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| 研究生： |
楊芝寧 Chih-Ning Yang |
|---|---|
| 論文名稱： |
矽烷偶合劑接枝之氧化石墨烯及熱脫層氧化石墨烯之合成及探討其對環氧樹脂之聚合固化反應動力、玻璃轉移溫度、X光散射特性、聚合固化樣品微觀型態結構、體積收縮、機械性質、熱傳導及導電性質的影響 Synthesis of silane-grafted graphene oxide (sg-GO) and silane-grafted thermally reduced graphene oxide (sg-TRGO), and their effects on the cure kinetics, glass transition temperatures, X-ray scattering characteristics, cured sample morphologies, volume shrinkage, mechanical properties, and thermal and electrical conductivities for epoxy resins |
| 指導教授： |
黃延吉
Yan-Jyi Huang |
| 口試委員: |
邱文英
Wen-Yen Chiu 陳崇賢 Chorng-Shyan Chern |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2021 |
| 畢業學年度： | 109 |
| 語文別： | 中文 |
| 論文頁數： | 304 |
| 中文關鍵詞： | 氧化石墨烯 、熱脫層氧化石墨烯 、矽烷接枝之氧化石墨烯 、矽烷接枝之熱脫層氧化石墨烯 、抗收縮劑 、環氧樹脂 、聚合固化 、聚合固化反應動力 、微分掃描熱分析儀 、玻璃轉移溫度 、動態機械分析儀 、X光散射特性 、微觀型態結構 、掃描式電子顯微鏡 、體積收縮 、機械性質 、熱傳導性質 、導電性質 |
| 外文關鍵詞： | silane-grafted graphene oxide, curing; curing kinetics, X-ray scattering characteristics |
| 相關次數： | 點閱：464 下載：6 |
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本文探討添加氧化石墨烯(GO)、矽烷接枝氧化石墨烯(sg-GO)、熱脫層氧化石墨烯(TRGO)以及矽烷接枝熱脫層氧化石墨烯(sg-TRGO)等數種特用添加劑的合成及其對環氧樹脂(EPR)/ 4,4-二氨基二苯甲烷(DDM)/特用添加劑三成份系統於100℃/180℃階段性恆溫固化之聚合固化反應動力、玻璃轉移溫度、及X光散射特性、聚合固化樣品微觀型態結構、体積收縮、機械性質、熱傳導及導電性質的影響。
熱脫層氧化石墨烯(TRGO)是將氧化石墨烯(GO)置於1050℃的高溫爐中30秒合成熱脫層而得；GO則是將平均粒徑為75μm的天然石墨粉以改良Hummers 法製得。
矽烷接枝氧化石墨烯(sg-GO)及矽烷接枝熱脫層氧化石墨烯(sg-TRGO)係帶有環氧基團的矽烷偶合劑，即（3-縮水甘油氧基丙基）三甲氧基矽烷（GPS），做為表面改質劑。
另外，吾人使用差式掃描卡計(DSC)、動態機械分析儀(DMA)、小角度X-ray散射儀(SAXS)測定環氧樹脂(EPR)/ 4,4-二氨基二苯甲烷(DDM)/特用添加劑三成份系統之聚合固化反應動力、玻璃轉移溫度及X光散射特性之影響。
最後吾人亦使用掃描式電子顯微鏡(SEM)、萬用材料試驗機、耐衝擊測試機、熱傳導係數測定儀及表面電阻計研究EPR/DDM/添加劑三成分系統聚合固化後之體積收縮、微觀型態結構、機械性質、熱傳導及導電性之影響。
The effects of graphene oxide (GO), silane-grafted graphene oxide (sg-GO) , thermally reduced graphene oxide (TRGO), silane-grafted thermally reduced graphene oxide (sg-TRGO) as special additives on the cured sample on the cure kinetics, glass transition temperature, X-ray scattering characteristics,morphologies, volume shrinkage characteristics , mechanical properties, thermal conductivities and electrical properties of the Epoxy/DDM/Additive ternary system cured after a stepwise isthermal process of 100℃/180℃ were investigated.
The thermally reduced graphene oxide (TRGO) was produced by placing graphene oxide (GO) in a high-temperature furnace kept at 1050℃, which was synthesized from natural graphites with average particle size of 75μm by a modified Hummers method.
The silane-grafted GO (sg-GO) or silane-grafted TRGO (sg-TRGO) was synthesized by using the silane coupling agent bearing epoxy functional group, namely, γ-glycidyloxy propyl trimethoxy silane (GPS), as a surface modifier for the surface treatment of GO.
Moreover, the reaction kinetics for the Epoxy/DDM/Additive ternary system during the cure was measured by differential scanning calorimetry (DSC). Finally, based on the Takayanagi mechanical models, the glass transition temperature in each region of the cured samples for Epoxy/DDM/special additive ternary system has been measured by dynamic mechanical analysis (DMA).
Finally, the effects of additives synthesized, such as, GO, sg-GO, TRGO, and sg-TRGO, on the volume shrinkage, mechanical properties, thermal and electrical conductivities for the Epoxy/DDM/Additive ternary systems after the cure have also been investigated.
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