鋰離子電池是為近年來持續受到關注之議題，製備快速且具有優良的效能的電極成為研究學者們的目標，而常壓電漿產業也因可提供快速與簡易的鍍膜、表面改質等特點受到矚目。錳氧化物是許多產業所使用的材料之一，因錳氧化物易於生產且穩定，經常應用在電池領域中。但是常見之鋰離子電池負極材料多為矽材或碳類材料添加以提升電池性能，極少數使用薄膜方式一步製備電極。
在本研究中，使用常壓電漿噴射束與前驅物四水合硝酸錳在碳類基材上沉積電極材料，且透過添加葡萄糖改善顆粒粒徑，而後檢測膜層材料特性分析與電化學性能。結果分析使用X光繞射儀進行材料鑑定，掃描式電子顯微鏡觀察表面形貌，薄膜附著性透過方格試驗，熱重分析分析材料熱裂解溫度，充放電試驗檢測效能，電化學阻抗分析得知電極效用。
結果顯示透過常壓電漿鍍膜一步法製備之負極膜層電極，可沉積α-Mn2O3薄膜，其具有4B等級之附著性能，而在結構上添加葡萄糖 (P-MG)可有效提升結晶性，以及經由計算可知顆粒粒徑大小由原始500 nm縮小至300 nm，縮小粒徑更有利於鋰離子嵌入與嵌出。在後續的電池分析中可知未添加葡萄糖(P-M)之負極首圈電容量1765 mAh/g，且在第五圈充放電後藉由XRD檢測得知，結構無序化無法提供完整充放電之條件；添加葡萄糖之負極(P-MG)在首圈電容量為2277 mAh/g，提供穩定之結構緩解電容急速衰退的問題。
此研究表明，透過常壓電漿鍍膜鋰離子電池負極膜層之方法具有實用性能，不僅減少製備電極之時間，也簡化製備過程，以達到效果，實現了一步法製備電極材料之應用。

In recent years, the lithium-ion battery has become an issue of concern. The main goals of in field of the lithium-ion battery are fast preparation and excellent efficiency electrode. Atmospheric pressure plasma jet (APPJ) can provide a high speed of coating and surface treatment. In this study, APPJ and the precursor of manganese(II) nitrate tetrahydrate to deposit electrode material on the carbon-based substrate is used. As adding glucose into the precursor, the particle size has been significantly decreased. The crystalline structure of the prepared material is detected by X-ray diffraction (XRD). The surface morphology is observed by scanning electron microscopy (SEM). The Cross-Cut Test (ACCT) is used to test the adhesion characteristic of the deposited film. The material of the thermal pyrolysis temperature is measured by thermogravimetric analysis (TGA). The efficiency of the battery is tested by charging and discharging in a electrochemical station and an electrochemical impedance spectroscopy (EIS).

These results show that the rapid synthesis of manganese thin films in a one-step process via APPJ is achieved. It cab be indicated that the films coated with Mn2O3 prepared by APPJ exhibit a superior adhesion performance, while adding glucose (P-MG) into the precursor can increase the crystallinity. Furthermore, the particle size can be decreased to intercalate and deintercalate in the lithium-ion battery. Also, the particle size becomes smaller from 500 nm to 300 nm. In electrochemical performacne, the first charge-discharge (C–D) cycling performance data is 1765 mAh/g without adding glucose (P-M) while the first cycle of capacity is 2277 mAh/g by adding glucose (P-MG) into the precursor. The effect of glucose addition provides stable structure to improve the degradation of capacity. In conclusion, APPJ provides an efficient method of coating in the lithium-ion battery. It decreases the time-consuming preparation and simplifies the preparation process. The application of electrode material is successfully achieved.

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