) 740.
    [3] Y.W. Yen, C.C. Jao, H.M. Hsiao, C.Y. Lin, C.P. Lee, J. Electron. Mater. 36 (2007) 147.
    [4] S.L. Chen, F. Zhang, S. Daniel, F.Y. Xie; et al., JOM 55 No 12 (2003) 48.
    [5] U.R. Kattner, JOM., 54 No 12, (2002) 45.
    [6] S.W. Chen, C.H. Wang, S.K. Lin, C.N. Chiu J. Mater. Sci.: Mater. Electron. 18 (2007) 19.
    [7] O. Redlich, A.T. Kister, Ind. Eng. Chem. 40 (1948) 345.
    [8] S.L. Chen, et al., CALPHAD 17 (1993) 47.
    [9] L. Kaufman, H. Bernstein, Computer Calculation of Phase Diagrams.
    Academic Press, New York, 1970.
    [10] H.L. Lukas, J. Weiss, E.T. Henig, CALPHAD 6 (1982) 229.
    [11] B. Sundman, B. Jansson, and J.O. Anderson, CALPHAD 9 (1985) 153.
    [12] G. Eriksson, K. Hack, Metall. Trans. B 21B (1990) 1013.
    [13] Y.A. Chang, et al., Progress in Material Science 49 (2004) 313.
    [14] S.L. Chen, et al., CALPHAD 26 (2002) 175.
    [15] H. Okamoto, T.B. Massalski, Bull. Alloy Phase Diagrams 5 (1984) 492
    [16] J. Ciulik, M.R. Notis, J. Alloy Compounds 191 (1993) 71.
    [17] P.Y. Chevalier, Thermochimica Acta 130 (1988) 1.
    [18] H.S. Liu, C.L. Liu, K. Ishida, Z.P. Jin, J. Electron. Mater. 32 (2003)1290.
    [19] A.T. Dinsdale, CALPHAD 15 (1991) 317.
    [20] N. Saunders, A.P. Miodownik, Bull. Alloy Phase Diagrams 11 (1990) 278.
    [21] W. Martienssen (Eds.), Thermodynamic Properties of Inorganic Materials – Compiled by SGTE, Landolt Börnstein Vol. 19 Subvolume B Part 3. Springer- Verlag, Berlin, 2005, pp. 1-4.
    [22] J.H. Shim, C.S. Oh, B.J. Lee, and D.N. Lee, Z. Metallkd. 87 (1996) 205.
    [23] G. Wojcieh, S.W. Chen, S.K. Lin, J. Mater. Res. Submitted for publication (2007)
    [24] H. Okamoto, D.J. Shakrabarti, D.E. Laughlin, T.B. Massalski, Bull. Alloy Phase Diagrams 8 (1987) 454.
    [25] W. Martienssen (Eds.), Thermodynamic Properties of Inorganic Materials - Compiled by SGTE, Landolt Börnstein Vol. 19 Subvolume B Part 1. Springer- Verlag, Berlin, 2002, pp. 1-2.
    [26] H. Sato, R.S. Toth, Phys. Rev. 124 (1961) 1833.
    [27] B. Sundman, S.G. Fries, W.A. Oates, CALPHAD 22 (1998) 335.
    [28] N. Bochvar, Y. Liberov, in:Martienssen, W. ed, Ternary Alloy Systems - Phase Diagrams, Crystallographic, and Thermodynamic Data, Landolt Börnstein Vol. 11 Subvolume C Part 3. Springer- Verlag, Berlin, 2007, pp. 138-148.
    [29] O.B. Karlsen, A. Kjekshus, E. Rost, Acta Chem. Scand. 46 (1992) 147.
    [30] E. Zakel, Untersuchung einer Cu-Sn-Au, Cu-Au und Cu-Sn metallisiernngssystemen fiir die TAB Technologie, Ph.D. Thesis, Berlin University of Technology, 1994.
    [31] J.F. Roeder, Phase Equilibria and Compound Formation in the Au-Cu-Sn System at Low Temperature, Ph.D. Thesis, Lehigh University, 1988.
    [32] C.N.C. Luciano, K. Udoh, M. Nakagawa, S. Matsuya, M. Ohta, J. Alloy Compounds 337 (2002) 289.
    [33] A. Janz, R.S. Fetzer, CALPHAD 29 (2005) 37.
    [34] K. Schubert, H. Breimer, R. Gohle, Z. Metallkd. 50 (1959) 146.

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