在本論文以carbazole結構之電子傳輸材料4,4’,4”-Tris(carbazol- 9-yl)triphe-
nylamine ( TCTA )作為電子受體，以及以triazine結構之電洞傳輸材料2,4,6-tris(3-
(1H-pyrazol-1-yl)phenyl)-1,3,5-triazine( 3P-T2T )作為電子施體，以共蒸鍍的方式混和兩種材料，使得在介面上產生高效率的激發錯合體形成，並從PL光譜證明激發錯合體的產生。
接著在透過結構上的調變，分析結構對其效率之影響，並使載子達到平衡得到最佳的元件效率，而綜合了結構調變的實驗結果，最佳化元件在無摻雜材料下得到了10%外部量子效率，而摻雜入8%綠色磷光材料Ir(ppy)2(acac)則得到了29.6%的外部量子效率，以及在2000nits下T75得到了1400 min的高元件壽命。
最後本論文從薄膜與材料端進行分析，證明了膜層的不穩定性與材料存在載子陷阱將影響元件的壽命。

In this thesis, we use carbazole structure of 4,4’,4”-Tris(carbazol- 9-yl)triphe-
nylamine ( TCTA ) as electron acceptor and triazine structure of the hole transport material 2,4,6-tris(3-(1H-pyrazol-1-yl)phenyl)-1,3,5-triazine( 3P-T2T ) as electronic donor. The two materials were mixed in a co-vapor deposition way to produce highly efficient excitation complexes on the interface, and the exciplex generation was proved by PL spectrum.
We analyze the effect on the efficiency by changing the structure of the device to achieve the best efficiency with charge balance. The result of optimized device shows 10% and 29.6% external quantum efficiency with and without green phosphorescence material Ir(ppy)2(acac) and lifetime of ~1400 minutes with initial brightness of 2000 cd/m2.
In conclusion, the analysis of films and materials show that the instability of the film and the existence of carrier traps will lead to the life of the devices

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