本研究以富含矽、鋁元素之爐石粉與偏高領土製作三類無機聚合物：A類複合型無機聚合物(70%偏高領土+30%爐石粉)，B類複合型無機聚合物(30%偏高領土+70%爐石粉)及C類爐石無機聚合物(100%爐石粉)，使用氫氧化鈉及矽酸鈉溶液作為激發基材活性之激發劑，其中，A類聚合物使用水玻璃模數(0.6、0.8及1.0)、鹼激發量濃度(11、13及 15%)與水固比(0.55、0.60及0.65)，B類及C類聚合物分別使用0.7與0.6水玻璃模數、9%與7%激發量及0.45與0.33水固比，以探討無機聚合物漿體新拌性質(流度、初終凝及水化熱)(A類)及硬固工程性質(抗壓強度、動彈及動剪性質、超音波速、乾縮及熱傳性質)(A、B及C類)，同時三類無機聚合物均以含砂率作變數(10，30及50%體積比)，探討不同含砂率對無機聚合物砂漿硬固工程性質之影響。
研究結果顯示：
1. A類複合型無機聚合物漿體工作性隨鹼激發濃度與水固比之增加而提升，最佳流度值可達125 %，而隨著玻璃模數增加、鹼激發濃度之提升與降低水固比，會縮短凝結時間與提升水化熱溫度，凝結時間最短約1.8小時即完成終凝，水化溫度最高可達81 ℃。
2. A、B與C類無機聚合物之動態彈性與剪力模數、超音波波速與熱傳導係數會隨著含砂量之增加而提升，分別增加15 %、96 %、74 %；11 %、110%、73 %；21 %、16 %、9 %；100%、48 %、65 %，但抗壓強度與乾縮量則會隨著含砂量之增加而下降，分別降低23 %、10 %、22 %；74 %、35 %、62 %。
3. A類聚合物漿體為均勻收縮；B 及 C類無機聚合物漿體為不均勻乾縮。

In this study, the slag and metakaolin which contain rich elements of silica and aluminium were used to manufacture three types of composite geopolymer: Type A (70% metakaolin and 30% slag), Type B (30% metakaolin and 70% slag) and Type C (100% slag). Both the sodium hydroxide and sodium silicate solution were used as the activators. Type A composite geopolymer uses three water glass moduli of 0.6, 0.8 and 1.0, three concentrations of alkali activator (11, 13 and 15%) and three water-to-solid ratios (0.55, 0.60 and 0.65), while Types B and C use the water glass moduli of 0.6 and 0.7, the e amount of alkali activator of 9% and 7%, and the water-to-solid ratios of 0.45 and 0.33, respectively. The engineering properties of flowability, initial and final setting times and polymerization temperature at the fresh state and the compressive strength, dynamic elastic and shear moduli, ultrasonic pulse speed, dry shrinkage and thermal properties at hardened for Type A composited geopolymer were studied. But only the engineering properties at hardened state for Types B and C were investigated.
The results of study show that:
1. The flowablity of Type A composite geopolymer increases with the increase of the concentration of activator and water-to-solid ratio to reach a best flowability ratio of 125%. The increase of water glass modulus and activator concentration and decrease of water-to-solid ratio tend to reduce the setting times and increase the polymerization temperature with a shortest final setting time of 1.8 hours and a highest temperature of 81oC.
2. The dynamic elastic and shear moduli, ultrasonic pulse speed and thermal conductivity of Types A, B and C geopolymer increase with the increase of sand content with 15%, 96%, 74%, and 11%, 110%, 73%, and 21%, 16%, 9%, and 100%, 48%, 65%, respectively. But both the compressive strength and dry shrinkage decrease with the increase of sand content with 23%, 10%, 22%, and 74%, 35%, 62%, respective.
3. Type A composite geopolymer exhibits a state of uniform shrinkage, but Types B and C show a state of uneven shrinkage.

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