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研究生: 陳煊
JASON - CHEN
論文名稱: 真空燒結對Ni60-WC性質與顯微結構之研究
Properties and Microstructures of Ni60-WC composites prepared by Vacuum Sintering
指導教授: 林舜天
Shun-Tian Lin
口試委員: 吳翼貽
Ye-Ee Wu
胡泉凌
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 機械工程系
Department of Mechanical Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 69
中文關鍵詞: 碳化鎢鎳合金燒結耐腐蝕耐磨耗
外文關鍵詞: Nickel alloy, Wear resistance
相關次數: 點閱:261下載:1
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鎳基合金和碳化鎢(WC)的複合材料已被廣泛應用於各種領域中,由於鎳合金的高耐腐蝕性和碳化鎢的高耐磨損性。真空燒結是有效製造硬質合金的方法,可以防止材料氧化和脫碳現象。在這項研究中,在不同的成分比例Ni60合金(Ni/Cr/B/Si)和WC組成的複合材料(30.0 - 39.4 vol% WC)以不同的燒結燒結溫度(1125℃、1150℃、1175℃、1200℃)進行。優化結果顯示,碳化鎢複合材料30.0 vol%WC在1175℃,硬度達 HV889 kgf / mm2和較低的腐蝕速率7.26 mg / cm2 / hr,測試用70 % 硫酸。根據XRD、SEM和EDS微觀結構的分析顯示,燒結溫度的升高至1200℃,產生W2C及 Ni2W4C造成 Ni60-WC複合材料硬度及耐腐蝕性的下降。


Composites based on nickel alloys and tungsten carbide (WC) have been widely used in various fields, due to high corrosion resistance of nickel alloys and the high wear resistance of tungsten carbide. Vacuum sintering process is an effective method for producing cemented carbides as the vacuum environment can prevent the materials from being oxidized and decarburized. In this study, composite materials composed of Ni60 (Ni/Cr/B/Si) and WC at various composition ratios (30.0 To 39.4 vol% WC) were sintered at different sintering temperatures (1125°C, 1150°C, 1175°C and 1200°C). Optimized results indicated that the composite with 30.0 vol% WC in the composite sintered at 1175 o C, a hardness as high as Hv 889 kgf / mm2 and a corrosion rate as low as 7.26 mg / cm2 / hr, tested using 70% sulfuric acid, can be achieved. The microstructural analysis based on XRD, SEM, and EDS indicated that Sintering temperature to 1200℃, will produce W2C and Ni2W4C, resulting in a decline Ni60-WC composite hardness and corrosion resistance.

摘要I ABSTRACTII 目錄IV 圖目錄VII 表目錄X 第一章緒論1 1.1前言1 1.2 研究目的與動機2 第二章基礎理論3 2.1 Ni60粉末3 2.2 WC-Ni與 WC-( Fe, Co)3 2.3 Ni60-WC 系統6 2.4 (Ni-Si)-WC系統7 2.5(Ni-B)-WC系統9 2.6 (Ni-Cr)-WC 系統與Ni-Cr2C310 2.7 (Ni-Cr-B-Si-Fe)-WC系統11 2.8 添加其它合金元素作為WC金屬黏結劑之目的12 2.9 添加其他元素所產生之化合物13 2.10 影響WC複合材料機械性質因素15 2.11 影響WC複合材料燒結因素17 第三章 實驗設備與研究方法21 3.1 實驗儀器21 3.2 實驗流程22 3.3 原始粉末23 3.4 真空燒結27 3.5 性質分析28 3.5.1 孔隙率檢測28 3.5.2 相對密度檢測29 3.5.3 金相觀察29 3.5.4 掃描式電子顯微鏡29 3.5.5 硬度試驗30 3.5.6 X-ray 繞射30 3.5.7 腐蝕試驗30 第四章 結果與討論32 4.1 孔隙率分析32 4.2 相對密度分析33 4.3 SEM表面分析34 4.4 硬度試驗分析39 4.5 XRD繞射分析41 4.6 微結構成分組成45 4.7 腐蝕試驗分析59 4.8各分析相互影響61 第五章 結論64 參考文獻65

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