氧化鋁與316不鏽鋼接合之研究｜國立臺灣科技大學博碩士論文系統

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研究生：	葉凱庭 Kai-ting Yeh
論文名稱：	氧化鋁與316不鏽鋼接合之研究 study of alumina/316SS join
指導教授：	郭東昊 Dong-hau Kuo
口試委員:	薛人愷 Ren-kae Shiue 韋文誠 Wen-Cheng, Wei 蔡大翔 Dah-Shyang Tsai
學位類別：	碩士 Master
系所名稱：	應用科技學院 - 應用科技研究所 Graduate Institute of Applied Science and Technology
論文出版年：	2010
畢業學年度：	98
語文別：	中文
論文頁數：	137
中文關鍵詞：	鉬錳製程、活性硬銲、金屬與陶瓷的接合
外文關鍵詞：	moly-manganese process, active metal braze, brazing
相關次數：	點閱：156 下載：3
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陶瓷材料具有耐高溫、耐酸鹼、高硬度等特性，但由於本質脆性使其在應用上有相當的難度，透過與金屬接合，藉由金屬的延展性來減少其應用上的不可靠性，才能擴展陶瓷的應用面。陶瓷與金屬接合方法計有鉬錳製程、活性硬銲及軟銲，以上除了軟銲之外，其餘皆需在900℃以上的高溫才可以有效接合陶瓷與金屬。
　　本研究分別進行了兩個方向，一是鉬錳製程，另一是活性硬銲接合，皆用來將氧化鋁與316不鏽鋼接合在一起；由於以往的鉬錳製程反應所需溫度極高，為了降低其反應溫度，將其製程改為兩段式製程外，也在其中加入鮮少會添加之金屬鎳，以此降低反應溫度。活性硬銲接合氧化鋁與316不鏽鋼，係在陶瓷與金屬之間夾上一夾層金屬來達到降低殘留應力的效果，避免因熱膨脹係數相差太大導致殘留應力過大，使氧化鋁端出現裂痕與缺陷導致接合效果不好。
　　實驗結果顯示，二階段的鉬錳製程於1250℃在氧化鋁基板上進行反應層反應，再於1250℃於反應層上進行鉬錳層反應，最後於800℃下硬銲接合至316不鏽鋼。SEM觀察後證明此方法是可以有效將氧化鋁與316不鏽鋼接合且使其反應溫度可以降低到1250℃。當使用Kovar合金與金屬鎳網當夾層金屬，於900℃持溫5分鐘硬銲接合氧化鋁與316不鏽鋼，其接合強度分別185與大於385MPa。

Ceramic materials have high melting temperature and are brittle and corrosion-resistant, but their brittleness has limited their wide applications in industries. Ceramic-to-metal joining is the major approach to extend the ceramic applications. The methods of joining metal and ceramic involve the moly-manganese process、active metal braze, and soldering. Except for soldering, moly-manganese process and active metal braze need to be processed over 900℃.
The moly-manganese process and active metal braze were used in this study to bond Al2O3 and 316SS. The traditional moly-manganese process operates above 1450℃. We modified the moly-manganese process into a two-step process with nickel added to the moly-manganese reaction layer for reducing the reaction temperature. Alumina and 316SS were brazed by the active metal. We put a Kovar or nickel-net interlayer between alumina and 316SS to reduce the high residual stress.
During the moly-manganese process, a reaction layer on alumina was firstly performed at 1250℃. Secondly, a moly-manganese layer on the reaction layer was proceeded at 1250℃. Thirdly, the surface-reacted Al2O3 was brazed to 316SS at 800℃. SEM observation showed this modified two-step moly-manganese process can join alumina and 316SS at lower temperature of 1250℃. For the active metal brazing, Kovar layer and Ni net were used as an interlayer to join alumina and 316SS at 900℃. The shear bond strengths reach 185 MPa for the Kovar-interlayer joining and over 385MPa for the Ni-net brazing.

摘要	I
Abstract	III
致謝	V
目錄	VI
表目錄	VIII
圖目錄	IX
第一章	緒論	1
1-1前言	1
1-2 金屬與陶瓷接合方法	1
1-3 研究動機	2
第二章	理論基礎與文獻回顧	3
2-1　陶瓷材料分析	3
2-2 金屬材料分析	3
2-3 陶瓷與金屬接合考慮因素	4
2-3-1　潤濕性	4
2-3-2 熱應力	7
2-4 接合方式	7
2-4-1 活性硬銲	8
2-4-2金屬化(metallization)	13
2-4-3 擴散接合	21
2-5 接合強度	26
2-5-1 四點彎曲	26
2-5-2 Double cantilever beam test	27
2-6 實驗設計理論	28
第三章	實驗步驟	31
3-1使用儀器介紹	31
3-2 兩段式鉬錳製程藥品選擇及實驗流程	32
3-3 活性硬銲材料、銲料之選擇與實驗流程	37
3-4 剪力測試裝置圖	41
3-5 氧化鋁與不鏽鋼的接合	42
3-5-1兩段式鉬錳層之接合	42
3-5-2 活性硬銲接合	43
3-6 量測儀器	43
3-6-1 X光繞射分析儀(X-ray Diffractometer，XRD)	43
3-6-2 電子微探儀(Electron Probe X-Ray Microanalyzer，EPMA)	44
第四章	結果與討論	47
4-1兩段式鉬錳製程	47
4-1-1 反應層-氧化鉍添加量、反應溫度與成分	47
4-1-2 鉬錳層	57
4-1-3 鉬錳層上鍍銅之目的	58
4-1-4 兩段式鉬錳層接合後之橫截面觀察與探討	59
4-1-5 破斷面XRD	77
4-1-6 總結	82
4-2 活性硬銲	88
4-2-1活性硬銲橫截面探討	88
4-2-2活性硬銲之剪應力測試	103
4-2-3活性硬銲界面反應機制	106
4-2-4 Abaqus殘留應力模擬分析	111
結論	117
參考文獻	119

                                

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