研究生: |
吳永祥 Yung-shiang Wu |
---|---|
論文名稱: |
多親水基Gemini型界面活性劑之改質及界面性質 Modification and Surface Activity of Multi-Hydrophilic Gemini Surfactants |
指導教授: |
陳耿明
Keng-ming Chen |
口試委員: |
王英靖
Ing-jing Wang 劉興鑑 Hsin-jiant Liu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2008 |
畢業學年度: | 96 |
語文別: | 中文 |
論文頁數: | 57 |
中文關鍵詞: | 多親水基界面活性劑 、Gemini 、表面張力 、乳化性 |
外文關鍵詞: | Multi-Hydrophilic, Gemini, Surface Tension, emulsification |
相關次數: | 點閱:355 下載:0 |
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本研究係以間苯二甲酸二甲酯磺酸鈉(Dimethyl 5- sulfoisophthalate sodium salt;SIPM)、聚乙二醇(Polyethylene glycol;PEG)及十八烯酸(Oleic acid)為原料合成一系列陰非離子之gemini型界面活性劑。
合成產物之構造使用FT-IR及1H-NMR等方法確認其分子結構。由測試結果顯示,此系列之界面活性劑具有良好的界面性質,包括降低表面張力、良好的濕潤性、耐酸鹼性、乳化能力及安定性、分散性。應用於直接染料染棉織物上,具有緩染及促染效果。
A series of anionic-nonionic surfactants have been synthesized by the reaction of SIPM、oleic acid and polythylene glycol which have variety of molecular weights.
1H-NMR and FT-IR have been used to confirm the structure of these compounds. These surfactants have been found to exhibit excellent surface active properties including reducing surface tension, increasing wetting power, foaming, emulsifiable ability and stability. The results of the influence on the direct dye-cotton dyeing system have been found that the presence of these surfactants in direct dyeing solution can retard or increases the rate of cotton.
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