目前國內水性聚氨酯在乾式塗佈上多應用於接著為主，在紡織品則多應用於加工助劑之使用，且國內應用防水透濕上之發展進展不大，水性聚氨酯於透濕防水技術上因聚氨酯本身的耐水性不足，需達到兼具良好的透溼度及耐水壓之物性平衡之技術有待改善，因此了解水性樹酯乾式成膜物性之關鍵因素以及建立水性聚氨酯膜塗佈控制因素是必要的，未來提升水性聚氨酯量化使用之參考指標並進一步可提升本產業之競爭力。

本研究將水性聚氨酯乾式塗佈於織物上，形成無孔質親水性膜層，訴求其織物具有防水透濕功能，主要方式為後加工配方調配、調整塗佈方式以及膜之熟成條件，可成功製成透濕 (g/m2．24hr)及耐水壓(mmH2O)達10000以上，且易於加工亦不會產生環保問題，未來希望可望量化應用於戶外運動用品織物上。

At present, the development of domestic waterborne polyurethane in dry coating is mostly used in adhesives, and in the textile application mainly for processing aids. The progress of the development of waterborne polyurethane is slow. As a result of composition, resulting in lower hydrostatic pressure test. We have to improve water vapor permeability and hydrostatic pressure test technology so it’s necessary to understand the key factors of water resin dry film forming properties and establish waterborne polyurethane film coating control factors. In the future, enhance the use of water-based polyurethane reference indicators can promote the competitiveness of the industry.
With these researches the major purpose is to use waterborne polyurethane coating on fabrics let the fabrics have the advantage with permeability and water resistance. In this research, we can make the better recipes and working conditions for the small amount production and the stable reference conditions for manufacturing. Moreover, these high performances of breathable fabrics maintain the competitive advantage in high class of textiles.

[1] Harshorn, S.R., “Introduction”, Structural Adhesives, 1986.
[2] C.H.M. Jacques, “polymer alloys, Blend, block, Craft, and
interpenetrating network”, Polymer Science and Technolog,1997.
[3] S.A. buzahr, G.L. Wilkes and Z. Ophir., “Structure-property
behavior ofsegmented polyether-MDI-butanediol based urethane：
effect ofcomposition ratio”, Polymer, pp.23, 2005.
[4] C. Hepburn. , “polyurethane Elastomer”, Chapter 3 and 10, 1991.
[5] D. Karalekas and K. Antoniou, “Composite rapid prototyping: Overcoming the drawback of poor mechanical properties”, Journal of Materials Processing Technology, Vol.153-154, No.1- 3, pp. 526-530, 2004.
[6] J. W. Rosthauser, K. Nachtkamp , “Coated Fabrics”, pp.16-39, 1986.
[7] S. K. Kim, J. C. Lee , “ Polym. Sci.: Part A Polymer Chemisty ”,
Vol. 34, No.131, 1996.
[8] 李紹雄、劉益軍，「聚氨酯樹及其應用」，化學工業出版社，
2002。
[9] 陳素珍，「陰離子水性聚氨酯奈米複材之製備與研究」，中原
大學化學系研究所碩士論文，2004。
[10] D. Dieterich, W. Keberle, “polyurethane Elastomer ”,
Vol.34, No.131, 1996.
[11] D. Dieterich and H. Reiff, “Coated Fabrics”, Vol. 85, 1972.
[12] Y.K. Jhon, I.W. Cheong, J.H. Kim, “Colloids and Surfaces
”, Physicochemical and Engineering Aspects, Vol.179, 2001.
[13] Skeist, “Adhesive”, Vol.6, pp.979, 1993.
[14] J. Julia, D. Salvat ella and J. Lope, “Adhesive Age”, Vol.37, pp.26, 1994.
[15] S.W. Zhang, W.J. Wang, H.X. LI and C.M. Liu, “Zhongguo
Jiaonianji”, Vol.11, pp.4, 2002.
[16] B.K. Kim, J.C. Lee, “Waterborne polyurethanes and their properties 1”, Vol.4, pp.1095-1104, 1996.
[17] 許戈文等，「水性聚氨酯材料」，化學工業出版社，2006。
[18] B.K.Kim and Y.M.Lee, “Colloid Polymer Scilience ”, pp.956-961, 1992.
[19] 預計全球水性聚氨酯市場2019年將達100億美元且年增9%
(民104年7月16日)。慧聰表面處理網。取自：
http://www.pf.hc360.com。
[20] 2022年全球水性塗料產量預計達3271萬噸(民105年7月20
日)。中國塗料網。取自：http://www.tuliao86.com/。
[21] 石捷麟，「水性聚氨酯/二氧化鈦複合材料之製備與性質研究」，
萬能科技大學材料科技研究所碩士論文，2009。
[22] 張欣程，「矽氧烷-氨基甲酸酯共聚合體之合成及物理性質」，
逢甲大學紡織工程研究所博士論文，2008。

[23] 許耀基，「聚(矽氧烷/丁醚-氨基甲酸酯)共聚合體熱性質」，國
立台灣科技大學高分子工程研究所博士論文，2008。
[24] C.S. chollenberger , F.D. Stewart , “Advanes in urethane”,
Science and Technology, Vol.2, 1973.
[25] ASTM D570 , “Standard Test Method for Water Absorption of
Plastics”, 2010.
[26] K.C. Frisch, S.L. Reegen, “Advanes in urethane ”, Science and Technology, Vol 2, 1973.
[27] AATCC 140-1992 , “AATCC Technical Manual”, pp. 243-244, 1994.
[28] J.W Britain, P.G. Gemeinhardt, “Applied Polymer Science”, Vol. 4, pp. 207,1960.
[29] M. B. C. Fernanda, C. D. Marcia, S. A. Lairton, “Anionic
waterborne polyurethanedispersions based on hydroxyl-
terminated polybutadiene and poly(propylene glycol): Synthesis
and characterization, ” Journal of Applied Polymer Science, Vol.80,
pp. 566-572, 2001.
[30] M. G. Lu, J. Y. Lee, M. J, Shim, S. W. Kim, “Synthesis and
properties of anionic aqueous polyurethane dispersions, ” Journal
of Applied Polymer Science, Vol. 86, pp. 3461-3465, 2002.
[31] Michael Szycher, “Szycher’s Handbook of Polyurethane,” Chapter 14, 1999.
[32] G. Philipp, H. Schmidt, “New materials for contact lenses
prepared from Si-and Ti-alkoxides by the sol-gel process”,
Journal of Non-Crystalline Solids, Vol. 63, pp. 283, 1984.
[33] K. Geng, F. Yang, “Nanoindentation of submicron
polymeric coating systems”, Materials Science and Engineering,
pp.157-163, 2008.
[34] J.C. Tanne, “Breath ability Comfort and Gore-TexLaminates”,
Journal of Coated Fabrics,Vol. 8, pp.312, 1979.
[35] G.R. Lomax, “Lightweight Brathable Fabrics”, Journal of Coated
Fabrics, Vol. 15, pp.115, 1985.
[36] P.B.Jacobs, P.C.Yu “Two-Component Waterborne Polyurethane Coatings”, Journal of Coating, Vol.65, pp.82, 1993.
[37] B. Zorn, “Porous Polyurethane Film and Coatings”, Journal of
Coated Fabrics, Vol.13, pp.166, 1984.
[38] Y.Naka, Hirakata, K.Kawakami, Kyoto, “Moisture-Permeable Waterproof Coated Fabric and Method of Marking the Same”, United States Patent, Vol. 442, pp.900, 1984.
[39] Qian Lei, Zhou Hong, “Coating behaviours of aqueous anion
ionomer polyurethane”, Journal of China Textile University, Vol.
17, No.4 , pp.69, 1991.
[40] 郭淑琴，「酯醚型混合軟鏈節水性PU樹脂之合成、構造與物
性及其對耐龍織物透濕防水加工之研究」，國立台灣科技大學
纖維及高分子研究所博士論文，1998。
[41] 黃晉男、顏明雄，「以含PEG末端酯醚型共聚合水性PU寡聚
合物對聚酯纖維(PET)織物進行親水加工之研究」，國立台灣科
技大學纖維及高分子研究所碩士論文，1999。
[42] 梁婷茹，「以蒸處凝固方式應用於水性PU耐龍織物透詩防水
加工」，國立台灣科技大學纖維及高分子研究所碩士論文，
2000。
[43] 房姿均、顏明雄，「非離子水性PU之合成、構造與物性及對
PET織物親水加工之研究」，國立台灣科技大學纖維及高分子
研究所碩士論文，2002。