研究生: |
黃文慶 Wen-ching Huang |
---|---|
論文名稱: |
內建可見光觸媒之新型太陽能電池的設計與研究 Research and Module Design of Visible-Light Photocatalyst Driven New Solar Cell System. |
指導教授: |
蕭敬業
Ching-Yeh Shiau 黃炳照 Bing-Joe Hwang |
口試委員: |
蘇威年
Wei-Nien Su |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 200 |
中文關鍵詞: | 光觸媒 、可見光驅動 、太陽能電池 |
外文關鍵詞: | visible light driven, solar energy, photocatalysts |
相關次數: | 點閱:188 下載:3 |
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本研究主要為研發新型太陽能電池(New Solar Cell, NSC),成功開發出NSC系統的模型,並使用透過離子交換法合成的CuFeO2、溶膠凝膠法合成的Bi20TiO32,商業化的WO3和經過400 ℃,10 % H2氣氛的熱還原氧化石墨烯(reduced graphene oxide, rGO)作為光觸媒,以作為NSC的發電的來源。其中,T400_rGO光觸媒材料的前驅物,是藉由modified Hummers’ method製備而成的氧化石墨烯(graphene oxide, GO)。除了將GO熱還原成rGO,且以此作為光觸媒的用途之外,另外還藉由光觸媒於400 W汞燈照射下將GO還原,將此用以改善其它光觸媒本身較弱的導電性質。
光觸媒經由可見光照射,而產生光生電子電洞對。其中的光電子與電解質啟光電化學還原反應;電洞則與電解質發生光電化學氧化反應,最後用以發電。經由恆電位儀測試眾多NSC系統的結果,現階段以20_WPr與30_rGO系統的數據最佳,其所測得之最大開環電壓(open circuit voltage, Voc)為0.37 V,系統之反應面積為4.75 x 10-5 m2,故經過計算得到的最大短路電流密度(short circuit current density, Jsc)為8.6 x 10-3 A/m2,且填充因子(filling factor, FF)為34.3 %。
In this work a new solar cell (NSC) system is demonstrated for first time. The system is powered by ion exchange fabricated CuFeO2 and sol-gel synthesized Bi20TiO32 as photocathode and anode, respectively. The use of commercial WO3 and self-made hydrogen-assisted thermal reduced graphene oxide are also studied. The precursor of T400_rGO photocatalyst is made via a modified Hummers’ method. Besides playing a role as a photocatalyst, graphene oxide here also serves as a conductive framework by photo-reduction with other photocatalyst under a 400 W mercury lamp. This proves beneficial to the electron conductivity of photocatalysts.
Electron-hole pairs are generated while the photocatalyst is exposed to visible light. The photoelectron triggers the reduction reaction of the electrolyte and the holes participate in the photo-oxidation reaction which leads to power generation. After investigation by potential static equipment amongst several testing conditions the 20_WPr and 30_rGO show the best results. 0.37 V open circuit voltage is observed under a reaction area of 4.75 x 10-5 m2. It is found that the short circuit current density and filling factor are 8.6 x 10-3 A/m2 and 34.3 %, respectively.
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