無機聚合物擁有比卜特蘭水泥優異之物理與化學性質，但是受限於原料品質與來源不穩定，且原料價格偏高等情形，故仍然無法取代卜特蘭水泥，廣泛的使用在營建工程上。而現今環保意識高漲，水泥之製造已成為環境污染和全球暖化的元兇，因而尋求取代高污染水泥的替代材料已成為營造業刻不容緩之課題，而無機聚合物是利用鹼溶液將富含Si與Al離子的礦物材料或工業廢棄物，經由溶解與聚合反應而形成之新穎環保材料。而本研究主要的激發材料為黏土礦物的偏高嶺土與農業廢棄物之稻殼灰，將兩者混合後加入氫氧化鈉與矽酸鈉調製成的鹼激發劑，再使用鹼激發技術製成複合型之無機聚合物，希望利用兩種材料經由高溫燒結後的性質與複合材料互補加成之特性，製作出高耐火低熱傳導係數材料，並檢測其他工程性質，作為評估本研究高耐火低熱傳導係數材料之性能，另外本研究為節省材料使用上之成本，直接將稻殼灰取代量提高至25%和50%，以減少偏高嶺土的浪費。而研究結果顯示，複合型無機聚合物砂漿在工作性、抗壓強度、單位重、熱傳導係數、耐火試驗之背溫溫度方面都有不錯的效果，而抗壓強度最高為72Mpa，單位重最低為1468(kg/m3)，背溫溫度大部分配比都可以符合規範要求溫度，最低為155℃，由此可證明無機聚合物擁有比卜特蘭水泥優越之耐火性能，稻殼灰取代量增加有利於降低熱傳導係數，使材料之防火性質更佳，也符合了本研究之農業廢棄物稻殼灰大量使用的原則。

Geopolymer with excellent physical and chemical properties than Portland cement，but is limited by the quality of raw materials and sources of instability，and expensive of raw materials situation, it is still unable to replace Portland cement, widely used in construction engineering。Nowadays, environmental consciousness promote, and the manufacture of cement has become the culprit of environmental pollution and global warming, therefore seek alternative materials to replace the highly polluting cement has become imperative for the construction industry topics, The Geopolymer is used alkaline solution rich in Si and Al ions, mineral materials or industrial waste through the dissolution and polymerization and the formation of new environmentally friendly materials。In this study, the main excitation material is metakaolin of clay mineral and agricultural waste,is rice husk ash, By adding sodium hydroxide and sodium silicate modulated into two mixed alkali activator, re-use the alkali excitation technique made of composite Geopolymer, want to use two materials through the nature of the high-temperature sintering and composite complementary bonus features, and to produce low thermal conductivity and high fire-resistant material, and to detect the other properties of engineering, as the assessment of this study for the high fire-resistant and low thermal conductivity material performance, in addition, this study in order to save the cost of use of the material directly to the rice husk ash to replace the amount increased to 25% and 50% in order to reduce the waste of metakaolin。The study results show that the Geopolymer mortar of workability, compressive strength, unit weight, thermal conductivity, fire resistance test-back warm temperature has a good effect, the compressive strength the highest was 72 MPa, unit weight a minimum of 1468 (kg/m3), back warm temperature most of the mix proportion can be in accordance with the standard postulate temperature, a minimum of 155 ℃, this proof of the Geopolymer has a superior performance of fire-resistance than Portland cement, The rice husk ash increased help to reduce the thermal conductivity, the fire-resistance of material is better,and also in line with the principle of agricultural waste rice husk ash heavy use of the study.

1. Xu, H., Van Deventer, J.S.J. “The geopolymerisation of alumino-silicate minerals”, International Journal of Minerals Processing, Vol. 59, pp. 247-266 (2000).
2. Davidovits, J., “Mineral polymers and methods of makinthem”,USA Patent, No. 4, pp. 349-386 (1999).
3. Palomo, A., Grutzeck, M.W., Blanco, M.T.,“Alkali-activated fly ashes A cement for the future”, Cement and Concrete Research, Vol. 29, pp 1323-1329 (1999).
4. Lloyd, R.R., Provis, J.L., and Van Deventer, J.S.J., “Microscopy and microanalysis of inorganic polymer cemen. 2:The gel binder,” Journal of Materials Science, Vol. 44, No. 2, pp. 620-631 (2009).
5. Dombrowski, K.A., and Buchwald, M. Weil., “The influence of calcium content on structure and thermal performance of fly ash based geopolymers”, Journal of Materials Science, Vol. 42, No. 9, pp. 3033-3042 (2007).
6. Geopolymer Institute、http://www.geopolymer.org.
7. Davidovits, J., “Geopolymer:man-made rock geosynthesis and the resulting development of very early high strength cement”, Journal of Materials Education, Vol.16, No.2-3, pp.91-139. (1994).
8. Krizana, D., Zivanovic, B., “ Effects of dosage and modulus of water glass on early hydration of alkali-slag cements”, Cement and Concrete Research,Vol. 32, pp. 1181-1188 (2002).
9. 吳忠偉、廉慧珍，「高性能混凝土」，中國鐵道出版7社，北京(1999)。
10. Wang, S. D., Pu, X. C., Scrivener, K. L., Pratt, P. L., “Alkali-activated cement and concrete. A review of properties and problems”, Advances in Cement Research, Vol. 7(27), pp.93-102 (1995).
11. Shi, C., Krivenko, P.V., and Roy, D., “Alkali-activated Cement and Concrete”, London and New York: Taylor＆Francis (2006).
12. J. Davidovits, “Geopolymer Chemistry and Applications A Practical and Scientifc Approach to Sustainable Development 2nd Edition”, Editors: Joseph Davisovits, pp.3-18 (2008).
13. R.N. Swamy, M.M. “Al-Asali, Engineering properties of concrete affected by alkali-silica reaction”, ACI Materials Journal 85, Vol. 5 pp. 367-374 (1988).
14. Della M Roy, “Alkali-Activated Cements Opportunities and
15. challenges,” Cement and Concrete Research, Vol. 29, pp.249-254.(1999)
16. Li, C., Sun, H., and Li, L. “A review : The comparison between alkali-activated slag (Si+Ca) and metakaolin (Si+Al) Cement”,Cement and Concrete Research, doi:10.1016.(2010)
17. Wang,S.D.,Scivener,K.L.,“Hydration products of alkali activated slag cement”,Cement and Concrete Research, Vol.25(3),pp.561-571
18. (1995)
19. Lecomte, I., Henrist, C., Liegeois, M., Maseri, F., Rulmont, A., Cloots, R., “(Micro)-structural comparison between geopolymers, alkali-activated, slag cement and Portland cement”, Journal of the European Ceramic Society, Vol.26, pp.3789-3997(2006)
20. 徐彬，固態鹼組分礦渣礦渣水泥的研製極其水化機理和性能的研 究，博士學位論文，清華大學，北京 (1995)
21. 代新祥、文梓芸， 「無機聚合水泥」 ，新型建築材料，北京， 第34、35頁 (2001)
22. Davidovits, J. “Geopolymers: Inorganic polymeric new materials” , Journal of thermal analysis, Vol.37, 1633-1656 (1991)
23. Davidovits, J. “30 years of successes and failures in gerpolymer applications. Market trends and potential breakthroughs”, Proc., Int. Conf. on Geopolymer. (2002)
24. Hua Xu, Van Deventer, J.S.J., and G.C. Luckey, “Effect of alkali metals on the preferential geopolymerization of stilbite/kaolinite mixtures,” International Engineering Chemical Research, Vol. 40, pp. 3749-3756,(2001)
25. 李元凱，「偏高嶺土聚合膠體工程性質之研究」，碩士論文，國立台灣科技大學，(2008)，(張大鵬教授指導)
26. 成立，「三種鹼激發膠凝材料的反應機理及其產物」，荊門職業技術學院學報，第19卷第6期，第92~95(2004)
27. Huanhai, Z., Xuequan, W. and Zhongzi, X., “Kinetic Study on Hydration of Alkali –Activated Slag”, Cement and Concrete Research, Vol. 23, pp. 1253-1258 (1993)。
28. 王悟敏、禹尚仁，「無熟料硅酸鈉礦渣水泥的水化機理」，硅酸鹽學報，第18卷第2期，第104~106頁 (1990)。
29. 楊南如，「鹼膠凝材料形成的物理化學基礎」，硅酸鹽學報，第24卷第2期，第209~215頁 (1996)。
30. Van Jaarsveld, J.G.S., Van Deventer, J.S.J. and Lorenzen, L., “The potential use of geopolymeric materials to immobilize toxic metals: Part I,” Theory and application,Minerals Engineering, Vol.10, No.7,pp. 659-669 (1997)。
31. Sun, W., Zhang, Y.S., Lin, W. and Liu, Z.Y., “In situ monitoring of the hydration process of K-PS geopolymer cement with ESEM”, Cement and Concrete Research, Vol. 34, pp. 935-940 (2004)
32. Xu, H., and Van Deventer, J.S.J., “The geopolymerisation of natural alumino-silicates,” Proceedings of Geopolymere 99 Second International Conference, edited by: Davidovits, J., Davidovits, R. and James, C., Institut Geopolymere, Saint-Quentin, France, pp. 43-64 (1999)
33. Barbosa, V.F.F., MacKenzie, K.J.D. and Thaumaturge, C., “Synthesis and characterization of materials based on inorganic polymers of alumina and silica: sodium polysialate polymers,” International Journal of Inorganic Materials, Vol. 2, pp. 309-317 (2000)。
34. Fernandez-Jimenez, A., palomo, J. G., Puertas, F., “Alkali-Activated Slag Mortars Mechanical Strength Behaviour”, Cement and Concrete Research, Vol. 29, pp. 1313-1321 (1999)。
35. Davidovits, J., “Chemistry of geopolymeric systems terminology”, Proceedings of Geopolymere 99 Second International Conference, editors by: Davidovits, J., Davidovits, R. and James, C., Institut Geopolymere, saint-Quentin, France, pp. 9-40 (1999a)。
36. Duxson, P., Fernandez-Jimenez, A., and Provis, J.L. and Lukey, G.C. and Palomo, A. and Van Deventer, J.S.J., “Geopolymer technology: the current state of the art”, Journal of Material Science, Vol. 42, No.9, pp. 2917-2933 (2007)。
37. Davidovits, J., “Geopolymer chemistry and sustainable development. The poly (sialate) terminology: a very useful and simple model for the promotion and understanding of green-chemistry”, Geopolymer Green Chemistry and Sustainable Development Solutions, edited by: Davidovits, J., Institut Geopolymere, Saint-Quentin, France, pp. 9-15 (2005)。
38. 戴詩潔，「高嶺石鋁矽酸鹽聚合材料之研究」，碩士論文，國立台北科技大學，(2005)。(鄭大偉教授指導)
39. 陳志賢，「含矽質廢棄物之無機聚合物」，博士論文，國立成功大學土木工程研究所，(2009)。(黃忠信教授指導)
40. C. Kunze and R. Gatzweiler and G. Kiebig and J. Davidovits, “Solidification of various radioactive residues by geopolymere with special emphasis on long-term-stability. Proceedings of Geopolymer 99 Second International Conference”, Editors: Joseph Davidovits, Ralph Davidovits and Claude James, pp. 211-228 (1999)
41. Davidovits, J. and Davidovits, M., Geopolymer: Room-tempurature ceramic matriz for composites, Ceramic Engineering Science Proceedings, Vol. 9, pp. 835-841 (1988)。
42. Davidovits, J., Method for bonding fiber reinforcement on concrete and steel structures and resultant products, U.S Patent 5,925,449, pp. 1-13 (1999)
43. Davidovits, J., Chemistry of geopolymeric systems terminology, Proceeding of Geopolymer 99 Second International Conference, Editors: Davidovits, J., Davidovits, R. and James, C., France, pp. 9-37 (1999b)
44. Peter Duxson, John L. Provis, Grant C. Lucky and Jannie S. J. Van Deventer, “Structural ordering in geopolymers derived from metakaolin. Geopolymer, Green Chemistry and Sustainable Development Solutions”, Editors: Joseph Davidovits, pp. 21-25 (2005)
45. J.W.Phair, J.S.J. Van Deventer, “Effect of silicate activator pH on the microstructural characteristics of waste-based geopolymers”, International Journal Minerals Process, Vol. 66, pp. 121-143 (2002)
46. Davidovits, J., Davidovits, M., “Geopolymer：ultra-high temperature tooling material for the manufacture of advanced composites”, International SAMPE Symposium and Exhibition Proceedings, Vol. 36, pp. 1939-1949 (1991)
47. Davidovits, J., Synthetic mineral polymer compound of the silicoaluminates family and preparation process, USA Patent 4,472,199 (1984)
48. Duxson, P., Provis, J. L., “Understanding the relationship between geopolymer composition, microstructure and mechanical properties”, Colloids and Surfaces A: Physicochem. Eng. Aspects, 269, pp. 47-58 (2005)
49. Schmucker, M. and Mackezie, K.J.D., “Microstructure of sodium polysialate siloxo geopolymer”, Ceramics International, Vol. 31, No. 3, pp. 433-437 (2004)
50. Davidovits, J., Process for obtaining a geopolymeric alumino-silicate and products thus obtained, USA Patent 5,342,595 (1994)
51. Davidovits, J., Alkaline alumino-silicate geopolymeric matrix for composite materials with fiber reinforcement and method for obataining same, USA Patent 5,978,307 (1998)
52. 蒲心誠，楊長輝，「高強混凝土與高強鹼爐石混凝土研究」，混凝土，第6卷第3期，第18∼30頁 (1994)
53. Davidovits, J., Global Warming Impact on Cement and Aggregates Industries, World Resource Review, (6)2, pp. 263-278 (1994)
54. Davidovits, J., Early high-strength mineral polymer, United States Patent 4,509,985 (1985)
55. Davidovits, J., Method for obtaining a geopolymeric binder allowing to stabilize, solidify and consolidate toxic or waste materials, USA Patent 5,349,118 (1994)
56. Yip, C. K., Lucky, G. C., Van Deventer, J.S.J., The coexistence of geopolymeric gel and calcium silicate hydrateat the early stage of alkaline activation, Cement and Concrete Research, 35, pp. 1688-1697 (2005)
57. Phair, J. W. and Van Deventer, J. S. J., “Effect of Silicate Activator pH on the leaching and material characteristics of waste- based inorganic polymers”, Minerals Engineering, Vol. 14, No. 3, pp. 289-304 (2001)
58. 陳松，李玉香，「模擬含鹼高放廢液“鹼-偏高嶺土-礦渣”固化性能研究」，矽酸鹽通報，第25卷第3期，第42~47頁 (2006)
59. 代新祥，「鹼機活土聚水泥的製備、結構與性能」，博士論文，華南理工大學 (2002)
60. Davidovits , J., “Waste solidification and disposal method”, USA Patent 4,859,367 (1989)
61. 金漫彤，樓梅曉，韓懁芬，「摻加礦渣的土壤聚合物對重金屬的固化」，浙江工業大學學報，第34卷第6期，第599~602頁 (2002)
62. 任玉峰，馬鴻文，王剛，馮武威，丁秋霞，「利用金礦製尾砂製備礦物聚合材料的實驗研究」，現代地質，第2期，第171~175頁 (2003)
63. Van Jaarsveld, J.G.S., Van Deventer, J.S.J., “Effect of the alkali metal activator on the properties of fly ash-based geopolymers, Industrial & Engineering Chemistry Research, Vol. 38, pp. 3932-3941 (1999)
64. Swanepoel, J. C., Strydom, C. A., “Utilisation of fly ash in a geopolymeric materic”, Applied Geochemistry,V. 17, No. 8, pp. 1143-1148 (2002)
65. Barbosa, V. F. F., MacKenzie, K. J. D., “Thermal behavior of inorganic geopolymers and composites derived from sodium polysialate”,Materials Research Bulletin, Vol. 38 pp. 319-331 (2003)
66. S.D. Wang, K.L. Scrinener, P.L. Pratt, “Factors Affecting the Strength of Alkali-Activated Slag”, Cement and Concrete Research, Vol. 24, No. 6, pp. 1033-1043, (1994)
67. Shi, C., and Day, R.L., “Some factors affecting early hydration of alkali-slag cement”, Cement and Concrete Research, Vol. 26, No. 3, pp. 439-447 (1996)
68. Shi, C., and Day, R.L., “A calorimetric study of early hydration of alkali-slag cement”, Cement and Concrete Research, Vol. 25, No.6, PP. 1333-1346 (1995)
69. Song, S., and Jennings, H.M., “Pore solution chemistry of alkali-activated groud granulated blast-furnace slag”, Cement and Concrete Research, Vol. 29, No. 2, pp. 159-170 (1999)
70. 馬鴻文，楊靜，任玉峰，凌發科，「礦物聚合材料：研究現狀與發展前景」，地學前緣，第9卷第4期，第397~407頁 (2002)
71. Glukivski, V.D., “Alkali-earth binder and concrete produced with them, USSR, Russian, Visheka shkola, Kiev. (1979)
72. C. Kaps, and A. Buchwald, “Property controlling influences on the generation of geopolymeric based on clay”, Geopolymer 2002 International Conference, Melbourne, Australia, CD-ROM, (2002)
73. Phair, J. W., Deventer J. S. and Smith, J. D., Mechanism of polysialation in the incorporation of zirconia into fly ash-based geopolymers, International Engineering Chemical Research, Vol. 39, pp. 2925-2934 (2000)
74. 馬鴻文，任玉峰，王剛，馮武威，丁秋霞，「金礦尾砂礦物聚合材料的製備及其影響因素」，岩礦測試，北京，第22卷第2期 ，第103-107頁 (2003)
75. 枋吟霞，鄭大偉，翁祖炘，邱文通，「利用焚化灰渣製成無機聚合材料之研究」，資源與環境學術研討會，(民國93年)
76. 郭文瑛，文梓芸，殷素紅，吳國林，「兩種土壤聚合物與鹼激發劑的激發效果對比」，華南理工大學學報，第35卷第8期，第103-108頁，(2007)
77. Komnitasa, K., Zaharaki, D., and Perdikatsis, V., “Effect of synthesis parameters on the compressive strength of low-calcium ferronickel slag inorganic polymers”, Journal of Hazardous Materials, Vol. 161, No. 2-3, pp. 760-768 (2009)
78. Brough, A.R., Holloway, M., and Sykes, J. and Atkinson, A., “Sodium silicate-based alkali-activated slag mortars Part II:The retarding effect of additions of sodium chloride or malic acid”, Cement and Concrete Research, Vol.30, No. 9, pp. 1375-1379 (2000)
79. 文梓芸，「鹼-硅酸集料反應的化學原理」，硅酸鹽學報，第22卷第6期，5697-604 (1994)
80. 張西玲，姚愛玲，「礦渣的活性激發技術及機理的研究進展」，萍鄉高等專科學校學報，第3期，第12-16頁 (2007)
81. Weng, L., Sagoe Crentsil, K., Brown, T. and Song, S., “Effects of aluminates on the formation of geopolymers, Materials Science and Engineering B, Vol. 117, pp. 163-168 (2005)
82. 蔡宗翰，「綠水泥與綠水泥混凝土之性質探討」，碩士論文，國立台灣科技大學 (2011)
83. Fernandez-Jimenez, A., Palomo, A., “Composition and microstructure of alkali activated fly ash binder: Effect of the activator”, Cement and Concrete Research, Vol. 35, pp. 1984-1992 (2005)
84. 李明霖，鄭大偉，「無機聚合物吸附重金屬之研究」，資源與環境學術研討會論文集，花蓮，第131-138頁 (2005)
85. 張文華，鄭大偉，吳傳威，「以飛灰製成無機聚合樹脂應用於混凝土補強之可行性研究」，第十屆海峽兩岸環境保護學術研討會，台中 (2005)
86. Bakharev, T., Sanjayan, J. G., Cheng, Y. B., “Effect of elevated temperature curing on properties of alkali-activated slag concrete”, Cement and Concrete Research, Vol. 29, No. 10, pp. 1619-1625, (1999)
87. Shi C., Li, Y., “Investigation on some factors affecting the characteristics of alkali-phosphorus slag cement”, Cement and Concrete Research, Vol. 19, No.4, pp. 527-533, (1989)
88. Shi C., Xie, P., “Interface between cement paste and quartz sand in alkali-activated slag mortars”, Cement and Concrete Research, Vol. 28, No. 6, pp. 887-896, (1998)
89. 付興華，陶文宏，孫鳳金，「水玻璃對地聚物膠凝材料性能影響的研究」，水泥工程，濟南，第2期，第6-10頁， (2008)
90. Silva, P.D., Sagoe, Crenstil, K. and Sirvivatnanon, V., “Kinetics of geopolymerization: Role of Al2O3 and SiO2”, Cement and Concrete Research, Vol. 37, No. 4, pp. 512-518 (2007)
91. 馬鴻文，凌發科，楊靜，王剛，「利用鉀長石尾礦製備聚合材料的實驗研究」，地球科學－中國地質大地學報，北京，第27卷第5期，第576-583頁 (2002)
92. 鄭娟榮，周同和，劉麗娜，「鹼－偏高嶺石－礦渣系膠凝材的凝結硬化性能研究」，矽酸鹽通報，鄭州，第26卷第6期，第1064-1067頁， (2007)
93. 林瑋倫，「鹼激發爐石基膠體工程性質之研究」，碩士論文，國立台灣科技大學營建工程系 (2009)
94. 丁慶軍，張高展，王紅喜，趙運承，胡曙光，「鋼渣-偏高嶺土體系地聚合物試驗方案與結果」，武漢理工大學學報，第29卷第1期，第18-21頁 (2007)
95. Zhang, S., Gong, K. and Lu, J., “ Novel modification method for inorganic geopolymer by using water soluble organic polymers”, Materials Letters, Vol. 58, pp. 1292-1296 (2004)
96. 馬鴻文，丁秋霞，馮武威，王剛，「利用石英砂制備礦物聚合材料的實驗研究」，建築石膏與膠凝材料，北京，第6-8頁 (2003)
97. Van Jaarsveld, J.G.S., Van Deventer, J.S.J. and Lukey, G. C., “The effect of composition and temperature on the properties of fly ash and kaolinite based geopolymers, Cemical Engineering Journal, Vol. 89, pp. 63-73 (2002)
98. Hardjito, D., Wallah, S.E. and Rangan, B.V., Research into engineering properties of geopolymer concrete, Geopolymer 2002 International Conference, Melbourne, Australia, CD-ROM (2002)
99. 黃立遠，「飛灰基無機聚合物工程性質及應用之研究」，博士論文，國立台灣科技大學 (2010)
100. Davidovits, J., “Geopolymer chemistry and applications”, France, Saint-Quentin, Institut Geopolymere, pp. 384-385 (2008)
101. Davidovits, J., “Fire proof Geopolymeric”, St. Quentin, France Cordi-Geopolymere, pp. 165-170 (1999)
102. 陳冠宇，「鹼激發爐石基膠體配比因子對其工程性質影響之研究」，碩士論文，國立台灣科技大學 (2010)
103. 金漫彤，「土壤聚合物固化重金屬技術及其終產物之研究」，碩士論文，浙江大學 (2005)
104. Phair,J.W., Van Deventer, J.S., and Smith, J.J.D., “Effect of Al source and alkali activation on Pb and Cu immobilization in fly-ash based geopolymers”, Applied Geochemistry, Vol. 19, No. 3, pp. 423-434 (2004)
105. 林孟瞱，「利用燃煤底灰製成無機聚合材料之研究」，碩士論文，國立台北科技大學資源工程系研究所 (2006)
106. 郭錦崑，「利用當量分子莫耳來探討無機聚合物之最佳配比設計」，博士論文，國立台灣科技大學 (2012)
107. 黃柏齡，「礦物熱差分析鑑定手冊」，科學出版社，北京，第516-518頁 (1987)
108. 黃怡禎，「礦物學」，地球科學文教基金會，第534頁 (2000)
109. 韓敏芳，「非金屬礦物材料制備與工藝」，化學工業出版社，北京，第208-215頁 (2004)
110. Van Jaarsveld, J.G.S., Van Deventer, J.S.J. and Schwartzman, A., “The potential use of geopolymeric materials to immobilize toxic Metals︰Part II. Minerals and characteristics, Minerals Engineering, Vol. 12, No. 1, pp. 75-91 (1999)
111. 丁明，「非金屬礦加工過程」，化學工業出版社，北京，第327-332頁 (2003)
112. Chakraborty, A. K., “DTA study of preheated kaolinite in the mullite formation region”, Thermochinica Acta, Vol. 398, No. 2, pp. 203-209 (2003)
113. 曹德光，蘇達根，楊占印，宋國勝，「偏高嶺石的微觀結構與鍵合反應能力」，礦物學報，第24卷第4期，第366-372頁 (2004)
114. 陳秋艷，那倞，「偏高嶺土在我國的潛在應用」，礦業研究與開發，第24卷第4期，第31-33頁 (2004)