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| 研究生： |
林鈺筌 Yu-Cyuan Lin |
|---|---|
| 論文名稱： |
具新穎性之穩定電致變色與多顏色聚醯胺 Electrochromism and Multicolor of Polyamide with Great Novelty |
| 指導教授： |
陳燿騰
Yaw-Terng Chern |
| 口試委員: |
蔡大翔
Dah-Shyang Tsai 華沐怡 Mu-Yi Hua |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2016 |
| 畢業學年度： | 104 |
| 語文別： | 中文 |
| 論文頁數： | 96 |
| 中文關鍵詞： | 電化學 、電致變色 、多顏色 、聚醯胺 、三苯胺 |
| 外文關鍵詞： | electrochemistry, electrochromism, muticolor, polyamide, triphenylamine |
| 相關次數： | 點閱：236 下載：1 |
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本研究成功合成新的主鏈型多三苯胺電致變色材料，由新的二胺單體分別與不同二酸進行聚縮合反應合成4系列聚醯胺。這些新合成的聚醯胺可溶於大部分有機溶劑，例如N-methyl-2-prrolidinone(NMP)與N,N-dimethyl-acetamide(DMAC)等。此外這些聚醯胺具有好的熱穩定性，軟化溫度介於203~217℃之間，在空氣與氮氣下的10% 熱重量損失皆高於400℃，且在800℃的殘餘率超過53%以上。這些聚醯胺呈現非常好的電致變色特性，以4b為例，在第一階氧化態，有高的對比(△T% = 50.4%)與高的著色效率(168 cm2/C) ，在經過30000次的開關測試後，其著色效率只衰減4.5%。4b也呈現多色階的特性，在電壓從0.0 V到1.15 V 間，顏色從中性態的無色依序氧化到不同氧化態呈現綠黃色、黃綠色、森林綠、暗青色及深藍色。
A series of main-chain-type electrochromic novel polyamides 4 based on triphenylamine were synthesized from the polycondensation reaction of new diamine monomer 3 with various commercially available aromatic dicarboxylic acids. All the polyamides were amorphous with good solubility in many organic solvents, such as N-methyl-2- prrolidinone (NMP) and N,N-dimethyl-acetamide (DMAC). These polyamides had good thermal stability, with the softening temperature between 203~217℃, 10% weight-loss temperature in excess 400℃ under nitrogen and air state, and char yield at 800℃ in nitrogen higher than 53%.
All the polyamides exhibited excellent electrochromic properties. For example, the polyamide 4b at the first oxidation stage had high color contrast (△T% = 50.4%) and coloration efficiency (168 cm2/C) in visible region, with excellent electrochemical cycling stability(over 30000 times within 4.5% loss relative to its initial coloration efficiency).The polymer film also showed a multicolor characteristic, when applied a potential ranging from 0.0 to 1.15 V, the color change from colorless neutral state to greenyellow, yellowgreen, forestgreen, darkcyan and darkblue.
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