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研究生: 徐雅怡
Ya-I Hsu
論文名稱: 銀粉及碳黑對環氧樹脂複合導電效應之研究
The Study of Compound Conductive Effect of Silver Flake and Carbon Black to Epoxy Resin
指導教授: 邱顯堂
Hsien-Tang Chiu
口試委員: 邱士軒
Shih-Hsuan Chiu
陳建光
Jem-Kun Chen
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2009
畢業學年度: 97
語文別: 中文
論文頁數: 47
中文關鍵詞: 銀粉碳黑導電度
外文關鍵詞: silver flake, carbon black, conductivity
相關次數: 點閱:258下載:3
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對填充型的導電複合材料而言,其中的填充物無疑是決定導電性的要角;以目前的半導體封裝產業來說,銀粉仍然被廣泛使用於導電複合材料中,乃是基於銀的優良導電性及化學安定性,但銀粉價格昂貴,所以本研究中尋求降低成本且兼顧優良導電性之方法。
本研究中先探討單一銀粉粒子添加量對導電複合材料的導電度影響,再比較多種不同粒徑大小銀粉混合時的複合影響效應及環境試驗的結果,茲將本研究結果摘要如下:
1.單一銀粉粒子添加量在混合物總量50wt﹪以上才是屬於導電物質。
2.銀粉粒子的particle size越小且Specific surface area越大者易有優良的導電度,在不同粒徑大小混合時仍有提升整體導電度的作用。
3.而針對降低成本的需求,降低高單價銀粉填充量,以碳黑及銀粉同時填充複合材料,少量銀粉的添加對整體導電度就有極顯著的提升作用,且導電性不易受環境試驗的影響。
4.由於導電複合材料的使用上多需要考量黏著性,故進行百格膠帶試驗法來評估其對基材的附著性。
5.銀粉粒子比重大易沉降,藉由SEM(掃描式電子顯微鏡)可觀察銀粉在樹脂基材中的分散狀況。

關鍵字:銀粉、碳黑、導電度


Speaking of the filled conductive compound materials, in which filler is the strong character decided its conductivity. By the present semiconductor seal industry, the silver powder was still widely used in the conductive compound materials, is based on the fine conductivity and the chemical stability of silver, but the price of silver powder is expensive, therefore in this research seeks to reduce the cost, and gives dual attention to the method of the fine conductivity.
This research discusses the conductivity influence for the content of sole silver flake powder first to the conductive compound materials, again time quite many kinds of different particle size silver flake powder mix compound influence effect and environmental testing result, the findings abstract will be as follows:
1.The content of sole silver flake powder in mixture to total quantity is 50wt % above ,belongs to the conductive material.
2.The silver flake particle size is smaller and specific surface area is bigger have fine conductivity, when different particle size mixed still has the promotion of whole mixture conductivity.
3.In view of the cost down, reduce the filled quantity of high price silver flake powder, simultaneously filled the compound materials by carbon black and silver flake powder, the few filled quantity of silver flake powder is extremely promoted the compound materials conductivity , and the conductivity is not easily affected by environmental testing.
4.Because of the application of conductive compound materials needs to consider the adhesiveness, therefore carries on cross-cut tape testing standard method to appraise it to the parent substrate adhesiveness.
5.Because of silver density is moe heavy leads to precipitation, may observe the dispersion condition of the silver flake powder particle in resin by SEM.

Keyword:silver flake, carbon black , conductivity

中文摘要………………………………………………………………………І 英文摘要………………………………………………………………………II 誌謝……………………………………………………………………………IV 目錄……………………………………………………………………………V 圖表索引………………………………………………………………………VII 第一章 緒論………………………………………………………………… 1 第二章 基礎理論與文獻回顧……………………………………………… 2 2.1 高分子導電複合材料簡介……………………………………… 2 2.2 導電填充物……………………………………………………… 4 2.3 高分子基材……………………………………………………… 8 2.3.1 環氧樹脂的硬化反應……………………………………… 9 2.4 導電複合材料的導電機制分析………………………………… 11 2.4.1 滲透理論(Percolation Theory) …………………………… 12 2.4.2 接觸電阻(Constriction Resistivity)………………………… 15 2.4.3 穿隧效應(Tunneling Effect) ……………………………… 16 第三章 實驗藥品與儀器設備介紹………………………………………… 18 3.1 銀粉……………………………………………………………… 18 3.2 環氧樹脂………………………………………………………… 20 3.3 硬化劑…………………………………………………………… 21 3.4 碳黑……………………………………………………………… 22 3.5 四點探針電阻測試儀…………………………………………… 23 3.6 SEM …………………………………………………………… 23 第四章 實驗結果與討論…………………………………………………… 24 4.1 實驗簡介………………………………………………………… 24 4.2 Silver flake添加量對導電度的影響效應……………………… 27 4.3 Silver flake/ CB的導電度複合效應…………………………… 32 4.4 Silver flake particle size 對導電度的影響效應………………… 37 4.5 百格附著性試驗………………………………………………… 41 4.5.1 Silver flake 添加量對百格附著性的影響效應…………… 41 4.5.2 Silver flake / CB的百格附著性複合效應…………………… 42 4.5.3 Silver flake particle size 對百格附著性的影響效應……… 43 第五章 結論 ………………………………………………………………… 44 參考文獻……………………………………………………………………… 45

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