本實驗是由含anthraquinone側基之新二胺單體，所製備的一系列聚醯亞胺。所合成聚醯胺酸的固有黏度範圍在0.56~1.05 dL/g，可溶型的聚醯亞胺黏度則為0.82 dL/g，這些聚醯亞胺可溶於m-cresol、
o-chlorophenol等溶劑中，其抗張強度於46~152 MPa之間，斷裂伸長率為4.5~11.3％之間，經由DMA測試所合成之聚醯亞胺的玻璃轉移溫度介於303~401℃之間，經由TGA測試所合成之聚醯亞胺的熱安定性，其10%熱重量損失，於空氣下介於543~574℃之間，於氮氣下介於551~574℃之間，於氮氣下600℃燃燒殘餘率介於77~83％之間。
經由UV/Visible測試所合成之聚醯亞胺之光學性質在溶液狀態下之最大吸收波長在316~321 nm之間，經由UV起始吸收波長(λonset)所得之能隙(Eg)範圍在3.0~3.05 eV之間。經由PL光譜顯示，其激發螢光在596~647nm之間，屬於紅光的範圍。
最後，藉由循環伏安計量法(CV) 測試所合成之聚醯亞胺之電化學性質，發現其半波電位在1.25~1.4 V之間；HOMO值在-5.61~-5.76eV之間；LOMO值在-2.56~-2.74eV之間。

另外由含anthraquinone側基之新二胺單體與芳香族二酸所合成的聚醯胺的固有黏度分別為0.42、1.02 dL/g。這些聚醯胺可溶於NMP、DMAc、m-cresol、o-chlorophenol等溶劑中，其抗張強度分別為49、62 MPa，斷裂伸長率分別為3、5％，經由DMA測試所合成之聚醯胺的玻璃轉移溫度分別為266、288℃，經由TGA測試所合成之聚醯胺的熱安定性，其10%熱重量損失，於空氣下分別為494、534℃，於氮氣下分別為496、512℃，於氮氣下600℃燃燒殘餘率分別為72、74％。
經由UV/Visible測試所合成之聚醯亞胺之光學性質在溶液狀態下之最大吸收波長分別為317、310 nm，經由UV起始吸收波長(λonset)所得之能隙(Eg)分別為2.92、2.93 eV。經由PL光譜顯示，其激發螢光分別在622、612nm，屬於紅光的範圍。
最後，藉由循環伏安計量法(CV) 測試所合成之聚醯亞胺之電化學性質，發現其半波電位分別為0.96、0.99 V；HOMO值分別為-5.32、-5.35eV；LOMO值分別為-2.4、-2.42eV。

A series of polyimides containing pendent anthraquinone groups were synthesized. The poly(amic-acid)s had inherent viscosities of 0.56~1.05 dL/g. The soluble polyimide had inherent viscosities of 0.82 dL/g. The polyimide were soluble in m-cresol、o-chlorophenol. The polymer films had tensile strengths of 46~152MPa, and elongation to break of 4.5~11.3%. The dynamic mechanical analysis (DMA) reveals that the glass transition temperatures ranged on 303∼401℃. In addition, the temperatures of 10% weight loss in air and nitrogen ranged on 543~574℃ and 551~574℃, respectively.
In the UV/Visible spectra, those polyimides had strong absorption bands from 316~321 nm in solution state. The energy band gaps of polymers calculated from the onset absorption wavelength of UV spectra in solution state were in the range from 3.0~3.05 eV. The photoluminescence spectra showed maximum bands ranged on 596~647nm in the red region.
In addition, cyclic voltammetry (CV) was employed to investigate the electrochemical behaviors of polyimides. The results showed that reversible oxidation redox couples at E1/2 ranged on 1.25~1.4 V. The HOMO and LOMO energy levels of the polyimides ranged on 5.61~5.76eV and 2.56~2.74eV, respectively.

A series of polyamides containing pendent anthraquinone groups were synthesized. The polyamides had inherent viscosities of 0.42 and 1.02 dL/g, respectively. The polyamide were soluble in N-Methyl-2-pyrrolidone (NMP) , N,N'-Dimethylacetamide (DMAc)、m-cresol、o-chlorophenol. The polymer films had tensile strengths of 49 and 62MPa, respectively and elongation to break of 3 and 5%, respectively. The dynamic mechanical analysis (DMA) reveals that the glass transition temperatures were 266 and 288℃, respectively. In addition, the temperatures of 10% weight loss in air and nitrogen were 494、534℃ and 496、512℃, respectively.
In the UV/Visible spectra, those polyamides had strong absorption bands at 317 and 310 nm in solution state, respectively. The energy band gaps of polymers calculated from the onset absorption wavelength of UV spectra in solution state were 2.92 and 2.93 eV, respectively. The photoluminescence spectra showed maximum bands were 622 and 612 nm in the red region, respectively.
In addition, cyclic voltammetry (CV) was employed to investigate the electrochemical behaviors of polyamides. The results showed that reversible oxidation redox couples at E1/2 were 0.96 and 0.99 V, respectively. The HOMO energy levels of the polyamides were -5.32、-5.35eV, respectively. The LOMO energy levels of the polyamides were -2.4 and -2.42eV, respectively.

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