研究生: |
李貝薿 Pei-Ni Li |
---|---|
論文名稱: |
水相AgInS2與AgInSe2量子點合成及量子點敏化太陽能電池應用 Aqueous synthesis of AgInS2 and AgInSe2 quantum dots for quantum dots-sensitized solar cell |
指導教授: |
張家耀
Jia-Yaw Chang |
口試委員: |
李昇隆
Shern-Long Lee 何郡軒 Jinn-Hsuan Ho |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2017 |
畢業學年度: | 105 |
語文別: | 中文 |
論文頁數: | 98 |
中文關鍵詞: | 量子點敏化太陽能電池 、AgInS2量子點 、AgInSe2量子點 、水相合成 |
外文關鍵詞: | Quantum dots-sensitized solar cell, AgInS2 quantum dots, AgInSe2 quantum dots, Aqueous synthesis |
相關次數: | 點閱:451 下載:1 |
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本研究藉由微波輔助法預先合成水相不含重金屬離子之AgInS2 (AIS)與AgInSe2 (AISe)量子點,反應時間僅需10分鐘,利用微波可瞬時升溫至反應溫度的特性,在定溫均勻受熱環境一步合成出量子點,不需再經配位體置換之表面改質,製程簡易且快速。
將TiO2光電極浸泡於量子點敏化溶液,接著用連續離子吸附與反應沉積ZnS鈍化層,分別與Cu2S或CuS背電極組裝成電池元件,使用AIS量子點之電池元件光電轉換效率為2.72% (Jsc = 9.75 mA/cm2, Voc = 432 mV, FF = 64.6%),而使用L-Glutathione (GSH)做為包覆劑製成的AISe量子點並透過TiCl4化學沉積前處理程序之電池元件光電轉換效率達到5.68% (Jsc = 16.86 mA/cm2, Voc = 664 mV, FF = 50.8%)。將不同雙功能分子Thioglycolic acid (TGA)、Mercaptopropionic acid (MPA)與GSH做為包覆劑製成的AISe量子點電池元件進行電化學分析,證實以GSH所製備而成的AISe量子點與TiO2間有較長的電子生命週期與較短的電子傳遞時間,因此具有最佳的光電轉換效率。
In this study, we synthesized heavy metal-free AgInS2 (AIS) and AgInSe2 (AISe) quantum dots (QDs) via the microwave-assisted synthetic route within 10 min in an aqueous-phase system. Under microwave irradiation, precursor molecules directly absorb the microwave energy and heats up more efficiently. The synthesis process is simple, rapid and effective without further surface modification of ligand exchange.
The quantum dot-sensitized solar cells (QDSSCs) were constructed with QDs and co-adsorbent deposited on TiO2 film. ZnS deposited as passivation layer by successive ionic layer adsorption and reaction (SILAR). Counter electrode made from Cu2S or CuS components assembly with photoelectrode to become the cell component. The performance showed that AIS QDSSC had a power conversion efficiency of 2.72% (Jsc = 9.75 mA/cm2, Voc = 432 mV, FF = 64.6%) under full one sun irradiation (AM 1.5 G, 100 mW/cm2). Further, the performance showed that the GSH-capped AISe QDSSC with TiCl4 treatment exhibited an excellent power conversion efficiency of 5.68% (Jsc = 16.86 mA/cm2, Voc = 664 mV, FF = 50.8%) under full one sun irradiation. This is because GSH-capped AISe QDs allowed for more efficient electron transport and less charge recombination than did the TGA-capped AISe and MPA-capped AISe QDs, as revealed by the electrochemical impedance spectroscopy (EIS) and intensity-modulated photocurrent/photovoltage spectroscopy (IMPS/IMVS) measurements.
[1]J. P. Holdren, Science, 2008, 319, 424–434.
[2]M. Grätzel, Nature, 2001, 414, 338–344.
[3]E. Centurioni and D. Iencinella, IEEE Electron Device Lett., 2003, 24, 177–179.
[4]O. Schultz, S. W. Glunz and G. P. Willeke, Prog. Photovolt. Res. Appl., 2004, 12, 553–558.
[5]K. Masuko, M. Shigematsu, T. Hashiguchi, D. Fujishima, M. Kai, N. Yoshimura, T. Yamaguchi, Y. Ichihashi, T. Mishima, N. Matsubara, T. Yamanishi, T. Takahama, M. Taguchi, E. Maruyama and S. Okamoto, IEEE J. Photovoltaics, 2014, 4, 1433–1435.
[6]I. Repins, M. A. Contreras, B. Egaas, C. DeHart, J. Scharf, C. L. Perkins, B. To and R. Noufi, Progr. Photovolt.: Res. Appl., 2008, 16, 235–239.
[7]A. G. Aberle, Thin Solid Films, 2009, 517, 4706–4710.
[8]M. A. Green, K. Emery, Y. Hishikawa, W. Warta and E. D. Dunlop, Prog. Photovolt: Res. Appl., 2014, 22, 701–710.
[9]H. Tsubomura, M. Matsumura, Y. Nomura and T. Amamiya, Nature, 1976, 261, 402–403.
[10]B. O'Regan and M. Grätzel, Nature, 1991, 353, 737–740.
[11]E. Groeneveld, Synthesis and optical spectroscopy of (hetero)-nanocrystals. Ph.D. Thesis, Utrecht University, 2012.
[12]G. Sun, The Intersubband Approach to Si-based Lasers, Advances in Lasers and Electro Optics, Nelson Costa and Adolfo Cartaxo (Ed.), 2010.
[13]Y. Wang and N. Herron, J. Phy. Chem., 1991, 95, 525–532.
[14]R. Koole, E. Groeneveld, D. Vanmaekelbergh, A. Meijerink and C. de Mello Donegá, Size Effects on Semiconductor Nanoparticles. In Nanoparticles: Workhorses of Nanoscience Nanoparticles. Springer Berlin Heidelberg (Ed.), 2014; pp 13−51.
[15]W. R. Algar, K. Susumu, J. B. Delehanty and I. L. Medintz, Anal. Chem., 2011, 83, 8826–8837.
[16]R. D. Schaller and V. I. Klimov, Phys. Rev. Lett., 2004, 92, 186601.
[17]A. J. Nozik, Inorg. Chem., 2005, 44, 6893–6899.
[18]T. Takagahara and K. Takeda, Phys. Review B, 1992, 46, 15578.
[19]S. Kan, T. Mokari, E. Rothenberg and U. Banin, Nat. Mater., 2003, 2, 155–158.
[20]A. L. Rogach, T. Franzl, T. A. Klar, J. Feldmann, N. Gaponik, V. Lesnyak, A. Shavel, A. Eychmüller, Y. P. Rakovich and J. F. Donegan, J. Phys. Chem. C, 2007, 111, 14628–14637.
[21]A. J. Nozik, Chem. Phys. Lett., 2008, 457, 3–11.
[22]G. Smestad, C. Bignozzi and R. Argazzi, Sol. Energy Mater. Sol. Cells, 1994, 32, 259–272.
[23]R. D. Schaller, V. M. Agranovich and V. I. Klimov, Nat. Phys., 2005, 1, 189–194.
[24]A. J. Nozik, M. C. Beard, J. M. Luther, M. Law, R. J. Ellingson and J. C. Johnson, Chem. Rev., 2010, 110, 6873–6890.
[25]O. E. Semonin, J. M. Luther, S. Choi, H.-Y. Chen, J. Gao, A. J. Nozik and M. C. Beard, Science, 2011, 334, 1530–1533.
[26]M. C. Hanna and A. J. Nozik, J. Appl. Phys., 2006, 100, 074510.
[27]S. Rühle, M. Shalom and A. Zaban, ChemPhysChem, 2010, 11, 2290–2304.
[28]I. Hod and A. Zaban, Langmuir, 2014, 30, 7264–7273.
[29]P. V. Kamat, J. A. Christians and J. G. Radich, Langmuir, 2014, 30, 5716–5725.
[30]E. Shanthi, A. Banerjee, V. Dutta and K. L. Chopra, J. Appl. Phys., 1982, 53, 1615–1621.
[31]J. C. Manifacier, M. De Murcia, J. P. Fillard and E. Vicario, Thin Solid Films, 1977, 41, 127–135.
[32]R. G. Gordon, MRS Bull., 2000, 25, 52–57.
[33]J. Desilvestro, M. Grätzel, L. Kavan, J. Moser and J. Augustynski, J. Am. Chem. Soc., 1985, 107, 2988–2990.
[34]G. Redmond, D. Fitzmaurice and M. Grätzel, Chem. Mater., 1994, 6, 686–691.
[35]I. Bedja, S. Hotchandani and P. V. Kamat, J. Phy. Chem., 1994, 98, 4133–4140.
[36]L. Li, X. Yang, J. Zhao, J. Gao, A. Hagfeldt and L. Sun, J. Mater. Chem., 2011, 21, 5573–5575.
[37]L. Li, X. Yang, J. Gao, H. Tian, J. Zhao, A. Hagfeldt and L. Sun, J. Am. Chem. Soc., 2011, 133, 8458–8460.
[38]J. H. Bang and P. V. Kamat, ACS Nano, 2009, 3, 1467–1476.
[39]Z. Du, H. Zhang, H. Bao and X. Zhong, J. Mater. Chem. A, 2014, 2, 13033–13040.
[40]Q. Zhang, X. Guo, X. Huang, S. Huang, D. Li, Y. Luo, Q. Shen, T. Toyoda and Q. Meng, Phys. Chem. Chem. Phys., 2011, 13, 4659–4667.
[41]S. Günes and N. S. Sariciftci, Inorg. Chim. Acta, 2008, 361, 581–588.
[42]H. A. Greijer, J. Lindgren and A. Hagfeldt, J. Photochem. Photobiol., A, 2004, 164, 23–27.
[43]A. Hagfeldt and M. Grätzel, Acc. Chem. Res., 2000, 33, 269–277.
[44]M. Grätzel, Inorg. Chem., 2005, 44, 6841–6851.
[45]S.-W. Rhee and W. Kwon, Korean J. Chem. Eng., 2011, 28, 1481–1494.
[46]S. D. Sung, I. Lim, P. Kang, C. Lee and W. I. Lee, Chem. Commun., 2013, 49, 6054–6056.
[47]X. Peng, M. C. Schlamp, A. V. Kadavanich and A. P. Alivisatos, J. Am. Chem. Soc., 1997, 119, 7019–7029.
[48]Y. Bai, C. Han, X. Chen, H. Yu, X. Zong, Z. Li and L. Wang, Nano Energy, 2015, 13, 609–619.
[49]S. Jiao, Q. Shen, I. Mora-Seró, J. Wang, Z. Pan, K. Zhao, Y. Kuga, X. Zhong and J. Bisquert, ACS Nano, 2015, 9, 908–915.
[50]S. Jiao, J. Wang, Q. Shen, Y. Li and X. Zhong, J. Mater. Chem. A, 2016, 4, 7214–7221.
[51]Z. Pan, K. Zhao, J. Wang, H. Zhang, Y. Feng and X. Zhong, ACS Nano, 2013, 7, 5215–5222.
[52]J. Wang, Y. Li, Q. Shen, T. Izuishi, Z. Pan, K. Zhao and X. Zhong, J. Mater. Chem. A, 2016, 4, 877–886.
[53]G. Hodes, J. Phys. Chem. C, 2008, 112, 17778–17787.
[54]V. Chakrapani, D. Baker and P. V. Kamat, J. Am. Chem. Soc., 2011, 133, 9607–9615.
[55]G. Wolfbauer, A. M. Bond, J. C. Eklund and D. R. MacFarlane, Sol. Energy Mater. Sol. Cells, 2001, 70, 85–101.
[56]D. Sharma, R. Jha and S. Kumar, Sol. Energy Mater. Sol. Cells, 2016, 155, 294–322.
[57]G. Hodes, J. Manassen and D. Cahen, J. Electrochem. Soc., 1980, 127, 544–549.
[58]X. Jiang, Y. Xie, J. Lu, W. He, L. Zhu and Y. Qian, J. Mater. Chem., 2000, 10, 2193–2196.
[59]C. S. Kim, S. H. Choi and J. H. Bang, ACS Appl. Mater. Interfaces, 2014, 6, 22078–22087.
[60]S. S. Kalanur, S. Y. Chae and O. S. Joo, Electrochim. Acta, 2013, 103, 91–95.
[61]S. A. Haque, E. Palomares, B. M. Cho, A. N. M. Green, N. Hirata, D. R. Klug and J. R. Durrant, J. Am. Chem. Soc., 2005, 127, 3456–3462.
[62]I. Hod, V. González-Pedro, Z. Tachan, F. Fabregat-Santiago, I. Mora-Seró, J. Bisquert and A. Zaban, J. Phys. Chem. Lett., 2011, 2, 3032–3035.
[63]J. Kim, H. Choi, C. Nahm, C. Kim, S. Nam, S. Kang, D.-R. Jung, J. I. Kim, J. Kang and B. Park, J. Power Sources, 2012, 220, 108–113.
[64]S.-M. Yang, C.-H. Huang, J. Zhai, Z.-S. Wang and L. Jiang, J. Mater. Chem., 2002, 12, 1459–1464.
[65]D. R. Pernik, K. Tvrdy, J. G. Radich and P. V. Kamat, J. Phys. Chem. C, 2011, 115, 13511–13519.
[66]W. Li and X. Zhong, J. Phys. Chem. Lett., 2015, 6, 796–806.
[67]R. S. Mane and C. D. Lokhande, Mater. Chem. Phys., 2000, 65, 1–31.
[68]J. M. Doña and J. Herrero, J. Electrochem. Soc., 1997, 144, 4081–4091.
[69]Q. Shen, J. Kobayashi, L. J. Diguna and T. Toyoda, J. Appl. Phys., 2008, 103, 084304.
[70]A. L. Rogach, A. Kornowski, M. Gao, A. Eychmüller and H.Weller, J. Phys. Chem. B, 1999, 103 , 3065–3069.
[71]L. Manna, D. J. Milliron, A. Meisel, E. C. Scher and A. P. Alivisatos, Nat. Mater., 2003, 2, 382–385.
[72]U. Tohgha, K. Varga and M. Balaz, Chem. Commun., 2013, 49, 1844–1846.
[73]S. Giménez, I. Mora-Seró, L. Macor, N. Guijarro, T. Lana-Villarreal, R. Gómez, L. J. Diguna, Q. Shen, T. Toyoda and J. Bisquert, Nanotechnology, 2009, 20, 295204.
[74]F. Sauvage, C. Davoisne, L. Philippe and J. Elias, Nanotechnology, 2012, 23, 395401.
[75]I. Robel, V. Subramanian, M. Kuno and P. V. Kamat, J. Am. Chem. Soc., 2006, 128, 2385–2393.
[76]K. Zhao, Z. Pan, I. Mora-Seró, E. Cánovas, H. Wang, Y. Song, X. Gong, J. Wang, M. Bonn, J. Bisquert and X. Zhong, J. Am. Chem. Soc., 2015, 137, 5602–5609.
[77]J. Du, Z. Du, J.-S. Hu, Z. Pan, Q. Shen, J. Sun, D. Long, H. Dong, L. Sun, X. Zhong and L.-J. Wan, J. Am. Chem. Soc., 2016, 138, 4201–4209.
[78]S. Jiao, J. Du, Z. Du, D. Long, W. Jiang, Z. Pan, Y. Li and X. Zhong, J. Phys. Chem. Lett., 2017, 8, 559–564.
[79]A. Sahasrabudhe and S. Bhattacharyya, Chem. Mater., 2015, 27, 4848–4859.
[80]J.-Y. Chang, C.-H. Li, Y.-H. Chiang, C.-H. Chen and P.-N. Li, ACS Appl. Mater. Interfaces, 2016, 8, 18878–18890.
[81]P. Boolchand and W. J. Bresser, Nature, 2001, 410, 1070–1073.
[82]B. Gates, Y. Wu, Y. Yin, P. Yang and Y. Xia, J. Am. Chem. Soc., 2001, 123, 11500–11501.
[83]U. Jeong, P. H. C. Camargo, Y. H. Lee and Y. Xia, J. Mater. Chem., 2006, 16, 3893–3897.
[84]R. E. Bailey and S. Nie, J. Am. Chem. Soc., 2003, 125, 7100–7106.
[85]X. Zhong, Y. Feng, W. Knoll and M. Han, J. Am. Chem. Soc., 2003, 125, 13559–13563.
[86]L. A. Swafford, L. A. Weigand, M. J. Bowers II, J. R. McBride, J. L. Rapaport, T. L. Watt, S. K. Dixit, L. C. Feldman and S. J. Rosenthal, J. Am. Chem. Soc., 2006, 128, 12299–12306.
[87]A. Tubtimtae, K.-L. Wu, H.-Y. Tung, M.-W. Lee and G. J. Wang, Electrochem. Commun., 2010, 12, 1158–1160.
[88]J.-J. Wu, R.-C. Chang, D.-W. Chen and C.-T. Wu, Nanoscale, 2012, 4, 1368–1372.
[89]I. Hwang and K. Yong, ChemPhysChem, 2013, 14, 364–368.
[90]B. Liu, D. Wang, Y. Zhang, H. Fan, Y. Lin, T. Jiang and T. Xie, Dalton Trans., 2013, 42, 2232–2237.
[91]W. J. Mir, A. Swarnkar, R. Sharma, A. Katti, K. V. Adarsh and A. Nag, J. Phys. Chem. Lett., 2015, 6, 3915–3922.
[92]I. Hwang, M. Seol, H. Kim and K. Yong, Appl. Phys. Lett., 2013, 103, 023902.
[93]A. Tubtimtae, M.-W. Lee and G.-J. Wang, J. Power Sources, 2011, 196, 6603–6608.
[94]K.-C. Cheng, W.-C. Law, K.-T. Yong, J. S. Nevins, D. F. Watson, H.-P. Ho and P. N. Prasad, Chem. Phys. Lett., 2011, 515, 254–257.
[95]K. P. Kadlag, P. Patil, M. J. Rao, S. Datta and A. Nag, CrystEngComm, 2014, 16, 3605–3612.
[96]C. Cai, L. Zhai, Y. Ma, C. Zou, L. Zhang, Y. Yang and S. Huang, J. Power Sources, 2017, 341, 11–18.
[97]T. Sasamura, K. Okazaki, A. Kudo, S. Kuwabata and T. Torimoto, RSC Adv., 2012, 2, 552–559.
[98]Y. Wang, Q. Zhang, Y. Li and H. Wang, Nanoscale, 2015, 7, 6185–6192.
[99]M. Jagadeeswararao, A. Swarnkar, G. B. Markad and A. Nag, J. Phys. Chem. C, 2016, 120, 19461–19469.
[100]S. M. Kobosko, D. H. Jara and P. V. Kamat, ACS Appl. Mater.Interfaces, DOI: 10.1021/acsami.6b14604.
[101]L.-C. Chen, Y.-C. Ho, R.-Y. Yang, J.-H. Chen and C.-M. Huang, App. Surf. Sci., 2012, 258, 6558–6563.
[102]T. Kameyama, Y. Douke, H. Shibakawa, M. Kawaraya, H. Segawa, S. Kuwabata and T. Torimoto, J. Phys. Chem. C, 2014, 118, 29517–29524.
[103]Z.-C. Wang, S.-H. Xu, C. Wang, L. Zhu, F. Bo, X.-Y. Lin, Z.-Y. Wang and Y.-P. Cui, RSC Adv., 2015, 5, 46186–46191.
[104]G. Halder and S. Bhattacharyya, J. Mater. Chem. A, 2017, 5, 11746–11755.
[105]C. Ji, Y. Zhang, X. Zhang, P. Wang, H. Shen, W. Gao, Y. Wang and W. W. Yu, Nanotechnology, 2017, 28, 065602.
[106]Y.-R. Ho and M.-W. Lee, Electrochem. Commun., 2013, 26, 48−51.
[107]W.-C. Yang and M.-W. Lee, J. Electrochem. Soc., 2014, 161, H92−H96.
[108]P.-C. Huang, W.-C. Yang and M.-W. Lee, J. Phys. Chem. C, 2013, 117, 18308–18314.
[109]S. Zhou, J. Yang, W. Li, Q. Jiang, Y. Luo, D. Zhang, Z. Zhou and X. Li, J. Electrochem. Soc., 2016, 163, D63−D67.
[110]I. Bilecka and M. Niederberger, Nanoscale, 2010, 2, 1358–1374.
[111]M. Baghbanzadeh, L. Carbone, P. D. Cozzoli and C. O. Kappe, Angew. Chem., Int. Ed., 2011, 50, 11312–11359.
[112]M. B. Gawande, S. N. Shelke, R. Zboril and R. S. Varma, Acc. Chem. Res., 2014, 47, 1338–1348.
[113]Y.-J. Zhu and F. Chen, Chem. Rev., 2014, 114, 6462–6555.
[114]R. G. Pearson, J. Chem. Educ., 1968, 45, 581–587.
[115]J. Tauc and A. Menth, J. Non-Cryst. Solids, 1972, 8–10, 569–585.
[116]J. L. Shay, B. Tell, H. M. Kasper and L. M. Schiavone, Phys. Rev. B, 1973, 7, 4485–4490.
[117]J. L. Shay, B. Tell, L. M. Schiavone, H. M. Kasper and F. Thiel, Phys. Rev. B, 1974, 9, 1719–1723.
[118]P. Dey, J. Bible, S. Datta, S. Broderick, J. Jasinski, M. Sunkara, M. Menon and K. Rajan, Comput. Mater. Sci., 2014, 83, 185–195.
[119]V. Chakrapani, D. Baker and P. V. Kamat, J. Am. Chem. Soc., 2011, 133, 9607–9615.
[120]R. Xie, M. Rutherford and X. Peng, J. Am. Chem. Soc., 2009, 131, 5691–5697.
[121]S. Sadhu and A. Patra, J. Phys. Chem. C, 2012, 116, 15167–15173.
[122]W.-D. Xiang, H.-L. Yang, X.-J. Liang, J.-S. Zhong, J. Wang, L. Luo and C.-P. Xie, J. Mater. Chem. C, 2013, 1, 2014–2020.
[123]S. Ito, P. Liska, P. Comte, R. Charvet, P. Péchy, U. Bach, L. Schmidt-Mende, S. M. Zakeeruddin, A. Kay, M. K. Nazeeruddin and M. Gräetzel, Chem. Commun., 2005, 4351–4353.
[124]B. C. O'Regan, J. R. Durrant, P. M. Sommeling and N. J. Bakker, J. Phys. Chem. C, 2007, 111, 14001–14010.
[125]Z. Du, H. Zhang, H. Bao and X. Zhong, J. Mater. Chem. A, 2014, 2, 13033–13040.
[126]N. Guijarro, Q. Shen, S. Giménez, I. Mora-Seró, J. Bisquert, T. Lana-Villarreal, T. Toyoda and R. Gómez, J. Phys. Chem. C, 2010, 114, 22352–22360.
[127]S. M. Farkhani and A. Valizadeh, IET Nanobiotechnol., 2014, 8, 59–76.
[128]S. S. M. Rodrigues, D. S. M. Ribeiro, J. X. Soares, M. L. C. Passos, M. L. M. F. S. Saraiva and J. L. M. Santos, Coord. Chem. Rev., 2017, 330, 127–143.