簡易檢索 / 詳目顯示

回結果列表
研究生： 黃豪寬
Hao-Kuan Huang
論文名稱： 由元素矽水解法合成無機二氧化矽奈米顆粒及以RAFT活 自由基溶液聚合法合成用於不飽和聚酯及乙烯基酯具核殼型結構之高分子接枝二氧化矽奈米顆粒、高分子接枝之氧化石墨烯、及高分子接枝之脫層石墨烯奈米層板抗收縮劑及增韌劑
Synthesis of nano-scale colloidal silica from elemental silicon by hydrolysis, and synthesis of polymer-grafted silica nanoparticle, polymer-grafted graphene oxide, and polymer-grafted exfoliated graphene nanoplatelet with core-shell structure as low-profile additives and tougheners for unsaturated polyester and vinyl ester resins by RAFT living free radical solution polymerizations
指導教授： 黃延吉
Yan-Jyi Huang
口試委員: 陳崇賢
Chorng-Shyan Chern
邱文英
Wen-Yen Chiu
學位類別： 碩士
Master
系所名稱： 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年： 2015
畢業學年度： 103
語文別： 中文
論文頁數： 180
中文關鍵詞： 無機/有機核殼型顆粒(CSP) 、抗收縮劑 (LPA) 、增韌劑 、可逆加成-斷裂鏈轉移聚合法(RAFT) 、乙烯基酯樹脂(VER) 、二氧化矽奈米顆粒 、氧化石墨烯 、體積收縮 、機械性質 、聚合固化樣品之微觀型態結構 、掃瞄式電子顯微術(SEM) 、穿透式電子顯微術(TEM)
外文關鍵詞： inorganic/organic core-shell particle (CSP), low-profile additive (LPA), toughenor, reversible addition-fragmentation chain transfer, vinyl ester resins (VER), Silica nanoparticle(SNP), graphite oxide(GO), volume shrinkage, mechanical properties, cured sample morphology, SEM, TEM
相關次數： 點閱：669  下載：4 
分享至:
查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報

    • 本文探討用作熱固性樹脂抗收縮劑及增韌劑之奈米級無機/有機核殼型顆粒(CSP)的合成，其對低收縮乙烯基酯樹脂在聚合固化後之樣品微觀型態結構、体積收縮特性及機械性質的影響。
    這些核殼型顆粒(CSP)，分別以SiO2-polymer及GO-polymer標示之，前者係以二氧化矽奈米顆粒(SNP)、氧化石墨烯(GO)為核心，兩者皆以有機高分子為外殼，以Z支撐的可逆加成-斷裂鏈轉移聚合法(RAFT)，利用二氧化矽或氧化石墨烯支撐的3-(benzylsulfanylthiocarbonylsulfanyl) propionic acid (SiO2-BSPA 或 GO-BSPA)作為鏈轉移試劑合成而得。其中，直徑15 nm的二氧化矽奈米顆粒是以可控制顆粒尺寸的矽元素水解法合成，而氧化石墨烯則是由平均粒徑為2至15微米的天然石墨粉經氧化合成而得。SiO2-polymer、GO-polymer核殼型顆粒的高分子外殼為聚丙烯酸甲酯(poly(methyl acrylate), PMA)、丙烯酸甲酯(MA)中導入不同比例甲基丙烯酸環丙氧酯(GMA)(佔外層10及20mole%)，以形成共聚合物(P(MA-co-GMA))、丙烯酸丁酯(BA)與丙烯酸甲酯之團聯共聚合物(PBA-b-PMA)、或聚丙烯酸丁酯(BA)與丙烯酸甲酯(MA)及甲基丙烯酸環丙氧酯(GMA)的共聚合物之團聯共聚合物(PBA-b- P(MA-co-GMA))。
    BSPA、SiO2-BSPA、SiO2-polymer、GO-BSPA及GO-polymer的結構，吾人以FTIR、1H-NMR、13C-NMR、GPC、TGA及DSC鑑定之。本文中，吾人亦探討SiO2-polymer及GO-polymer對苯乙烯(St)/乙烯基酯(VER)/ SiO2-polymer或GO-polymer之三成份系統於120℃聚合固化後之體積收縮特性及機械性質的影響。

    Synthesis of nano-scale inorganic/organic core-shell particle (CSP) as low-profile additives (LPA) and toughenors for thermoset resins, and their effects on the cured sample morphology, volume shrinkage characteristics and mechanical properties for low-shrink vinyl ester resins (VER) during the cure were investigated.
    These CSP designated as SiO2-polymer or GO-polymer, the former of which contained silica nanoparticle (SNP) as the core and the latter of which contained graphite oxide(GO) as the cure and both of them with organic polymer as the shell, were synthesized by the Z supported reversible addition-fragmentation chain transfer (RAFT) graft polymerization using silica-supported or graphite oxide-supported 3-(benzylsulfanylthiocarbonylsulf- anl) propionic acid (SiO2-BSPA or GO-BSPA) as the chain transfer agent (CTA). The silica nanoparticle with a diameter of 15 nm was synthesized by size-controllable hydrolysis of elemental silicon, and the graphite oxide(GO) was synthesized from natural graphites with average particle size of 2 to 15μm. The grafted polymer as the shell of the SiO2-polymer or GO-polymer was made from poly(methyl acrylate)(PMA), copolymer of MA and glycidyl methacrylate(poly(MA-co-GMA)),poly(butylacrylate)-block-poly(methyl acrylate) (PBA-b-PMA) or PBA-block-poly(MA-co-GMA).
    Structure characterizations of BSPA, SiO2-BSPA, SiO2-polymer, GO-BSPA and GO-polymer have been performed by using FTIR, 1H-NMR, 13C-NMR, GPC and DSC. In this work, the effects of SiO2-polymer and GO-polymer on the volume shrinkage characteristics and mechanical properties of the styrene(St)/ vinyl ester(VER)/ SiO2-polymer or (GO-polymer) ternary systems during the cure have also been explored.

    摘要 I Abstract III 致謝 IV 目錄 V 圖目錄 I 表目錄 V 第一章 緒論 1 1-1 二氧化矽 [1] 1 1-2 高分子複合材料 1 1-3 不飽和聚酯 (Unsaturated polyester, UP) 2 1-4 環氧樹脂 (Epoxy Resin ) [19-24] 3 1-5 乙烯基酯樹脂 (Vinyl Ester Resin, VER) 6 1-6 抗收縮劑 (Low Profile Additive, LPA) 7 1-7 增韌劑 7 1-8石墨烯/高分子奈米複合材料 9 1-9 研究範疇 14 第二章 文獻回顧 16 2-1 二氧化矽 [1, 37-38] 16 2-1-1 二氧化矽的製備 [1, 34, 39- 40] 17 2-2 自由基聚合法 19 2-3 溶液聚合法 (Solution Polymerization) [43] 22 2-4 活性自由基聚合法 [44] 23 2-4-1 原子轉移自由基聚合法 (ATRP) 24 2-4-2 穩定自由基聚合法 (SFRP) 26 2-4-3可逆加成-斷裂鏈轉移聚合法 (RAFT) [30-32, 35, 53-55] 28 2-5不飽和聚酯與苯乙烯之交聯共聚合反應 31 2-6蒙特納石黏土(Montmorillonite, MMT)及蒙特納石黏土/高分子奈米複合材料 34 2-7 石墨烯/高分子奈米複合材料之研究 38 2-8氧化石墨烯(GO)及熱還原氧化石墨(TRGO)的製備 39 2-9以RAFT聚合法合成高分子接枝之氧化石墨烯 41 第三章 實驗方法及設備 42 3-1 實驗藥品 42 3-1-2 乙烯基酯樹脂 (Vinyl Ester Resin, VER) 49 3-2 實驗儀器與操作步驟 51 3-2-1動態光散射儀 (DLS) 51 3-2-2核磁共振光譜儀 (NMR) 51 3-2-3元素分析儀(EA) 52 3-2-4電灑游離法質譜(ESI) 52 3-2-5傅立葉轉換紅外線光譜儀 (FT-IR) 53 3-2-6熱重分析儀 (TGA) 54 3-2-7膠體滲透層析儀 (GPC) 55 3-2-8 動態DSC 55 3-2-9 拉伸測試 56 3-2-10 耐衝擊測試 56 3-2-11 掃描式電子顯微鏡 (SEM) 57 3-2-12 穿透式電子顯微鏡 (TEM) 58 3-3 實驗方法 60 3-3-1元素矽水解法合成二氧化矽 (Silica) [34, 85] 60 3-3-2活化二氧化矽顆粒 63 3-3-3 鏈轉移試劑(BSPA)之合成 [35-36, 44,84-92] 64 3-3-4 二氧化矽接枝鏈轉移試劑 (SiO2-BSPA) 之合成[36-37, 44, 54, 93] 67 3-3-5 熱還原氧化石墨烯之製備[79-80] 69 3-3-6氧化石墨烯接枝鏈轉移試劑 (GO-BSPA) 之合成 70 3-3-7二氧化矽接枝聚合物[94- 95]及氧化石墨烯接枝聚合物[82] (SiO2-Polymer or GO-Polymer) 之合成 72 3-3-7-1 單體純化 72 3-3-7-2 冷凍抽氣解凍循環 (Freeze-pump-thaw cycles) 72 3-3-7-3 二氧化矽外殼接枝高分子 73 3-3-7-4 二氧化矽外殼接枝雙區段共聚合物 (SiO2-PBA-b-PMA, SiO2-PBA-b-P(MA-co-GMA)) 76 3-3-7-5 氧化石墨烯外殼接枝高分子[83] 80 3-3-7-6 氧化石墨烯外殼接枝丙烯酸甲酯及丙烯酸丁酯雙區段共聚物之合成 (GO-PBA-b-PMA, GO-PBA-b-(MA-co-GMA)) 82 3-3-7-7 胺解斷鏈接枝聚合物鏈 84 3-3-8 St/VER(n=2)/無機有機核殼型顆粒(CSP) 三成分系統之固化試片製作 86 3-3-9 體積變化量測-密度法 88 3-3-10 St/VER(n=2)/無機有機核殼型顆粒(CSP) 三成分系統未反應前之相分離實驗 88 第四章 結果與討論 89 4-1 二氧化矽之合成 90 4-1-1元素矽水解法合成膠體二氧化矽奈米顆粒 [34] 90 4-1-1-1 二氧化矽製備之適度規模放大 99 4-1-2 製備二氧化矽粉末 103 4-1-3 活化前後二氧化矽顆粒之FTIR鑑定 104 4-2鏈轉移劑3-(benzylsulfanylthiocarbonylsufanyl) propionic acid (BSPA)之合成 113 4-2-1探討鏈轉移劑(BSPA) 之實驗步驟 113 4-2-2 鏈轉移試劑(BSPA) 之FTIR鑑定 115 4-2-3 鏈轉移試劑(BSPA) 之NMR鑑定 117 4-2-4 鏈轉移試劑(BSPA) 之EA鑑定 122 4-2-5 鏈轉移試劑(BSPA) 之ESI鑑定 124 4-3二氧化矽接枝鏈轉移試劑(SiO2-BSPA) 之合成 127 4-3-1二氧化矽接枝4-氯甲基苯基三甲氧矽烷(SiO2-Cl)之FTIR鑑定 128 4-3-2二氧化矽接枝鏈轉移試劑(SiO2-BSPA)之FTIR鑑定 130 4-4氧化石墨烯接枝鏈轉移試劑(GO-BSPA) 之合成 133 4-4-1氧化石墨烯接枝4-氯甲基苯基三甲氧矽烷(GO-Cl)之FTIR鑑定 134 4-4-2氧化石墨烯接枝鏈轉移試劑(GO-BSPA)之FTIR鑑定 137 4-5 接枝高分子之二氧化矽奈米顆粒(SiO2-polymer)之合成與 分析 140 4-5-1 GPC鑑定溶液中自由相高分子(free polymer)、二氧化矽奈米顆粒固相接枝高分子(grafted polymer)之分子量及其分佈 141 4-5-2二氧化矽之TGA鑑定 144 4-6 接枝高分子之氧化石墨烯(GO-polymer)之合成與分析[83] 157 4-6-1 GPC鑑定溶液中自由相高分子(free polymer)、氧化石墨烯固相接枝高分子(grafted polymer)之分子量及其分佈 158 4-6-2氧化石墨烯接枝高分子(GO-polymer)之TGA鑑定 162 4-7 RAFT溶液聚合法合成二氧化矽接枝高分子(SiO2-polymer)或氧化石墨烯接枝高分子(GO-polymer)之反應探討 166 第五章 結論 169 第六章 建議與未來工作 171 第七章 參考文獻 173

    [1] R. K. Iler, The chemistry of silica: solubility, polymerization, colloid and surface
    properties, and biochemistry, Wiley, New York 1979.
    [2] R. B. Burns, "Polyester molding compounds", Marcel Dekker, New York, 1982.
    [3] K. E. Atkins, H. G. Kia, Sheet Molding Compounds: Science and Technology, Ch. 4, H.G. Kia, Hanser, New York 1993.
    [4] Y. J. Huang, C. M. Liang, Polymer 1996, 37, 401.
    [5] Y. J. Huang, C. J. Chu, J. P. Dong, Journal of Applied Polymer Science 2000, 78, 543.
    [6] Y.J. Huang, T.S. Chen, J.G. Huang, F. H. Lee, "Polym. Mater. Sci. Eng. 83, 493 ", 2000.
    [7] Y.J. Huang, J.P. Dong, J.J. Yang, J.H. Lee, D. H. Lai, Polym. Mater. Sci. Eng. 85, 497 2001.
    [8] The B.F. Goodriche Co, WO93/21274, Oct. 28.1993.
    [9] E. Martuscelli, P. Musto, G. Ragosta, G. Scarinzi, E. Bertotti, Journal of Polymer Science Part B: Polymer Physics 1993, 31, 619.
    [10] S. B. Pandit, V. M. Nadkarni, Industrial & Engineering Chemistry Research 1994, 33, 2778.
    [11] D. S. Kim, K. Cho, J. H. An, C. E. Park, Journal of Materials Science 1994, 29, 1854.
    [12] J. S. Ullett, R. P. Chartoff, Polymer Engineering & Science 1995, 35, 1086.
    [13] M. Abbate, E. Martuscelli, P. Musto, G. Ragosta, G. Scarinzi, Journal of Applied Polymer Science 1995, 58, 1825.
    [14] M. L. L. Maspoch, A. B. Martinez, Polymer Engineering & Science 1998, 38, 290.
    [15] N. A. Miller, C. D. Stirling, Polym. Polym. Comps. 9, 31 2001.
    [16] R. E. Young, in "Unsaturated Polyester Technology" ed. P.F. Bruins, Gordon and Breach Science Publishers, New York 1976.
    [17] M. E. Kelly, in "Unsaturated Polyester Technology" ed. P.F. Bruins, Gordon and Breach Science Publishers, New York 1976, 370.
    [18] F. Fekete, in "Unsaturated Polyester Technology" ed. P.F. Bruins, Gordon and Breach Science Publishers, New York 1976, 28.
    [19] B. Ellis, "Chemistry and Technology of Epoxy Resins", London: Blackie Academic and Professional 1993.
    [20] 陳東課, 環氧樹脂在基層板之應用, 化工技術第四卷第五期, 1996.
    [21] 賴耿陽, 環氧樹脂應用實務, 復漢出版社, 台灣, 1999.
    [22] 賴家聲, 環氧樹脂與硬化劑(上), 復漢出版社, 台灣, 1999.
    [23] S. V. Levchik, G. Camino, M. P. Luda, L. Costa, G. Muller, B. Costes, Polymer Degradation and Stability 1998, 60, 169.
    [24] 黃滄閔, 國立成功大學 碩士論文 2001.
    [25] T. Mitani, H. Shiraishi, K. Honda, G. E. Owen, 44th Annual Conference Composite Institute, the Society of the Plastics Industry, session RF (Reb3-9) 1989.
    [26] W. Li, L. J. Lee, Polymer 1998, 39, 5677.
    [27] M. Kinkelaar, S. Muzumdar, L. J. Lee, Polymer Engineering & Science 1995, 35, 823.
    [28] R. R. Hill, S. V. Muzumdar, L. J. Lee, Polymer Engineering & Science 1995, 35, 852.
    [29] W. Crc for Polymers Pty. Ltd., WO97,43339 Nov 20,1997.
    [30] J. Chiefari, Y. K. Chong, F. Ercole, J. Krstina, J. Jeffery, T. P. T. Le, R. T. A. Mayadunne, G. F. Meijs, C. L. Moad, G. Moad, Macromolecules 1998, 31, 5559.
    [31] G. M. T. P. Le, S. H. T. E. Rizzardo, PCT Int. Appl. WO9801478 A1980115 1998.
    [32] D. J. Keddie, G. Moad, E. Rizzardo, S. H. Thang, Macromolecules 2012, 45, 5321.
    [33] H. Kim, A. A. Abdala, C. W. Macosko, Macromolecules 2010, 43, 6515.
    [34] J. Guo, X. Liu, Y. Cheng, Y. Li, G. Xu, P. Cui, Journal of Colloid and Interface Science 2008, 326, 138.
    [35] M. H. Stenzel, T. P. Davis, A. G. Fane, Journal of Materials Chemistry 2003, 13, 2090.
    [36] D. L. Patton, R. C. Advincula, Macromolecules 2006, 39, 8674.
    [37] R. P. W. Scott, "Silica Gel and Bonded Phases", Wiley, New York, 1993.
    [38] K. Ohno, T. Morinaga, K. Koh, Y. Tsujii, T. Fukuda, Macromolecules 2005, 38, 2137.
    [39] W. Stober, A. Fink, E. Bohn, Journal of Colloid and Interface Science 1968, 26, 62.
    [40] 合成二氧化矽的特性與用途, 高分子工業 1998.
    [41] 彭俊昇, 國立台灣科技大學 碩士論文 2000.
    [42] H. R. Allcock, F. W. Lampe, "Contemporary Polymer Chemistry, 2nd Ed." Prentice-Hall, New Jersey, 1990, 50.
    [43] C.S.Brazel and S.L. Rosen, "Fundamental Principles of Polymeric Materials, 3rd Ed." Wiley, New York, 2012.
    [44] "張容瑋, 國立台灣科技大學 碩士論文", 2008.
    [45] M. Szwarc, Nature, 178, 1168, London, 1956.
    [46] T. Otsu, M. Yoshida, Makromol Chem Rapid Commun. 1982, 3, 127, 542.
    [47] K. Matyjaszewski, J. Xia, Chemical Reviews 2001, 101, 2921.
    [48] J. S. Wang, K. Matyjaszewski, Journal of the American Chemical Society 1995, 117, 5614.
    [49] M. Kamigaito, T. Ando, M. Sawamoto, Chemical Reviews 2001, 101, 3689.
    [50] D. H. Solomon, E. Rizzardo, P. Cacioli, US Patent, 4, 581, 429, 1985.
    [51] M. K. Georges, R. P. N. Veregin, P. M. Kazmaier, G. K. Hamer, Macromolecules 1993, 26, 2987.
    [52] R. Francis, D. Taton, J. L. Logan, P. Masse, Y. Gnanou, R. S. Duran, Macromolecules 2003, 36, 8253.
    [53] P. Takolpuckdee, C. A. Mars, S. Perrier, Organic letters 2005, 7, 3449.
    [54] Y. Tsujii, M. Ejaz, K. Sato, A. Goto, T. Fukuda, Macromolecules 2001, 34, 8872.
    [55] R. Narain, S. P. Armes, Macromolecules 2003, 36, 4675.
    [56] Y. S. Yang, L. J. Lee, Polymer 1988, 29, 1793.
    [57] K. Horie, I. Mita, H. Kambe, Journal of Polymer Science Part A: Polymer Chemistry 1969, 7, 2561.
    [58] 江文慶, 國立台灣科技大學 碩士論文, 1996.
    [59] Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, T. Kurauchi, O. Kamigaito, Journal of Polymer Science Part A: Polymer Chemistry 1993, 31, 983.
    [60] 韋光華、林鴻明, "PU/矽酸鹽層奈米複材之合成與分析、金屬及陶瓷奈米微粒之合成與應用"，經濟部工業局九十年度工業技術人才培訓計畫上課講義，財團法人自強工業科學基金會，2001年9月18日
    [61]白世榮、蕭守道, "Applications of X-ray Scattering: Nanostructure Characterization in Frontier Polymer Research," Lecture Hand-out, 中興大學化工系，2002年6月26日.
    [62] Z. Wang, T. J. Pinnavaia, Chemistry of Materials 1998, 10, 3769.
    [63] I. N. Jan, T. M. Lee, K. C. Chiou, J. J. Lin, Industrial & engineering chemistry research 2005, 44, 2086.
    [64] J. J. Lin, I. J. Cheng, R. Wang, R. J. Lee, Macromolecules 2001, 34, 8832.
    [65] D. M. Moore, R. C. Reynolds, "X-ray Diffraction and the Identification and Analysis of Clay Minerals, 2nd ed", Oxford university press: New York, 1997.
    [66] X. Kornmann, L. A. Berglund, J. Sterte, E. P. Giannelis, Polymer Engineering & Science 1998, 38, 1351.
    [67] S. J. Park, B. J. Kim, D. I. Seo, K. Y. Rhee, Y. Y. Lyu, Materials Science and Engineering: A, 2009, 526, 74.
    [68] S. Sen, Polymer Composites, 2010, 31, 482.
    [69] M. K. Dean, S. A. Bateman, R. Simons, Polymer, 2007, 48, 2231.
    [70] H. Kim, Y. Miura, C. W. Macosko, Chemistry of Materials 2010, 22, 3441.
    [71] H. Kim, C. W. Macosko, Macromolecules 2008, 41, 3317.
    [72] W. Huang, X. Ouyang, L. J. Lee, ACS Nano, 6, 10178, 2012.
    [73] J. Z. Xu, C. Chen, Y. Wang, H. Tang, Z. M. Li, B. S. Hsiao, Macromolecules, 2011, 44, 2808.
    [74] J.R.Potts, O.Shankar, L. Du, and R.S. Ruoff, Macromolecules 2012, 45, 6045.
    [75] S. Wang, M. Tambraparni, J. Qiu, J. Tipton, D. Dean, Macromolecules, 2009, 42, 5251.
    [76]S. Ganguli, A. K. Roy, D. P. Anderson, Carbon 2008, 46, 806.
    [77]M. Martin-Gallego, R. Verdejo, M. A. Lopez-Manchado, M. Sangermano, Polymer 2011, 52, 4664.
    [78] S. Stankovich, D. A. Dikin, R. D. Piner, K. A. Kohlhaas, A. Kleinhammes, Y. Jia, Y. Wu, S. T. Nguyen, R. S. Ruoff, Carbon 2007, 45, 1558.
    [79] W. S. Hummers, R. E. Offeman, J. Am. Chem. Soc., 1958, 80, 1339.
    [80] H. C. Schniepp, J. L. Li, M. J. McAllister, H. Sai, M. Herrera-Alonso, D. H. Adamson, R. K. Prud'homme, R. Car, D. A. Saville, I. A. Aksay, The Journal of Physical Chemistry B 2006, 110, 8535.
    [81] Y. Yang, J. Wang, J. Zhang, J. Liu, X. Yang, H. Zhao, Langmuir 2009, 25, 11808
    [82] K. Jiang, C. Ye, P. Zhuang, X. Wang, and Y. Zhao, Macromolecules 2012, 45, 1346
    [83] F. Beckert, C. Friedrich, R. Thomann, R. Mulhaupt, Macromolecules 2012, 45, 7083.
    [84] M.Zhou, J. Xie, S. Yan, X. Jiang, T.Ye, and W. Wu, Macromolecules, 47,6055
    [85] H. Zheng, D. Zhang, W. Y. Wang, Y. Q. Fan, J. Li, H. P. Han, Microchimica Acta 2007, 157, 7.
    [86] J. i. Zhu, X. h. Zhang, H. Cheng, Y. o. Li, S. u. Cheng, R. i. Zhuo, Journal of Polymer Science Part A: Polymer Chemistry 2007, 45, 5354.
    [87] 謝宇軒, 國立台灣科技大學 碩士論文 2009.
    [88] 林建辰, 國立台灣科技大學 碩士論文 2010.
    [89] 劉家豪, 國立台灣科技大學 碩士論文 2011.
    [90] 陳彥廷, 國立台灣科技大學 碩士論文 2012.
    [91] 余雅婷, 國立台灣科技大學 碩士論文 2013.
    [92] 鍾宛倫, 國立台灣科技大學 碩士論文 2014.
    [93] Y. Zhao, S. Perrier, Macromolecules 2007, 40, 9116.
    [94] X. Jiang, W. Tian, C. Zhao, H. Zhang, M. Liu, Talanta 2007, 72, 119.
    [95] Y. Zhao, S. Perrier, Macromolecules 2006, 39, 8603.
    [96] R. Mueller, H. K. Kammler, K. Wegner, S. E. Pratsinis, Langmuir 2003, 19, 160.
    [97] D. Liu, H. J. Sue, Z. J. Thompson, F. S. Bates, M. A. Hillmyer, M. Dettloff, G. Jacob, N. Verghese, H. Pham, Polym. Mater. Sci. Eng. 2010, 103, 543.
    [98] A. Lazzeri, C. B. Bucknall, Journal of materials science 1993, 28, 6799.
    [99] M. S. e. Juang, I. M. Krieger, Journal of Polymer Science: Polymer Chemistry Edition 1976, 14, 2089.
    [100] 鍾孟儒, 國立台灣科技大學 碩士論文 2014.
    [101] 黃智偉, 國立台灣科技大學 碩士論文 2014.

    QR CODE