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研究生: 高健軒
Chien-Hsuan Kao
論文名稱: 脂環族二酸酐與其無色聚醯亞胺之合成與性質探討
Synthesis and properties of colorless polyimides derived from alicyclic dianhydrides
指導教授: 陳志堅
Jyh-Chien Chen
口試委員: 游進陽
Chin-Yang Yu
李世偉
Shih-Wei Lee
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2020
畢業學年度: 108
語文別: 中文
論文頁數: 72
中文關鍵詞: 脂環族二酸酐無色聚醯亞胺
外文關鍵詞: alicyclic dianhydride, colorless polyimides
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  • 摘要 i Abstract ii 誌謝 iii 目錄 iv Figure索引 vi Scheme索引 vii Table索引 viii 第一章 緒論 1 1.1前言 1 1.1.1 IC半導體之應用 2 1.1.2 軟性印刷電路板之應用 2 1.1.3 液晶顯示器之應用 3 1.2聚醯亞胺的背景 4 1.3聚醯亞胺的合成 5 1.3.1一步法(one-step method) 7 1.3.2二步法(two-step method) 8 1.3.3以矽烷化二胺與二酸酐合成聚醯亞胺 9 1.4無色聚醯亞胺的合成(colerless polyimide,CPI) 11 1.4.1導入高電負度基團 12 1.4.2導入扭曲式結構或巨大側基 15 1.4.3導入脂環族(脂肪族)結構 17 1.5研究動機 24 第二章 實驗步驟 25 2.1實驗藥品 25 2.2實驗儀器 26 2.3單體合成 27 2.3.1 Tetramethyl bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylate (BHTE) 的合成 27 2.3.2 bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylic acid (BHTA)的合成 27 2.3.3 bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylic dianhydride (BHDA(xn),Exo, Endo)的合成 28 2.3.4 bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA)的合成 28 2.4高分子合成 29 2.5高分子薄膜製備 30 第三章 結果與討論 31 3.1單體合成與表徵 31 3.1.1 tetramethyl bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylate (BHTE)的合成與表徵 32 3.1.2 bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylic acid (BHTA)的合成與表徵 33 3.1.3 bicyclo[2,2,1]heptane-2,3,5,6-tetracarboxylic dianhydride (BHDA)的合成與表徵 35 3.1.4 bicyclo[2,2,2]oct-7-ene-2,3,5,6-tetracarboxylic dianhydride (BCDA)的合成與表徵 37 3.2高分子合成與鑑定 41 3.3高分子分子量與溶解度 46 3.4高分子熱穩定性 48 3.5高分子機械性質 51 3.6高分子光學性質 52 3.7高分子介電性質 56 第四章 結論 57 Reference 58

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