銅基硬銲合金中，Cu-Sn-Ti合金是理想的活性銲料，對於含碳表面的潤濕性接合佳，適合鑽石的接合應用。本文分析銅錫鈦合金在850~1000℃之間對石墨的潤濕性、組成相變化與結合界面的關係。研究發現，鈦的添加有助於增加潤濕性，但也增加合金的融點。錫的添加有助於合金降低融點，但會影響到合金與石墨的化學反應接合能力。微結構在低錫(10at.%)含量時，鈦含量的增加幫助形成CuSn3Ti5相、Cu2SnTi3相及SnTi3相等硬質介金屬化合物相的存在。在低鈦(10at.%)含量時，錫的增加，會形成Cu6Sn5相、Sn5Ti 6相及Sn3Ti2相等易脆介金屬化合物相，存在偏軟的基地固溶相。結果發現Cu-Sn-Ti合金內若大量含有硬靭的介金屬化合物組成相，Cu-Sn-Ti合金與石墨的接合容易產生裂縫。
再以四種不同硬銲合金，對接硬銲CVD鑽石片，硬銲合金分別為Cu基、Ag基及二種Ni基合金。使用抗彎試驗測試硬銲合金與CVD鑽石片接合的強度。結果得知Cu-10Sn-15Ti (wt.%)合金與CVD鑽石片的接合強度(260 MPa)，較兩種Ni-Cr基(Ni-7Cr-3B-3Fe-0.5Si wt.%與Ni-14Cr-10P wt.%)硬銲合金的接合強度(分別為124MPa 及 88MPa)為高，而與銀基的硬銲合金(Ag-34.25Cu-1In-1.75Ti wt.%)與CVD鑽石片的接合強度(285 MPa)相當。

Cu-Sn-Ti alloys are ideal brazing filler suitable for bonding application of diamond because of its high wetting and bonding abilities. This study discussed the effects of various composition of Cu-Sn-Ti alloys on the wetting phenomena of graphite, its constitutions, and their interfaces at the temperature ranging from 850~1000℃.
It was found that the additions of Titanium enhancing the wetting ability of Cu-Sn-Ti alloys; however, although the additions of Tin could lower the melting temperature of the Cu-Sn-Ti alloys, it deteriorated the interface of between graphite and Cu-Sn-Ti alloys caused to affect the chemical bonding of the interface. When the content of Cu-Sn-Ti alloys was at constant low Tin concentration (10at.%), the Titanium addition produced the growth of hard intermetallic compound (IMC) phases, CuSn3Ti5, Cu2SnTi3, and SnTi3; when the content of Cu-Sn-Ti alloys was at constant low Titanium concentration (10at.%), the Tin addition produced the growth of brittle intermetallic compound (IMC) phases, Sn5Ti6 and Sn3Ti2, in the soft matrix. The result was found that the crack was easily occurred at the boundary of graphite and alloys if the constitution had lots of hard intermetallic compound phase (IMC).
To verify the experiment results, four kinds of most used brazing fillers were used to bond CVD diamonds for testing bending strength. The test results indicated that the bending strength of joining CVD diamonds by using Cu-10Sn-15Ti (wt.%) pre-alloys was higher than those by using two kinds of Ni-Cr based alloys, Ni-7Cr-3B-3Fe-0.5Si (wt.%) alloys and Ni-14Cr-10P (wt.%) alloys, but it had the similar value of the bending strength between CVD diamonds, which used Ag-34.25Cu-1In-1.75Ti (wt.%) alloys as brazing filler for CVD diamonds.

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