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研究生： 佘德宇
Te-Yu Hser
論文名稱： 添加苯乙烯 -壓克力 (SAR)樹脂對鹼激發材料性質影響之研究
The Study on the Influence of Properties of Alkali-activated Materials by Adding Styrene-Acrylic Resin(SAR) 研
指導教授： 黃兆龍
Chao-Lung Hwang
口試委員: 陳君弢
Chun-Tao Chen
林利國
Lee-Kuo Lin
學位類別： 碩士
Master
系所名稱： 工程學院 - 營建工程系
Department of Civil and Construction Engineering
論文出版年： 2020
畢業學年度： 108
語文別： 中文
論文頁數： 115
中文關鍵詞： 鹼激發材料 、苯乙烯 -壓克力 樹脂 、表面風化 、表面裂縫 、養護方式
外文關鍵詞： Alkali-Activated Materials, Styrene-Acrylic Resin, Surface Efflorescence, Surface Crack, Curing condition
相關次數： 點閱：262  下載：0 
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    • 本研究以添加苯乙烯-壓克力(SAR)樹脂對鹼激發材料性質影響作為主軸，首先比較不同細度爐石在高莫爾濃度(10M、 12M、 14M)下的性質並針對性能較好的爐石細度添加不同比例的來探討其工程性質之影響， 也比較水中及空氣養護對添加苯乙烯-壓克力樹脂 試體的影響，共計24組實驗組配比，並與未使用苯乙烯 -壓克力樹脂的控制組來做比較。試驗內容 包含 硬固性質(抗壓強度、超音波速、熱傳導係數)，耐久性質(表面風化、表面裂縫、長度變化量、吸水率)之量測，以及運微觀照片來觀察 內部顯微結構 。結果顯示，12M莫爾濃度下添加5%苯乙烯-壓克力樹脂在抗壓強度上有最好的成果。耐久性質方面，苯乙 -壓克力 樹脂 添加含量的增加，能有效減少鹼激發試體的表面風化、表面裂縫及長度變化量。另外比較了相同配比在水中養護及空氣的結果，不論是否添加樹脂空氣養護的鹼激發材料在各項面皆優於水中養護。

    The main purpose of this study was to evaluate the results on the influence of properties of alkali-activated materials by adding styrene-acrylic resin(SAR). In the first part, compare different fineness of slag and discuss about the engineering properties. And choose the fineness which have better performance and add styrene-acrylic resin to explore the engineering properties. Then compare air and water curing about the performance of the engineering properties about the alkali activated material with styrene-acrylic resin, totally 24 groups mix proportion. And compare the result with the mix proportion have no styrene-acrylic resin. The experiment content include harden properties(Strength、 UPV、 Thermal) and durability properties(Surface efflorescence、 Surface crack、 Length change、 Water absorption), and finally use the XRD to observe the chemical composition and the SEM to see the microstructure and observe the inside structure. As the result, thadding suitable styrene-acrylic resin can keep compressive strength similar to the control group, in durability properties, when the adding of amount increase can reduce surface efflorescence, surface crack and length change effectively. And in different curing condition, the same mix proportion no matter adding styrene-acrylic resin or not, air curing sample have better performance than water curing.

    摘要 iii Abstract ii 目錄 iii 表目錄 vi 圖目錄 viii 第一章 緒論 1 1 1 研究背景 1 1 2 研究動機與目的 1 1 3 研究方法與流程 2 第二章 文獻回顧 4 2 1 鹼激發材料 4 2 2 鹼激發鈣 矽材料 ( 5 2.1.1 鹼激發鈣 矽材料 ( 之反應機理 5 2.1.1 影響鹼激發鈣 矽材料 ( 之因素 6 2 3 鹼激發材料的表面風化 6 2.2.1 鹼激發材料的表面風化之反應機裡與影響 6 2.2.2 影響鹼激發材料的表面風化之因素 7 2.2.3 預防鹼激發材 料的表面風化的方法 7 2 4 鹼激發材料的乾縮性質 8 2.3.1. 鹼激發材料的乾縮之反應 8 2.3.2. 影響鹼激發材料的乾縮之因素 8 iv 2.3.3. 2.3.3. 預防影響鹼激發材料的乾縮的方法預防影響鹼激發材料的乾縮的方法 ...................................... 88 2 2--55 鹼激發材料的裂縫情形鹼激發材料的裂縫情形.................................................................... 99 2 2--66 水淬爐石粉水淬爐石粉........................................................................................ 99 2.5.1 2.5.1 水淬爐石之物理性質水淬爐石之物理性質 ............................................................ 1010 2.5.2 2.5.2 水淬爐石之化學性質水淬爐石之化學性質 ............................................................ 1010 2 2--77 乳膠漆乳膠漆(Latex)(Latex)於鹼激發材料的應用於鹼激發材料的應用............................................ 1111 第三章 第三章 試驗計畫試驗計畫.......................................................................................... 1818 3 3--11 計畫概要計畫概要.......................................................................................... 1818 3 3--22 試驗材料試驗材料.......................................................................................... 1818 3.2.1 3.2.1 爐石粉爐石粉 .................................................................................... 1818 3.2.2 3.2.2 氫氧化鈉溶液氫氧化鈉溶液 ........................................................................ 1919 3.2.3 3.2.3 拌合水拌合水 .................................................................................... 1919 3.2.4 3.2.4 苯乙烯苯乙烯--壓克力樹脂壓克力樹脂(Styrene(Styrene--Acrylic Resin)Acrylic Resin) ................ 1919 3 3--33 試驗設備試驗設備.......................................................................................... 1919 3 3--44 配比設計配比設計.......................................................................................... 2121 3.4.1 3.4.1 試驗變數試驗變數 ................................................................................ 2121 3.4.2 3.4.2 試體編號說明試體編號說明 ........................................................................ 2222 3.4.3 3.4.3 配比設計配比設計 ................................................................................ 2222 3.4.1 3.4.1 拌和程序拌和程序 ................................................................................ 2323 3 3--55 試驗項目試驗項目.......................................................................................... 2424 3.5.1 3.5.1 物理性質試驗物理性質試驗 ........................................................................ 2424 3.5.2 3.5.2 硬固性質試驗硬固性質試驗 ........................................................................ 2525 3.5.3 3.5.3 耐久性質試驗耐久性質試驗 ........................................................................ 2727 3.5.4 3.5.4 微觀結果分析微觀結果分析 ........................................................................ 2828 第四章 第四章 結果與分析結果與分析...................................................................................... 4646 v 4 4--11 物理性質試驗物理性質試驗.................................................................................. 4646 4.1.1 4.1.1 含水量試驗含水量試驗 ............................................................................ 4646 4 4--22 硬固性質實驗硬固性質實驗.................................................................................. 4646 4.2.1 4.2.1 抗壓強度試驗抗壓強度試驗 ........................................................................ 4646 4.2.2 4.2.2 超音波速試驗超音波速試驗 ........................................................................ 4848 4.2.3 4.2.3 熱傳導係數試驗熱傳導係數試驗 .................................................................... 5151 4 4--33 耐久性質試驗耐久性質試驗.................................................................................. 5353 4.3.1 4.3.1 表面風化加速試驗表面風化加速試驗 ................................................................ 5353 4.3.2 4.3.2 乾縮試驗乾縮試驗 ................................................................................ 5454 4.3.3 4.3.3 裂縫觀察裂縫觀察 ................................................................................ 5454 4.3.4 4.3.4 吸水率試驗吸水率試驗 ............................................................................ 5555 4 4--44 圍觀結果分析圍觀結果分析.................................................................................. 5757 4.4.1 4.4.1 XX光繞射儀光繞射儀 .............................................................................. 5757 4.4.2 4.4.2 掃描式電子顯微鏡掃描式電子顯微鏡(SEM)(SEM) ...................................................... 5757 第五章 第五章 結論與建議結論與建議...................................................................................... 9797 5 5--11 結論結論.................................................................................................. 9797 5 5--22 建議建議.................................................................................................. 9898 參考文獻 參考文獻.............................................................................................................. 9999

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