本研究主要分別以3:7的鋅-銻系統與2:3的銻-硫系統探討。第一部份，使用陽極氧化鋁模板的液壓鑄造處理製造異質結構的銻與銻化鋅(ZnSb)高序化奈米線陣列，而將塊材組份配在共晶組份，藉由壓鑄可將材料壓入具有高度有序的奈米陣列的模板裡，此外，控制蝕刻條件，可得的因相分離所產生的異質結構對於蝕刻液的蝕刻速率不同的奈米線，然而使用氧化鋁模板可以控制奈米線的直徑以及可以製造高度有序的奈米陣列。結果得知，奈米線的直徑約 70-100 nm，以及因為在共晶成分下所進行壓鑄也獲得異質結構的奈米線。利用掃描式電子顯微鏡觀察Sb-ZnSb異質結構的奈米線的形態。在藉由X-射線繞射分析和拉曼測量分析微結構。從XRD以及拉曼的結果也得到Sb-ZnSb的異質結構的相，其中異質結構的介面可以藉由高倍率穿透式電子顯微鏡觀察，也得到 Sb-ZnSb 的異質結構。
第二部份，藉由上述的方法製造出硫化銻(Sb2S3)，壓鑄方式可獲得高密度且平滑的奈米線，直徑約為70-100 nm，利用掃描式電子顯微鏡觀察Sb2S3的奈米線的形態。在藉由X-射線繞射分析和拉曼測量分析微結構。可以利用X-射線繞射分析和拉曼測量分析。結果得知，多孔的氧化鋁模板對於控制奈米線的直徑扮演重要的角色，藉由液壓鑄造可以成功製造出Sb2S3奈米線。

Sb-system is the mainly subject to discuss, the heterostructure of antimony-zinc antimonides (ZnSb), antimony (III) sulfide (Sb2S3) an dare divided into two parts in this thesis.
The highly ordered array of the heterostructure of antimony-zinc antimonides (ZnSb) nanowires are fabricated by a hydraulic pressure injection processing with anodic aluminum oxide and microstructure is analyzed by templates. We use control the composition of bulks in two phase region, through the die casting to press the material into the highly ordered array of template. Therefore, control etching condition, can get the heterostructured NWs due to the etching rate were different caused the phase separation. However, the highly ordered array of anodic aluminum oxide template can control the diameter of NWs and fabricate the highly ordered array of NWs. The results demonstrate that the diameter antimony-zinc antimonides (ZnSb) heterostructure NWs were 70-100 nm. Therefore, through die-casting under eutectic composition, heterostructure nanowires were obtained. The morphology of antimony-zinc antimonides (ZnSb) heterostructure NWs was observed by SEM. The microstructure of nanowires were characterized by XRD analysis and Raman measurement. From the results of XRD and Raman analysis obtained heterostructure phase of Sb-ZnSb. In addition, the interface of the heterostructure can be observed by TEM. The results demonstrate that heterostructure NWs can be obtained.
Sb2S3 nanowires were fabricated by a vacuum hydraulic pressure injection process using anodic aluminum oxide (AAO) as templates. It will help us to easily get a large quantity and uniform and flat Sb2S3 NWs The diameter of Sb2S3 NWs were about 70-100 nm. The morphology of NWs was observed by SEM, The microstructure of nanowires were characterized by XRD analysis and Raman measurement. The results shown porous anodic aluminum oxide played a significant role for the fabrication of Sb2S3, which controlled the diameter of NWs. Sb2S3 nanowires were successfully fabricated by a hydraulic pressure injection processing.

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