研究生: |
翁啟達 Chi-Da Weng |
---|---|
論文名稱: |
自組裝型固態高分子電解質合成及行為研究 Study on the Synthesis and Behavior of Self-assembling Solid Polymer Electrolyte |
指導教授: |
許應舉
Ying-Gev Hsu |
口試委員: |
黃茂全
none 王英靖 none |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2005 |
畢業學年度: | 93 |
語文別: | 中文 |
論文頁數: | 108 |
中文關鍵詞: | 自組裝 、固態高分子電解質 |
外文關鍵詞: | self assembly, solid polymer electrolytes |
相關次數: | 點閱:337 下載:0 |
分享至: |
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
中文摘要
本研究以4-羥基苯甲醛與11-溴-1-十一烯等起始物合成出具疏水基團之3,5-bis(11-methacryloylundecyl-1-oxybenzyloxy)benzoic acid(MBA),使之與poly(ethylene glycol)(PEG, Mw=600)進行酯化反應,合成具自組裝基團之poly(ethylene glycol)- 3,5-bis(11-methacryloyl -undecyl-1-oxybenzyloxy)benzoate(PEG-BMBA),其中間產物之結構均經由FT-IR、NMR和Mass等儀器證實。PEG-BMBA可經由兩種不同的方式進行組裝,其一為在不同的溶劑極性下,其在親疏水性差異的驅動下進行自組裝;另一方式為PEG-BMBA於過氯酸鋰溶液中,經由配位鍵的驅動下進行自組裝,其組裝可分別由UV-Vis與FT-IR光譜證實,此外,組裝後的PEG-BMBA加熱硬化後能夠溶合(solvation)過氯酸鋰,證明此固態高分子電解質(Solid Polymer Electrolyte)確實具有離子傳導的功能。
A poly(ethylene glycol) (PEG, Mw=600) containing self-assembly compound poly(ethylene glycol)-3,5-bis(11- methacryloylundecyl -1- oxybenzyloxy)benzoate (PEG-BMBA) was synthesized by the reaction of 3,5-bis(11- methacryloylundecyl-1-oxybenzyloxy) benzoic acid (MBA) with PEG. The structures of PEG-MBA and the intermediates were identified by FTIR, NMR and Mass spectroscopy. PEG-BMBA was through supersonic vibration of the compound in CH2Cl2/MeOH solution of different polarity and was examined by UV-Vis or FT-IR spectroscopy. It was found that the assembly of the compound was formed chiefly through hydrophobic interaction and coordinative bonding. After assembling, the supramolecules was cured.The polymer could solvate lithium ion in it to increase the ability of ionic conductivity.
第七章 參考文獻
1. 白世榮,固態聚電解質之應用與研究,材料會訊第七卷第五期高 分子材料專輯 。
2. M. B. Armand, J. M. Chabagno and M. Duclot, Extended Abstracts of Second International Meeting on Solid Electrolytes, St Andrews, Scotland, Sept., 1978.
3. J. R. MacCallum and C. A. Vincent, Eds., Polymer Electrolyte Reviews, Vol. 1 and 2, Elsevier Applied Science, London, 1987 and 1989.
4. J. S. Tonge and D. F. Shriver, in Polymers for Electronic Applications, J. H. Lai, Ed., CRC Press, Inc., Boca Raton, FL, 1989, Chap. 5.
5. R. J. Neat, in Modern Battery Technology, C. D. S. Tuck, Ed., Ellis Horwood Limited, New York, 1991.
6. D. W. Kim, J. K. Park, J. S. Bae and S. I. Pyun, J. Polym. Sci. Part B: Polym. Phys., 1996, 34, 2127-2137.
7. D. Świerczynski, A. Zalewska and W. Wieczorek, Chem. Mater. 2001, 13, 1560-1564.
8. P. Gavelin, R. Ljungbäck, P. Jannasch and B. Wesslen, Solid State Ionics, 2002, 147, 325-332.
9. H. W. Chen, C. H. Jiang, H. D. Wu and F. C. Chang, J. Appl. Polym. Sci., 2004, 91, 1207-1216.
10. S. Chao and M. S. Wrighton, J. Am. Chem. Soc., 1987, 109, 2197.
11. J. Plocharski and W. Wieczorek, Solid State Ionics, 1998, 28-30, 979.
12. D. E. Fenton, J. M. Parker and P. V. Wright, Polymer, 1973, 14, 589.
13. P. V. Wright, Br. Polym. J., 1975, 7, 319.
14. M. B. Armand, J. M. Chabagno and M. Duclot, Second International Meeting on Solid Electrolytes, St. Andrew, Scotland, September 20-22, 1978, Extended Abstracts.
15. K. Murata, S. Izuchi and Y. Yoshihisa, Electrochim. Acta, 2000, 45, 1501-1508.
16. W. H. Meyer, Adv. Mater. 1998, 10, 439-448.
17. A. Killis, J. F. LeNest, A. Gandini, H. Cheradame and J. P. Cohen, Solid State Ionics, 1984, 14, 231.
18. P. G. Hall, G. R. Davies, J. E. McIntyre, I. M. Ward, D. J. Bannister and K. M. F. Le Brocq, Polym. Commun. 1986, 27, 98-100.
19. J. Nishimoto, N. Furuya and M. Watanabe, Extended Abstracts of 62nd Meeting of Japanese Electrochemical Society, 3J12, 1995.
20. 曾宇燦,雙團聯式共聚物電解質之微相形態與離子傳導行為之研究,清華大學化學工程系碩士論文,2003。
21. Y. Tada, M. Stato, N. Takeno, T. Kameshima, Y. Nakacho and K. Shigekara, Macromol. Chem. Phys., 1994, 195, 571.
22. A. S. Gozdz, J. M. Tarascon, C. N. Schmutz, P. C. Warren, O. S. Gebizlioglu and F. Shokoohi, Proceedings of the 10th Annual Battery Conference on Applications and Advances, 1995, p. 301.
23. 葉偉斌,高分子電解質奈米複合材料之合成與物性研究,元智大學化學工程系碩士論文,2002。
24. U. Lauter, W. H. Meyer and G. Wegner, Macromolecules, 1997, 30, 2092-2101.
25. S. H. Chung, Y. Wang, L. Persi, F. Croce, S. G. Greenbaum, B. Scrosati and E. Plichta, Journal of Power Sources, 2001, 97-98, 644-648.
26. W. J. Liang and P. L. Kuo, Polymer, 2004, 45, 1617-1626.
27. Y. W. Chen-Yang, S. Y. Chen, C. Y. Yuan, C. H. Tsai and D. P. Yan, Macromolecules, 2005, 38, 2710-2715.
28. R. D. Bach, A. G. Baboul and H. B. Schlegel, J. Am. Chem. Soc., 2001, 123, 5787-5793.
29. 陳國成編著,實用有機化學。
30. L. G. Wade, JR., Organic Chemistry, 4th Ed., 1999.
31. H. L. Nyquist, E. A. Beeloo and L. S. Hurlbut, J. Org. Chem., 2002, 67, 3202-3212.
32. G. W. Kabalka, S. Yu and N. S. Li, Tetrahedron Lett., 1997, 38, 5455-5458.
33. J. Cossy, N. Blanchard, C. Hamel and C. Meyer, J. Org. Chem., 1999, 64, 2608-2609.
34. H. C. Brown and R. M. Gallivan, Jr., J. Am. Chem. Soc., 1968, 90, 2906-2915.
35. U. P. Dhokte and H. C. Brown, J. Org. Chem., 1997, 62, 865-869.
36. P. Shapland and E. Vedejs, J. Org. Chem., 2004, 69, 4094-4100.
37. R. Shelkov, M. Nahmany and A. Melman, J. Org. Chem., 2002, 67, 8975-8982.
38. R. B. Grossman, The Art of Writing Reasonable Organic Reaction Mechanisms, Springer-Verlag, 1999.
39. E. Vedejs and S. T. Diver, J. Am. Chem. Soc., 1993, 115, 3358-3359.
40. E. Vedejs, N. S. Bennett, L. M. Conn, S. T. Diver, M. Gingras, S. Lin, P. A. Oliver and M. J. Peterson, J. Org. Chem., 1993, 58, 7286-7288.
41. G. Quéléver, S. Burlet, C. Garino, N. Pietrancosta, Y. Laras and J. L. Kraus, J. Comb. Chem., 2004, 6, 695-698.
42. M. Zhang, P. Vedantham, D. L. Flynn and P. R. Hanson, J. Org. Chem., 2004, 69, 8340-8344.
43. M. Bodansky, Peptide Chemistry: A Practical Textbook; Springer, New York, 1998.
44. M. Nahmany and A. Melman, Org. Lett., 2001, 3, 3733-3735.
45. T. W. Graham Solomons, Solomons, Wiley.
46. G. M. Whitesides and B. Grzybowski, Science, 2002, 295, 2418-2421.
47. O. Lkkala and G. T. Brinke, Science, 2002, 295, 2407-2409.
48. C. G. Claessens, J. F. Stoddart, J. Phys. Org. Chem., 1997, 10, 254.
49. D. W. Yoo, S. K. Yoo, C. Kim and J. K. Lee, J. Chem. Sci., Dalton Trans. 2002, 3931.
50. H. M. Kao and C. L. Chen, Angew. Chem. Int. Ed., 2004, 43, 980-984.
51. P. Jannasch, Polymer, 2002, 43, 6449-6453.
52. H. Lee, L. Keplet and T. Mallouk, J. Am. Chem. Soc., 1998, 120, 618.
53. Y. Shimazaki, M. Mitsaishi and H. Yamamoto, Langmuir, 1997, 13, 1385.
54. K. Ariga, Y. Lvov and T. Kunitake, J. Am. Chem. Soc., 1997, 119, 2224.
55. T. M. Cooper, A. L. Campbell and R. L. Crane, Langmuir, 1995, 11, 2713.
56. E. R. Kleinfeld and G. S. Ferguson, Science, 1994, 265, 370.
57. Y. Lvov, K. Ariga, T. Kunitake and I. Ichinose, J. Am. Chem. Soc., 1995, 117, 6117.
58. G. Decher and Y. Lvov, Biosens Bioelectron, 1994, 9, 6775.
59. J. Y. Wang, Z. Q. Wang, X. Zhang and J. C. Shen, Macromol. Rapid. Commun., 1997, 18, 509.
60. W. B. Stockton and M. F. Rubner, Macromolecules, 1997, 30, 2717-2725.
61. M. Lee, B. K. Cho and W. C. Zin, Chem. Rev., 2001, 101, 3869.
62. H. A. Klok and S. Lecommandoux, Adv. Mater., 2001, 13, 1217.
63. S. Förster and T. Plantenberg, Angew. Chem. Int. Ed., 2002, 41, 689.
64. Y. Yu and A. Eisenberg, J. Am. Chem. Soc., 1997, 119, 8383.
65. L. Zhang and A. Eisenberg, Science, 1995, 268, 1728.
66. K. Kataoka, A. Harada and Y. Nagasaki, Adv. Drug Delivery Rev., 2001, 41, 113.
67. F. D. Jaeghere, E. Allémann, J. Feijen, T. Kissel, E. Doelker and R. Gurny, J. Drug Targeting, 2000, 8, 143.
68. J. F. Gohy, S. Creutz, M. Garcia, B. Mahltig, M. Stamm and R. Jerôme, Macromolecules, 2000, 33, 6378-6387.
69. B. C. Tofield, R. M. Dell and J. Jensen, AERE Harwell Report 11261, 1984.
70. C. F. Faul and M. Antonietti, Adv. Mater., 2003, 15, 673-683.
71. 李紹銘,新穎聚胺基甲酸酯於固態高分子電解質之研究,國立成功大學化學工程學系博士論文,2003。
72. B. Scrosati Ed., Applications of Electroactive Polymers, 1993.
73. M. B. Armand, Sixth International Conference on Solid State Ionics, Garmisch-Partenkirchen, 1987, paper A4-6.
74. C. Berthier, W. Gorecki, M. Minier, M. B. Armand, J. M. Chabagno and P. Rigaud, Solid State Ionics, 1983, 11, 91.
75. T. G. Fox and P. J. Floy, J. Polym. Sci., 1954, 14, 315.
76. M. H. Cohen and D. Turnbull, J. Chem. Phys., 1959, 31, 1164.
77. M. L. Williams, R. F. Landel and J. D. Ferry, J. Am. Chem. Soc., 1955, 77, 3701.
78. C. A. Vincent, In Electrochemical Science and Technology of Polymers 2, Elsevier Applied Science, London, 1990.
79. D. D. Perrin, Purification of Laboratory Chemicals, Pergamon Press, 2nd Ed., 1980.
80. 詹瓊瑩,聚乙二醇衍生物之合成及其自組裝行為之研究,國立台灣科技大學高分子工程研究所碩士學位論文,2004。
81. R. M. Silverstein and F. X. Webster, Spectrometric Identification of Organic Compounds, 6th Ed.
82. X. Lin, A. Zhong, D. Chen, Z. Zhou and B. He, J. Appl. Polym. Sci., 2002, 85, 638-644.
83. H. Cohen, J. Chem. Soc., 1952,4282.