研究生: |
黃豪寬 Hao-Kuan Huang |
---|---|
論文名稱: |
由元素矽水解法合成無機二氧化矽奈米顆粒及以RAFT活
自由基溶液聚合法合成用於不飽和聚酯及乙烯基酯具核殼型結構之高分子接枝二氧化矽奈米顆粒、高分子接枝之氧化石墨烯、及高分子接枝之脫層石墨烯奈米層板抗收縮劑及增韌劑 Synthesis of nano-scale colloidal silica from elemental silicon by hydrolysis, and synthesis of polymer-grafted silica nanoparticle, polymer-grafted graphene oxide, and polymer-grafted exfoliated graphene nanoplatelet with core-shell structure as low-profile additives and tougheners for unsaturated polyester and vinyl ester resins by RAFT living free radical solution polymerizations |
指導教授: |
黃延吉
Yan-Jyi Huang |
口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 Wen-Yen Chiu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 化學工程系 Department of Chemical Engineering |
論文出版年: | 2015 |
畢業學年度: | 103 |
語文別: | 中文 |
論文頁數: | 180 |
中文關鍵詞: | 無機/有機核殼型顆粒(CSP) 、抗收縮劑 (LPA) 、增韌劑 、可逆加成-斷裂鏈轉移聚合法(RAFT) 、乙烯基酯樹脂(VER) 、二氧化矽奈米顆粒 、氧化石墨烯 、體積收縮 、機械性質 、聚合固化樣品之微觀型態結構 、掃瞄式電子顯微術(SEM) 、穿透式電子顯微術(TEM) |
外文關鍵詞: | inorganic/organic core-shell particle (CSP), low-profile additive (LPA), toughenor, reversible addition-fragmentation chain transfer, vinyl ester resins (VER), Silica nanoparticle(SNP), graphite oxide(GO), volume shrinkage, mechanical properties, cured sample morphology, SEM, TEM |
相關次數: | 點閱:1016 下載:4 |
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本文探討用作熱固性樹脂抗收縮劑及增韌劑之奈米級無機/有機核殼型顆粒(CSP)的合成,其對低收縮乙烯基酯樹脂在聚合固化後之樣品微觀型態結構、体積收縮特性及機械性質的影響。
這些核殼型顆粒(CSP),分別以SiO2-polymer及GO-polymer標示之,前者係以二氧化矽奈米顆粒(SNP)、氧化石墨烯(GO)為核心,兩者皆以有機高分子為外殼,以Z支撐的可逆加成-斷裂鏈轉移聚合法(RAFT),利用二氧化矽或氧化石墨烯支撐的3-(benzylsulfanylthiocarbonylsulfanyl) propionic acid (SiO2-BSPA 或 GO-BSPA)作為鏈轉移試劑合成而得。其中,直徑15 nm的二氧化矽奈米顆粒是以可控制顆粒尺寸的矽元素水解法合成,而氧化石墨烯則是由平均粒徑為2至15微米的天然石墨粉經氧化合成而得。SiO2-polymer、GO-polymer核殼型顆粒的高分子外殼為聚丙烯酸甲酯(poly(methyl acrylate), PMA)、丙烯酸甲酯(MA)中導入不同比例甲基丙烯酸環丙氧酯(GMA)(佔外層10及20mole%),以形成共聚合物(P(MA-co-GMA))、丙烯酸丁酯(BA)與丙烯酸甲酯之團聯共聚合物(PBA-b-PMA)、或聚丙烯酸丁酯(BA)與丙烯酸甲酯(MA)及甲基丙烯酸環丙氧酯(GMA)的共聚合物之團聯共聚合物(PBA-b- P(MA-co-GMA))。
BSPA、SiO2-BSPA、SiO2-polymer、GO-BSPA及GO-polymer的結構,吾人以FTIR、1H-NMR、13C-NMR、GPC、TGA及DSC鑑定之。本文中,吾人亦探討SiO2-polymer及GO-polymer對苯乙烯(St)/乙烯基酯(VER)/ SiO2-polymer或GO-polymer之三成份系統於120℃聚合固化後之體積收縮特性及機械性質的影響。
Synthesis of nano-scale inorganic/organic core-shell particle (CSP) as low-profile additives (LPA) and toughenors for thermoset resins, and their effects on the cured sample morphology, volume shrinkage characteristics and mechanical properties for low-shrink vinyl ester resins (VER) during the cure were investigated.
These CSP designated as SiO2-polymer or GO-polymer, the former of which contained silica nanoparticle (SNP) as the core and the latter of which contained graphite oxide(GO) as the cure and both of them with organic polymer as the shell, were synthesized by the Z supported reversible addition-fragmentation chain transfer (RAFT) graft polymerization using silica-supported or graphite oxide-supported 3-(benzylsulfanylthiocarbonylsulf- anl) propionic acid (SiO2-BSPA or GO-BSPA) as the chain transfer agent (CTA). The silica nanoparticle with a diameter of 15 nm was synthesized by size-controllable hydrolysis of elemental silicon, and the graphite oxide(GO) was synthesized from natural graphites with average particle size of 2 to 15μm. The grafted polymer as the shell of the SiO2-polymer or GO-polymer was made from poly(methyl acrylate)(PMA), copolymer of MA and glycidyl methacrylate(poly(MA-co-GMA)),poly(butylacrylate)-block-poly(methyl acrylate) (PBA-b-PMA) or PBA-block-poly(MA-co-GMA).
Structure characterizations of BSPA, SiO2-BSPA, SiO2-polymer, GO-BSPA and GO-polymer have been performed by using FTIR, 1H-NMR, 13C-NMR, GPC and DSC. In this work, the effects of SiO2-polymer and GO-polymer on the volume shrinkage characteristics and mechanical properties of the styrene(St)/ vinyl ester(VER)/ SiO2-polymer or (GO-polymer) ternary systems during the cure have also been explored.
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