研究生: |
陳宏彬 Hung-Bin Chan |
---|---|
論文名稱: |
不同結構環氧樹脂/SiO2混成材料之製備及性質研究 Preparation and Properties of Epoxy/SiO2 Hybrids of different structure |
指導教授: |
許應舉
Ying-Gev Hsu |
口試委員: |
楊銘乾
Ming-Chien Yang 陳信龍 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2005 |
畢業學年度: | 93 |
語文別: | 中文 |
論文頁數: | 104 |
中文關鍵詞: | 凝膠 、溶膠 |
外文關鍵詞: | sol-gel |
相關次數: | 點閱:398 下載:0 |
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將具有矽氧烷類基團(-Si(OR)3)的改質劑(modifier)-3-Glycidoxypropyltrimethoxylsilane (GPTS)及3-(Trimethoxysilyl) propyl-methacrylate (TPA)與聚矽酸奈米顆粒PN (polysilicic acid nanoparticles)顆粒進行反應,將PN改質成表面含有-CH-CH2及-C-C(CH3)=CH2基團之顆粒-分別以G-PN、T-PN稱之。將DGEBA與G-PN、T-PN以不同組成比例混合均勻後,並在硬化促進劑2-methyl-imidazole (2-MI)及BPO存在下加熱硬化,分別製成架橋(cross linking networks, CLNs)、和網絡相互穿梭 (interpenetrating networks , IPNs) 三種不同結構的混成材料-DGEBA/2-MI/G-PN、DGEBA/2-MI/T-PN及DGEBA/2-MI/G3-T-PN。以各種精密儀器如FTIR、DSC、TMA及DMA分析材料之結構、硬化收縮、內應力、動態機械及熱性質…等,並藉此評估比較各種結構混成材料性質的影響。
The polysilic acid nanoparticle (PN) was modified by the reaction of silanol group on its surface with silyl group (-Si(OR)3) containing modifiers such as 3-glycidoxypropyltrimethoxylsilane (GPTS) and 3-(trimethoxysilyl) propyl-methacrylate (TPA), respectively to afford modified PNs, called G-PN, T-PN. G-PN and T-PN were mixed indifferent composes and ratios of DGEBA (diglycidyl ether bisphenol A) to prepare the homogeneous solutions, and then let homogeneous solution undergo curing reaction in the presence of 2-methyl-imidazole (2-MI) and BPO. Two kinds of hybrids with structure of cross-linking network (CLNs) and interpenetrating networks, (IPNs) were obtained. Through measusing the propenties such as thermal, internal stress, and flexural modulus by FT-IR, DSC, TMA, DMA, the hybrids of different structures were investigated and compare in detail.
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