超分子聚合物能有效地剝離二維奈米材料，進而形成具有特異物理性質的
低層數奈米片，因此極具潛力拓展至不同的應用領域。本次研究中，我們成功
以簡便且有效的方法合成出一具有自身互補多重氫鍵作用力之腺嘌呤官能化親
水性高分子（AJ），並將其與二硒化錸（ReSe2）混摻後進行液相脫層，形成層
數可控之 ReSe2-AJ 複合材料。因 AJ 與 ReSe2 之間存在特定的非共價作用力，
使其能在 ReSe2 表面形成腺嘌呤誘導排列之自組裝超分子微結構，能促進 ReSe2
之脫層效果並防止其回疊，其所得之複合材料具有許多特異的物理性質，包含
高度穩定的氫鍵作用力、熱可逆的黏彈行為，以及可控的形貌與層數。此外，
當應用於析氫反應時，相較於原始 ReSe2，這些複合材料能有效增加其催化效
果及導電特性，其主因可歸於脫層的 ReSe2 奈米片能有效增加其比表面積及反
應活性位點，因此此新興開發的複合材料系統極具潛力應用於催化領域。

The supramolecular polymers can efficiently exfoliate the two-dimensional nano
materials into few-layered nanosheets with specific physical properties, which is
potential to be used in various applications. In this study, we successfully synthesized
an adenine-functionalized hydrophilic polymer (AJ) with self-complemeatary
multiple hydrogen bonding interaction by a simple and effective approach. A liquid
phase exfoliation process was applied after the mixing between AJ and rhenium
diselenide (ReSe2), in order to form a layer-tunable ReSe2-AJ composite. Due to the
present of the non-covalent interaction between AJ and ReSe2 nanosheets, AJ could be
arranged into a self-assembled supramolucular nanostructrure on the suface of ReSe2,
being able to improve the efficiency of ReSe2 exfoliation and prevent them from
restacking. The resulting ReSe2-AJ composites possessed a numbers of unique
physical properties, including highly stable hydrogen bond interaction,
thermoreversable viscoelastic behavior, tunable morphological characteristics and
layer number. Additionally, in the application of the hydrogen evolution reaction, the
composites could significantly enhance the catalytic performance and conductivity
compared to the pristine ReSe2, being attributed from the exfoliated ReSe2 nanosheets
whom’s specific area and the active edge sites could be increased substaintially. Thus,
the newly developed composite system has the great potential for the applications in
the field of catalysis.

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