本文之目的，乃探討四種特用添加劑，分別為：(1)聚酯酸乙烯(poly(vinyl acetate)，PVAc)、(2)聚胺基甲酸酯(polycaprol- actone ，PCL)型LPA、(3)反應型微膠顆粒(reactive microgels)型LPA及(4)蒙特納石黏土(montmorillonite clay，MMT)，其對苯乙烯/不飽合樹脂/特用添加劑三成份系其聚合固化後成品之微孔洞生成、微觀型態結構、抗體積收縮特性、內部可染色性及機械性質之影響。實驗之結果，吾人將配合苯乙烯/不飽和聚酯樹脂/特用添加劑三成份系統之相容性，固化樣品破壞面之微觀結構、及微孔洞體積分率等因素加以解釋。

The effect of four series of additives, including(1)poly(vinyl acetate) (PVAc), (2)polycaprolactone(PCL) low-profile additives, (3)reactive microgel particle, (4) montmorillonite clay, on the microvoid formation, morphology, volume shrinkage characteristics,internal pigmentability and mechanical properties for the styrene/unsaturated polyester/additive ternary systems after the cure were investigated. The experimental results have been explained by phase characteristic of the styrene/ unsaturated poly- ester /additive ternary system before tht cure, cured sample morph- ology and volume fraction of microvoid generated during the cure.

1.E.J. Bartkus and C.H Kroekel, Appl.Polym.Symp.,15, 113(1970)
2.K.E.Atkins,in”Sheet Molding Compound :Science and Technology”.Ed., H.G. Kia, Hanser Publishers, New York,1993, Ch4.
3.V.A. Pattison, R.R. Hindersinn and W.T. Schwartz,J. Appl.Polym.Sci., 18,2763(1974)
4.V.A. Pattison, R.R. Hindersinn and W.T. Schwartz,J. Appl.Polym.Sci., 19,3045(1975)
5.L. Suspene, D. Fourquier and Y.S. Yang, Polymer,32,1593 (1991)
6.C.P. Hsu, M. Kinkelaar, P. Hu and L.J. Lee. Polym.Eng.Sci., 31, 1450 (1991)
7.Y.J Huang and C.M. Liang, Polymer, 37,401(1996)
8.Y.J. Huang, C.J. Chu, and J.P. Dong, J. Appl. Polym. Sci., 78, 543 (2000)
9.Y.J. Huang, T.S. Chen, J.G. Huang, and F.H. Lee,J.Appl. Polym. Sci., 89, 3336(2003)
10.J.P. Dong, J.G. Huang, F.H. Lee, J.W. Roan,and Y.J. Huang, J.Appl. Polym.Sci.,91,3388(2004)
11.K.E. Atkins and G.C. Rex. 48th Annual Conference, Composite Institute. SPI, Session 6-D (Feb, 8-11,1993)
12.K.E. Atkins and G.C. Rex. , C.G. Reid, R.L. Seats and R.C. Candy, 47th Annual Conference,Composite Institute. SPI, Session 7-D (Feb, 3-6,1992)
13.Y.J. Huang and C.C. Su,J. Appl.Polym.Sci., 55,323(1995)
14.P.W.K. Lam,Polym.Eng. Sci., 29,609(1989)
15.C.B. Bucknall, I.K. Partridge, and M.J. Phillips, Polymer, 32,786(1991)
16.Y.J. Huang and J.C. Horng, Polymer,39,3683(1998)
17.Y.J.Huang and W .C.Jiang, Polymer,39,6631(1998)
18.Y.J. Huang and L.D.Chen, Polymer ,39,7049(1998)
19.Y.J. Huang ,S.C.Lee, and J.P. Dong, J. Appl. Polym.Sci.,78, 558 (2000)
20.E. Martuscelli, P. Musto, G.. Ragosta, G. Scarinzi, and E. Bertotti, J.Polym.Sci., Part B：Polym.Phys.,31,619(1993)
21.S.B. Pandit, and V.M. Nadkarni,Ind. Eng. Chem. Res.,33, 2778 (1994)
22.The B.F. Goodrich Co., WO93/21274(Oct. 28,1993)
23.Crc for Polymers Pty. Ltd., WO97/43339(Nov. 20,1997)
24.Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, T. Kurauchi, and O. Kamigaito, J.Polym.Sci. Part A：Polym.Chem,31,983(1993)
25.X. Kornmann, L.A. Berglund, J. Sterte, and E.P. Giannelis, Polym. Eng. Sci.,38,1351(1998)
26.D.J. Suh, Y.T. Lim, and O.O. Park, Polymer,41,8557(2000)
27.R.K. Bharadwaj, A.R. Mehrabi, C. Hamilton, C. Trujillo, M. Murga, R. Fan, A.Chavira, and A.K. Thompson, Polymer,43,3699(2002)
28.盧天智，碩士論文，台灣科技大學，1991
29.Y.S. Yang and L.J.Lee, Polymer,29,1793(1998)
30.蘇進成，碩士論文，台灣科技大學，1992
31.林立翔，碩士論文，台灣科技大學，1992
32.K.E.Atkins, in “Polymer Blends” ed., D.R.Paul and S.Newman, Academic Press, New York, Vol.2.(1978)
33.Y.J. Huang and C.C. Su, J. Appl. Polym.Sci.,55,305(1995)
34.Y.J. Huang and C.C. Su, Polymer,35,2397 (1994)
35.Y.J. Huang and T.J. Lu and W. Hwu, Polym. Eng. Sci.,33,1 (1993)
36.T. Mitani, H. Shiraishi, K. Honda and G.E. Owen, 44th Annual Conference Composite Institute,SPI,Session 12-F (Feb. 6-9,1989)
37.M.B.C Park and F.J. Mcgarry, 48th Annual Conference , Composite Institute,SPI,Session 12-F(Feb.6-9,1989)
38.陳立德，碩士論文，台灣科技大學，1996
39.H.J. Sue, E.I. Garciameitin, and D.M. Pickelman, in”Polymer Toughening, Ch. 5”, ed., C.B.Arends, MarcelDekker, New York,1996
40.The Dow Chemical Company, US Patent 4, 778, 851(Oct. 18.1998)
41.J. Y. Qian, R.A. Pearson, V.L. Dimonie, and M.S. El-Aasser, J. Appl. Polym. Sci., 58, 439(1995)
42.K.F. Lin and Y.D. Sheh, J.Appl. Polym. Sci., 69, 2069(1998)
43.K.F. Lin and Y.D. Shieh, J.Appl. Polym. Sci., 70, 2313(1998)
44.P.Hazot, C.Pichot, and A. Maazouz, Macromol. Chem. Phys., 201, 632(2000)
45.W. Funke, R.Kolitz,and W. Straehle, Makromol. Chem. ,180, 2797 (1979).
46.W. Funke, Br. Polym J., 21, 107, (1989).
47.百康奈米科技股份有限公司產品目錄
48.W.E. Worrall, “Clays and Ceramic Raw Materials,” 2nd Ed., Elserier, London, 1986.
49.X. Kornmann,L. A. Berglund*, and J. Sterte, Polymer Engineering And Science,Vol.38, No.8,1351(1998)
50.T. Lan and T. J. Pinnavaia. Chem. Mater., 6, 2216(1994)
51.J.Roe,”Methods of X-Ray and Neutron Scattering in Polymer Science,” Oxford University Press , University , New York, 2000.\
52.J. Als-Nielsen, and D. McMorrow,”Elements of Modern X-Ray Physics,”Wiley, New York, 2001.
53.邱聖貴，碩士論文，台灣科技大學，2002
54.梁景冠，碩士論文，台灣科技大學，2003
55.陳紹偉，碩士論文，台灣科技大學，2004