研究生: |
張紫嫺 Tzu-sian Chang |
---|---|
論文名稱: |
太陽能再生電池之設計與探討 Investigation and Module Design of Solar Regenerated Battery |
指導教授: |
黃炳照
Bing-joe Hwang 朱瑾 Jinn P. Chu |
口試委員: |
蘇威年
Wei-nien Su |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2014 |
畢業學年度: | 102 |
語文別: | 中文 |
論文頁數: | 114 |
中文關鍵詞: | 太陽能再生電池 、光觸媒 、電解液 |
外文關鍵詞: | solar regenerated battery, photocatalyst, redox couple |
相關次數: | 點閱:376 下載:3 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
本研究致力於開發以可直接轉換太陽光能為電能之儲能裝置:太陽能再生電池(Solar Regenerated Battery, SRB)。此研究中,成功開發出採用SRB系統之產品雛型裝置(prototype),並以經離子交換法合成的CuFeO2粉體作為其光陰極之可見光驅動光觸媒。本研究進一步探討兩種氧化還原對(redox couple)對該系統之影響。
經由電化學測試,以銅氨錯合物與氯化銅為SRB系統之氧化還原對,可得出較高之電功率轉換效率,其值為5.01x10-4%。然而,以對苯醌與硫酸銅為SRB系統之氧化還原對,則有較高的光轉換效率,其值為2.7 x10-2 %。
A novel solar-regenerated battery, SRB, capable of converting solar energy to electricity and storing it, was sucessfully developed in this work. The prototype of SRB system in the present research, where visble-light-driven photocatalyst CuFeO2 played a role of photocathode, stably worked under illumination. Besides, the influence of two redox couples, Cu(NH3)4Cl2/Cu(NH3)2Cl and quinone/hydroquinone, on the electrochemical performance of the SRB was investigated.
The experimental results showed that a relatively high power efficiency, 5.01 x10-4%, was obtained as Cu(NH3)4Cl2/Cu(NH3)2Cl served as a redox couple for the SRB although the SRB system in which quinone/hydroquinone was the redox couple displayed a relatively high photon-to-current conversion efficiency, 2.7 x10-2%.
1.Cook, J., The correlation between concentration of CO2 and global temperature anomaly. http://www.skepticalscience.com/co2-temperature-correlation.htm, 2010.
2.Technologies, H.s.E., Securing a Stable Electric Power Supply and Reducing CO2 Emissions. . HITACHI Inspire the Next, 2009.
3.Administration, U.S.E.I., Primary energy production with renewable energy distribution. http://www.eia.gov/, 2010.
4.REN21, Renewables 2011 Global Status Report. http://www.ren21.net/, 2011.
5.Becquerel, E., Memoire sur les effets electriques produits sous l'influence des rayons solaires. Comptes rendus de l'Academie des Sciences, 1839. 9: p. 561-567.
6.Wilson, G. and R. Hulstrom, Best Research-Cell Efficiency. National Center for Photovoltaics, 2012.
7.Fujishima, A. and K. Honda, Electrochemical photolysis of water at a semiconductor electrode. Nature, 1972. 238(5358): p. 37-38.
8.Frank, S.N. and A.J. Bard, Heterogeneous photocatalytic oxidation of cyanide and sulfite in aqueous solutions at semiconductor powders. Journal of Physical Chemistry, 1977. 81(15): p. 1484-1488.
9.李曉平,徐寶琨,劉國範等, 功能材料. 1999. 30: p. 242~245.
10.周祖飛,蔣偉川,劉維屏, 環境科學. 1997. 18: p. 35~37.
11.孫奉玉,吳鳴,李文釧等, 催化學報. 1998. 19: p. 121~124.
12.陳士夫,趙夢月,陶耀武等, 環境科學. 1996. 17: p. 33~35.
13.陳耀武,趙孟月,陳士夫等, 催化學報. 1997. 18: p. 345~347.
14.Zhang, Q., L. Gao, and J. Guo, Effects of calcination on the photocatalytic properties of nanosized TiO2 powders prepared by TiCl4 hydrolysis. Applied Catalysis B: Environmental, 2000. 26(3): p. 207-215.
15.K., O., et al., Heterogeneous photocatalytic decomposition of phenol over TiO2 powder. Chemical Society of Japan, 1985. 58: p. 2015-2022.
16.Kudo, A. and Y. Miseki, Heterogeneous photocatalyst materials for water splitting. Chemical Society Reviews, 2009. 38(1): p. 253-278.
17.Gratzel, M., Photoelectrochemical cells. Nature, 2001. 414(6861): p. 338-344.
18.Licht, S., Multiple band gap semiconductor/electrolyte solar energy conversion. Journal of Physical Chemistry B, 2001. 105(27): p. 6281-6294.
19.Bensaid, S., et al., Towards artificial leaves for solar hydrogen and fuels from carbon dioxide. ChemSusChem, 2012. 5: p. 500-521.
20.Shannon, R.D., D.B. Rogers, and C.T. Prewitt, Chemistry of noble metal oxides. I. Syntheses and properties of ABO2 delafossite compounds. Inorganic Chemistry, 1971. 10(4): p. 713-718.
21.Shannon, R.D. and P.S. Gumerman, Effect of covalence on interatomic distances in Cu+, Ag+, Tl+ and Pb2+ halides and chalcogenides. Journal of Inorganic and Nuclear Chemistry, 1976. 38(4): p. 699-703.
22.Lalanne, M., et al., Synthesis and thermostructural studies of a CuFe1-xCrxO2 delafossite solid solution with 0 ≤ x ≤ 1. Inorganic Chemistry, 2009. 48(13): p. 6065-6071.
23.Mugnier, E., A. Barnabe, and P. Tailhades, Synthesis and characterization of CuFeO2+δ delafossite powders. Solid State Ionics, 2006. 177(5-6): p. 607-612.
24.Younsi, M., et al., Visible light-induced hydrogen over CuFeO2 via S2O32- oxidation. Solar Energy Materials & Solar Cells, 2005. 78(5): p. 574-580.
25.Omeiri, S., et al., Photoelectrochemical characterization of the delafossite CuFeO2: Application to removal of divalent metals ions. Journal of Electroanalytical Chemistry, 2008. 614(1-2): p. 31-40.
26.Petrangolini, P., et al., Quinone/Hydroquinone redox reaction studied by EC-STM: Implication for molecular electronics Journal of the American Chemical Society, 2010.
27.Tsai, Y.-M., 淺談電能儲存與液流電池(flow batteries)的最新發展. 2014.
28.Alotto, P., M. Guarnieri, and F. Moro, Redox flow batteries for the storage of renewable energy: A review. Renewable and Sustainable Energy Reviews, 2014. 29(0): p. 325-335.
29.B. Huskinson, M.P.M., C. Suh, S. Er, M.R. Gerhardt, C.J. and X.C. Galvin, A. Aspuru-Guzik, R.G. Gordon and M.J. Aziz, A metal-free organic-inorganic aqueous flow battery. Nature, 2014. 505: p. 195-198.
30.Yan, N.F., G.R. Li, and X.P. Gao, Electroactive Organic Compounds as Anode-Active Materials for Solar Rechargeable Redox Flow Battery in Dual-Phase Electrolytes. Journal of The Electrochemical Society, 2014. 161(5): p. A736-A741.
31.Kuthi, E.B., Crystalline silicon solar cells with selective emitter and the self-doping contact. 2004: p. 21-31.
32.黃文慶, Research and Module Design of Visible-Light Photocatalyst Driven New Solar Cell System. National Taiwan University of Science and Technology - Chemical Engineering, 2012.