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研究生： 吳致葦
Jhih-Wei Wu
論文名稱： 利用活性開環複分解反應合成不同嵌段數之共聚物及其在陰離子交換膜燃料電池之應用
Multiblock Copolymers Prepared by Living ROMP Polymerization and Their Application for Anion Exchange Membrane Fuel Cells
指導教授： 陳志堅
Jyh-Chien Chen
口試委員: 汪昆立
Kun-Li Wang
蕭育生
Yu-Sheng Hsiao
學位類別： 碩士
Master
系所名稱： 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年： 2023
畢業學年度： 111
語文別： 中文
論文頁數： 84
中文關鍵詞： 陰離子交換膜 、四級銨陽離子 、微相分離 、陰離子傳導率 、燃料電池 、開環複分解反應 、活性聚合
外文關鍵詞： anion exchange membrane, quaternary ammonium cation, microphase separation, anion conductivity, fuel cell, ring-opening metathesis polymerization, living polymerization
相關次數： 點閱：600  下載：0 
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    • 本文以dicyclopentadiene (DCPD)為起始物，利用Diels-Alder 加成反應合成出兩種不同降冰烯之衍生物，並以dichloromethane為溶劑以及[1,3-bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro(phenylmethylene)bis(3-bromopyridi ne) ruthenium(II) (G3)進行活性開環複分解聚合反應，成功合出一系列擁有不同嵌段共聚物結構的聚降冰烯高分子(rPNB)，並將其進行還原和四級銨化，最後以N,N,N′,N′-tetramethyl-1,3-diaminepropane (TMDAP)作為交聯劑，成功製備出不同IEC以及交聯程度之陰離子交換膜，並對其做燃料電池性質之探討。
    由於其四級銨鹽本身之熱穩定性，使得薄膜在200 ℃前皆無出現熱重損失，展現出極佳的熱穩定性。而block copolymer所測得含水率和溶脹率遠低於random copolymer並且在機械性質上也有不錯的表現。另外也藉由小角度X光散射(SAXS)證明block copolymers具有明確地微相分離，並且明顯反應至傳導率上，使D-2.00HPNB具有比相近IEC之其他AEM有更高的傳導率(80 ℃, 198.53 mS/cm)，最後在60 ℃之1 M NaOH中進行鹼性穩定性之測試，並在720小時都未發現明顯降解，顯示極佳的鹼性穩定性。

    In this work, we used dicyclopentadiene (DCPD) as a starting material and synthesized two kind of norbornene with different derivatives by Diels-Alder reaction. And we successfully prepared a series of polynorbornene with multiblock copolymer structure by using living ring-opening metathesis polymerization and controlled the IECs and crosslinking degree of the anion exchange membrane (AEM) by feeding ratio.
    The thermal stability of the resulting membranes is excellent, with no significant thermal weight loss observed below 200 °C. The block copolymer showed much lower water uptake and swelling ratio than the random copolymer and had good mechanical properties. Small-angle X-ray scattering (SAXS) proved that block copolymers have clear microphase separation, which is significantly reflected in the conductivity. D-2.00HPNB has a higher conductivity (80 ℃, 198.53 mS/cm) than other AEMs with similar IECs. Finally, the alkaline stability was tested in 1 M NaOH at 60 ℃, and no significant degradation was observed for up to 720 hours, demonstrating excellent alkaline stability.

    中文摘要 i Abstract ii 致謝 iii 目錄 iv Figure 索引 vii Scheme 索引 ix Table 索引 x 第一章 緒論 1 1.1 前言 1 1.2 燃料電池介紹 2 1.3 AEMFC之發電原理與結構 3 1.4 開環複分解聚合(ring-opening metathesis polymerization, ROMP) 5 1.5 活性聚合概述 (living polymerization) 6 第二章 文獻回顧 8 2.1 陰離子交換膜介紹 8 2.2 鹼性穩定性與陽離子基團之降解機制 9 2.3 活性開環複分解聚合(Living ring-opening metathesis polymerization, Living ROMP) 14 2.4 研究動機 16 第三章 實驗 17 3.1 實驗儀器 17 3.2 實驗藥品 18 3.3 單體合成 19 3.3.1 5-Bromopentene之合成 19 3.3.2 5‐(Bromopropyl)bicyclo[2.2.1]hept‐2‐ene (M1)之合成 19 3.3.3 5‐Butylbicyclo[2.2.1]hept‐2‐ene (M2)之合成 20 3.3.4 [1,3-Bis(2,4,6-trimethylphenyl)-2-imidazolidinylidene]dichloro (pheny lmethylene)bis(3-bromopyridine)ruthenium(II) (G3) 20 3.4 聚降冰烯之合成 22 3.4.1 Random copolymer之合成 22 3.4.2 Diblock copolymer之合成 23 3.4.3 Triblock copolymer之合成 24 3.5 聚降冰烯之還原 25 3.6 高分子薄膜之製備方法 26 第四章 結果與討論 27 4.1 單體合成與表徵 27 4.1.1 5‐(Bromopropyl)bicyclo[2.2.1]hept‐2‐ene (M1) 27 4.1.2 5‐Butylbicyclo[2.2.1]hept‐2‐ene (M2) 30 4.2 高分子合成與性質表徵 32 4.2.1 聚降冰烯之合成與性質表徵 32 4.2.2 活性聚合之證明 36 4.2.3 Random copolymer之證明 41 4.2.4 還原聚降冰烯之合成與性質表徵 42 4.2.5 AEM之製備 46 4.3 IEC、吸水率、溶脹率及熱性質 48 4.4 機械性質 53 4.5 微相分離之探討 55 4.6 離子傳導率 59 4.7 鹼性穩定性 63 第五章 結論 65 參考文獻 66

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    全文公開日期 2028/08/15 (校外網路)
    全文公開日期 2028/08/15 (國家圖書館：臺灣博碩士論文系統)
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