研究生: |
邱筱婷 Hsiao-Ting Chiu |
---|---|
論文名稱: |
預濺鍍銅、銀對430-LSMO73高溫氧化及電性之影響 Effect of Sputtering Cu and Ag on the High-temperature Oxidation and Electrical Conductivity of 430SS-LSMO73 |
指導教授: |
王朝正
Chaur-Jeng Wang |
口試委員: |
周振嘉
none 顏怡文 Yee-wen Yen, |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 機械工程系 Department of Mechanical Engineering |
論文出版年: | 2006 |
畢業學年度: | 94 |
語文別: | 中文 |
論文頁數: | 119 |
中文關鍵詞: | 固態氧化物燃料電池 、高溫氧化 、金屬雙極板 、ASR |
外文關鍵詞: | 430 Stainless Steel, Solid oxide fuel cell, High-temperature oxidation, Metallic Interconnects, area specific resistance. |
相關次數: | 點閱:266 下載:6 |
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本研究以430不銹鋼(430SS)為底材,並塗覆La0.7Sr0.3Mn3O (LSMO73)以及在塗覆LSMO73之前於430SS底材預濺鍍銀及銅銀,探討LSMO73燒結後於800℃之高溫氧化行為及導電性。實驗結果顯示,LSMO73於1200℃氮氣氣氛之燒結會發生分解,若燒結溫度降低至1100℃,則LSMO73已充分燒結且未發生分解。LSMO73經過1100℃氮氣燒結過後,於800℃空氣氣氛,具有高溫化學安定性並對430SS具保護性。LSMO73與合金界面處所產生的氧化層種類與厚度,取決於燒結過程中LSMO73與合金的反應。電性量測方面,於500℃〜800℃,430SS原材具有最高的導電性,其次依序為430塗覆LSMO73、800℃空氣預氧化48小時、800℃空氣預氧化120小時。主要影響ASR值的因素為金屬底材在高溫氧化環境下所產生的氧化層厚度及氧化物的種類。參雜低價Ag+於氧化層,可以約略降低氧化層的氧化速率,並在高溫時明顯提升氧化層的導電性。於塗覆LSMO73前的銅銀預鍍層,由於銅在高溫燒結過程中發生氧化,不僅會降低導電性,且銅會與LSMO73中的La反應,生成LaCuO4導致LSMO73分解,對導電性有不良的作用。
This study investigates the sintering phenomenon under N2 atmosphere at 1100℃ and 1200℃ for La0.7Sr0.3Mn3O (LSMO73) screen-printed by 430 Stainless Steel (430SS), meanwhile, the behavior and conductive characteristic of high temperature oxidation at 800℃ for LSMO73 after sintering is also investigated too. The experimental results shows that for 430SS and for sintering at 1200℃ under N2 atmosphere, LSMO73 will decompose, however, when the temperature is reduced to 1100℃, LSMO73 will be sintered completely and no decomposition will occur. After 1100℃ sintering under N2 atmosphere and then put it at 800℃ under air environment, LSMO73 will possess high temperature chemical stability and protective characteristic, therefore, the oxide type and thickness generated at the interface between LSMO73 and alloy is decided by the reaction between LSMO73 and alloy during the sintering process. In the electrical property measurement aspect, the major factor which affects ASR (Area specific resistance) value is the oxide thickness and oxide type (conductivity) generated under high temperature environment by metallic double electrode plate. As the oxide layer gets thicker, ASR value will get increased. Dope low valence Ag+ into oxide layer will slightly decrease the oxidation rate of the oxide layer and, under high temperature environment, obviously increase the conductivity of the oxide layer, In the aspect of increasing the wetting characteristic by using Cu, Cu will get oxidized during high temperature sintering process and the conductivity will thus be reduced, meanwhile, Cu will react with La of LSMO73 to form LaCuO4 which will in turn leads to the decomposition of LSMO73.
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