本文探討添加氧化石墨烯 (GO)、矽烷接枝氧化石墨烯 (sg-GO)、熱脫層氧化石墨烯 (TRGO)以及矽烷接枝熱脫層氧化石墨烯 (sg-TRGO) 等數種特用添加劑的合成及其對環氧樹脂(EPR)/ 4,4-二胺基二苯甲烷(DDM) / 特用添加劑三成份系統於100℃/180℃階段性恆溫固化之聚合之微觀型態結構、体積收縮、機械性質、熱傳導及導電性質的影響。
熱脫層氧化石墨烯(TRGO)是將氧化石墨烯(GO)置於1050℃的高溫爐中30與90秒合成熱脫層而得；GO則是將平均粒徑為75μm的天然石墨粉以改良Hummers 法製得。
矽烷接枝氧化石墨烯(sg-GO)及矽烷接枝熱脫層氧化石墨烯(sg-TRGO)係帶有環氧基團的矽烷偶合劑，即（3-縮水甘油氧基丙基）三甲氧基矽烷（GPS），做為表面改質劑。
最後吾人亦是用掃描式電子顯微鏡(SEM)、萬用材料測試機、耐衝擊測試機、熱傳導性質測定儀及表面電阻計研究GO與TRGO對EPR/DDM/添加劑三成分系統之固化後樣品體積收縮、微觀型態結構、機械性質、熱傳導與導電性之影響。

The effects of graphene oxide (GO), silane-grafted graphene oxide (sg-GO) , thermally reduced graphene oxide (TRGO), silane-grafted thermally reduced graphene oxide (sg-TRGO) as special additives on the cured sample on the cure kinetics, glass transition temperature, X-ray scattering characteristics,morphologies, volume shrinkage characteristics , mechanical properties, thermal conductivities and electrical properties of the Epoxy/DDM/Additive ternary system cured after a stepwise isthermal process of 100℃/180℃ were investigated.
The thermally reduced graphene oxide (TRGO) was produced by placing graphene oxide (GO) in a high-temperature furnace kept at 1050℃, which was synthesized from natural graphites with average particle size of 75μm by a modified Hummers method.
The silane-grafted GO (sg-GO) or silane-grafted TRGO (sg-TRGO) was synthesized by using the silane coupling agent bearing epoxy functional group, namely, γ-glycidyloxy propyl trimethoxy silane (GPS), as a surface modifier for the surface treatment of GO.
Finally, the effects of additives synthesized, such as, GO, sg-GO, TRGO, and sg-TRGO, on the volume shrinkage, mechanical properties, thermal and electrical conductivities for the Epoxy/DDM/Additive ternary systems after the cure have also been investigated.

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