本實驗以四乙氧基矽烷(TEOS)在鹼性環境中反應合成奈米級之玻璃薄膜，並使用美耐皿海棉為基材，接著以浸塗法(Dip-Coating)使奈米級玻璃包覆在海綿表面上，再以射頻磁控濺鍍(RF reactive magnetron sputtering)系統來沉積鋯基金屬玻璃於海綿表面形成薄膜，最後利用萬能拉伸機的壓縮測試及自製的吸震測試對濺鍍了不同時間的金屬玻璃海棉進行機械性質的探討。
藉由SEM觀察發現本實驗所合成之二氧化矽均勻貼附在海綿表面形成矽薄膜，改變了基材的熱穩定性及表面能。觀察經由鍍膜之海棉，可發現鍍膜時間2小時其金屬玻璃薄膜會沉積滿厚度為3mm的美耐皿海棉。再利用壓縮測試分別觀測濺鍍時間為2、4、6、8、10小時的海綿，發現在固定間距對應的最大力量及彈性係數變化依序為0.86、1.02、1.16、1.55、1.64Kg及0.103、0.12、0.159、0.164、0.176MPa，皆有高度的正相關。而在吸震測試中的第一次反彈高度依序為3.25、3.02、2.69、2.41、2.02公分，證明吸震性能有提升的趨勢。此外，將鍍了金屬玻璃薄膜與鍍了金屬薄膜之海棉以相同條件進行對比測試，在比較濺鍍時間為2、4、6小時的金屬薄膜發現其最大力量及彈性係數依序為0.49、0.44、0.42Kgf及0.068、0.052、0.027MPa，鍍了金屬薄膜的海綿的機械強度反而隨著鍍膜時間增加而呈負相關。本研究以設計高強度、高韌性與低成本的金屬玻璃薄膜於多孔高分子海綿上，做為緩衝材料對於各領域是具備高度發展潛力的。
關鍵字: 海綿、金屬玻璃薄膜

In this experiment, tetraethoxy decane (TEOS) was reacted in an alkaline environment to synthesize a nano-grade glass film, and the melamine sponge was used as a substrate, followed by dip-coating to make the nano-grade. The glass is coated on the surface of the sponge, and the RF reactive magnetron sputtering system is used to deposit the zirconium-based metallic glass to form a film on the surface of the sponge. Finally, the compression test of the universal stretching machine and the self-made shock absorption test are used for the sputtering. Metallic sponges plated at different times were used to investigate the mechanical properties.
It was found by SEM observation that the cerium oxide synthesized in this experiment was uniformly attached to the surface of the sponge to form a ruthenium film, which changed the thermal stability and surface energy of the substrate. Observing the sponge through the coating, it can be found that the metal glass film is deposited with a thickness of 3 mm of melamine sponge for 2 hours. The sponges were used to observe the sponges with a sputtering time of 2, 4, 6, 8, and 10 hours. The maximum strength and modulus of elasticity corresponding to the fixed spacing were found to be 0.86, 1.02, 1.16, 1.55, 1.64Kg, and 0.103, respectively. 0.12, 0.159, 0.164, 0.176 MPa, all have a high positive correlation. In the shock absorption test, the first rebound height is 3.25, 3.02, 2.69, 2.41, 2.02 cm, which proves that the shock absorption performance has an increasing trend. In addition, the metallic glass film and the metallic filmed sponge were tested under the same conditions. The maximum strength and elastic coefficient of the metal film with a sputtering time of 2, 4, and 6 hours were found to be 0.49. 0.44, 0.42Kgf and 0.068, 0.052, 0.027MPa, the mechanical strength of the sponge coated with the metal film is negatively correlated with the increase of the coating time. In this study, high-strength, high-toughness and low-cost metal glass films were designed on porous polymer sponges. As a cushioning material, it has high development potential in various fields.
Keywords: sponge, metallic glass film

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