研究生: |
吳怡嫻 Yi-sian Wu |
---|---|
論文名稱: |
含銀奈米顆粒之可撓式單層奈米碳管透明導電薄膜之製備及性質研究 Preparation and Properties of the Silver Nanoparticles decorated Single-wall Carbon Nanotube Flexible Transparent Conductive Film |
指導教授: |
許應舉
Ying-Gev Hsu |
口試委員: |
王英靖
Ing-jing Wang 陳耿明 Keng-ming Chen 林河木 Ho-mu Lin |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2012 |
畢業學年度: | 100 |
語文別: | 中文 |
論文頁數: | 65 |
中文關鍵詞: | 單層奈米碳管 、螯合性高分子 、銀奈米顆粒 |
外文關鍵詞: | single wall carbon nanotubes, chelating polymer, silver nanoparticles |
相關次數: | 點閱:339 下載:13 |
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本研究將單層奈米碳管 (single wall carbon nanotube, SWNT) 表面羧酸官能基化改質為SWNT-(CH2)2COOH (簡稱C-SWNT) ,並將合成之螯合性高分子—PPG-g-FA 接枝於C-SWNT 形成SWNT-(CH2)2COPPG-g-FA (簡稱PF-SWNT),使其能均勻地分散於水中,將PET薄膜表面披覆聚4-乙烯基吡啶(poly(4-vinylpyridine), P4VP) 形成具吸附性之PET薄膜 (簡稱 P4VP/PET) ; 利用浸塗 (dip-coating) 方式使P4VP/PET薄膜吸附C-SWNT 或 PF-SWNT,形成奈米碳管網絡 (CNT-networks) 薄膜—C-SWNT/P4VP/PET 及 PF-SWNT/P4VP/PET。最後利用此奈米碳管薄膜表面之官能基作為配位基 (ligands) 來螯合 (chelating) 銀離子形成錯化合物 (complex) ,並利用光化學還原 (photoreduction) 法製備得含銀奈米顆粒之可撓性奈米碳管透明導電薄膜—C-SWNT-Ag/P4VP/PET 及 PF-SWNT-Ag/P4VP/PET。以SEM、EDS及ESCA、四點探針和UV-Vis光譜儀分別測定透明導電薄膜表面型態、元素分析、導電度及透光度。
The modified single-walled carbon nanotube (SWNT), SWNT-(CH2)2COOH (denoted as C-SWNT), was prepared by the reaction of SWNT with succinic acid acyl peroxide (SAAP). SWNT-CH2CH2COOH further grafted with the synthesized chelating polymer, PPG-g-FA to afford another modified SWNT—SWNT-(CH2)2COPPG-g-FA (denoted as PF-SWNT). The dispersedness and particle size of C-SWNT and PF-SWNT in water were investigated. The modified poly(ethylene terephathalate, PET) film which could form hydrogen bond with C-SWNT and PF-SWNT was prepared by spin-coating of poly(4-vinylpyridene) (P4VP) on the PET film (called P4VP/PET). P4VP/PET was dipped in C-SWNT and PF-SWNT suspensions, respectively, to form thin modified SWNT conductive films—C-SWNT/P4VP/PET and PF-SWNT/P4VP/PET. The two films were dipped in AgNO3 solution to let carboxyl groups of C-SWNT and PF-SWNT chelate with silver cations. The chelated silver cations on the films were then photoreduced into silver nanoparticles and decorated on the films—C-SWNT-Ag/P4VP/PET and PF-SWNT-Ag/P4VP/PET. The conductivity and the optical transmittance of the C-SWNT-Ag/P4VP/PET and PF-SWNT-Ag/P4VP/PET films were recorded by 4-point probe and UV-vis spectrometer. The morphology of and the existence of silver on the film were investigated by the scanning electron microscope (SEM) and the electron spectroscopy for chemical analysis (ESCA).
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