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研究生: 康哲瑋
Che-Wei Kang
論文名稱: 環氧樹脂之韌化行為及加速老化之研究
A Study on Toughening Behavior and Accelerated Aging of Epoxy Composite
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 邱智瑋
Chih-Wei Chiu
賴秋君
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2015
畢業學年度: 103
語文別: 中文
論文頁數: 88
中文關鍵詞: 環氧樹脂核殼粒子增韌加速老化
外文關鍵詞: epoxy resin, core-shell rubber, toughen, accelerated Aging
相關次數: 點閱:263下載:2
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本研究主要分為兩部分,第一個部分是混摻(polymer blend)環氧樹脂(epoxy resin)、壓克力核殼粒子(PMMA Core-shell powder)以達到增韌效果,改善其耐衝擊性。首先以熱示差分析儀(DSC)分析交聯反應速度(curing rate)及加工條件,再以彎曲試驗、硬度試驗、拉伸強度試驗,做一系列對於物理機械強度的探討;接著,以粒子分散性分析儀(LUMICIZER)及粒子界面特性分析儀(Acorn Area)探討粒子在EPOXY溶液裡的穩定性及分散性;在以熱動態機械分析儀(DMA)可得知其相容性,以熱重損失分析(TGA)探討其耐熱性的變化,透過IZOD衝擊試驗確認衝擊性能的改變,最後再利用掃描式電子顯微鏡觀察其斷面斷裂情形觀察其增韌機制。
第二部分,環氧樹脂/砂漿複合材透過加速老化之研究去測量其壽命,將成型好的拉伸試片與彎取試片分別放置再三個不同溫度(95℃,180℃,200℃)的烘箱裡,每隔一段時間取出,測量其拉伸強度與彎曲強度的變化並推測其壽命。


There are two subjects in this research.In the first part,we mix up epoxy resin with the PMMA core-shell powder to toughen it and improve its impact strength.First,we used dynamic scanning calorimetry (DSC) to determine processing time and curing rate.With doing the bending test,hardness test, tensile test,we can know its mechnical properties.After that,we used Lumicizer and Acorn area to testify the stability and dispersibility of the powder in Epoxy.And through doing Dynamic Mechanical Analysis(DMA),we can investigate its miscibility.To know the quality of the thermal resistance,we use thermal gravimetric analysis(TGA) to test it.After that,doing the izod impact test can help us check wheather it really toughens or not. Finally,we observe phase separation and toughing mechanism by scanning electronic microscopy (SEM).
In the second part,we measure the effective duration of epoxy/sand composite through accelerating aging test.We put the testing samples in the oven with 3 different temperature(95℃,180℃,200℃).Take them out every once in a while and do the tensile and bending test.Through the test,we can infer the effective duration of the epoxy/sand composite.

摘要I AbstractII 誌謝III 目錄IV 圖目錄VI 表目錄VIII 第一章 緒論1 1.1 研究動機1 1.2 環氧樹脂之介紹2 1.2.1 環氧樹脂之緣起2 1.2.2 環氧樹脂之定義3 1.2.3 環氧樹脂之種類與特徵5 1.2.4 環氧樹脂的硬化反應與反應機構7 1.2.5 環氧樹脂的增韌改質劑11 1.2.6 環氧樹脂的增韌理論14 1.3 核殼粒子之介紹19 1.3.1 核殼粒子之定義19 1.3.2 核殼粒子之製備19 1.3.3 核殼粒子增韌環氧樹脂19 1.4 文獻回顧21 參考文獻24 第二章 Epoxy/壓克力核殼粒子之增韌27 2.1前言28 2.2實驗29 2.2.1 實驗流程29 2.2.2 實驗材料30 2.2.3 實驗配方30 2.2.4 試片製作31 2.3儀器原理及測定方法32 2.3.1 傅立葉轉換紅外線光譜儀32 2.3.2 熱示差掃描量熱儀32 2.3.3 熱重損失分析儀33 2.3.4 粒子分散性分析儀34 2.3.5 粒子界面特性分析儀35 2.3.6 應力與應變35 2.3.7 硬度37 2.3.8 衝擊試驗37 2.3.9 三點彎曲試驗38 2.3.10 熱動態機械分析39 2.3.11 掃描式電子顯微鏡39 2.4結果與討論40 2.4.1 傅立葉轉換紅外線光譜儀40 2.4.2 熱示差掃描量熱儀43 2.4.3 熱重損失分析儀48 2.4.4 粒子分散性分析儀52 2.4.5 粒子界面特性分析儀55 2.4.6 應力與應變56 2.4.7 三點彎曲試驗57 2.4.8 硬度60 2.4.9 衝擊試驗62 2.4.10 熱動態機械分析64 2.4.11 掃描式電子顯微鏡67 2.5 結論70 參考文獻70 第三章 環氧樹脂/砂漿複合材加速老化之研究71 3.1 前言72 3.2 實驗73 3.2.1實驗材料73 瑞肯材料科技有限公司73 瑞肯材料科技有限公司73 瑞肯材料科技有限公司73 3.2.2儀器原理及測定方法73 3.3結果與討論76 3.3.2拉伸強度測試壽命76 3.3.3三點彎曲測試壽命81 3.4 結論86 第四章 總結論87

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