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研究生： 張淳雅
Chun-Ya Chang
論文名稱： 探討富勒烯及非富勒烯電子傳輸層應用於鈣鈦礦光感測器之性能及穩定度
Study of Performance and Stability of Perovskite Photodetectors Based on Fullerene and Non-Fullerene Electron Transport Layer
指導教授： 張志宇
Chih-Yu Chang
口試委員: 張志宇
Chih-Yu Chang
葉旻鑫
Min-Hsin Yeh
林正裕
Jeng Yu-Lin
黃炳綜
Ping-Tsung Huang
林奇鋒
Chi-Feng Lin
學位類別： 碩士
Master
系所名稱： 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年： 2021
畢業學年度： 109
語文別： 中文
論文頁數： 102
中文關鍵詞： 鈣鈦礦光感測器 、電子傳輸層 、富勒烯 、非富勒烯
外文關鍵詞： perovskite photodetector, electron transport layer, fullerene, non-fullerene
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    • 摘要 I Abstract II 致謝 VII 圖目錄 VIII 表目錄 XV 第一章 緒論 1 1.1 前言 1 1.2 研究動機與目的 3 第二章 文獻回顧 4 2.1 光感測器發展歷史 4 2.1.1 橫向光感測器 (光電晶體管、光電導體) 5 2.1.2 縱向光感測器 (光電二極體) 5 2.2 光感測器之性能分析 6 2.2.1 暗電流 7 2.2.2 響應度 (responsivity, R) 8 2.2.3 探測度 (detectivity, D) 8 2.2.4 線性動態範圍 (linear dynamic range, LDR) 8 2.2.5等效噪聲功率 (noise equivalent power, NEP) 9 2.3 鈣鈦礦光感測器簡介 9 2.3.1 鈣鈦礦結構與光電特性 9 2.3.2 Cs0.15FA0.85PbI3結構鈣鈦礦 11 2.3.3 鈣鈦礦光感測器機制 15 2.3.4 鈣鈦礦光感測器發展 17 2.4 電子傳輸層 24 第三章 實驗步驟與分析 27 3.1 實驗設計 27 3.2 元件製備 28 3.2.1 材料準備 28 3.2.2 基板清洗流程 28 3.2.3 製備PDIN薄膜 28 3.2.4 光感測器元件製備 28 3.2.5 光感測器元件分析與量測 29 第四章 實驗結果與討論 30 4.1 鈣鈦礦主動層相關分析 30 4.1.1 XRD分析 30 4.1.2 UV及PL分析 31 4.1.3 AFM及 SEM分析 32 4.1.4 將Cs0.15FA0.85PbI3作為主動層應用於PVSK PDs 34 4.2 探討以PDIN作為ETL之可行性 37 4.2.1 PDIN熱穩定性分析 (TGA) 37 4.2.2不同濃度PDIN薄膜表面形貌分析 (SEM、AFM) 37 4.2.3 不同濃度PDIN之光電特性分析 (UV、PL) 39 4.2.4 不同濃度PDIN作為ETL之鈣鈦礦光感測器元件特性分析(無PEI層) 41 4.2.5 不同濃度PDIN作為ETL之鈣鈦礦光感測器元件穩定度分析 (無PEI層) 45 4.2.6 不同濃度PDIN作為ETL之鈣鈦礦光感測器元件特性分析(加入PEI層) 51 4.2.7 不同濃度PDIN作為ETL之鈣鈦礦光感測器元件穩定度分析 (加入PEI層) 55 4.3 比較PCBM與PDIN作為ETL之差異 60 4.3.1 PCBM與PDIN薄膜表面形貌分析 (SEM、AFM) 60 4.3.2 PCBM與PDIN光電特性分析 (UV、PL) 61 4.3.3 PCBM及PDIN作為ETL之鈣鈦礦光感測器元件特性分析 63 4.3.4 PCBM及PDIN作為ETL之鈣鈦礦光感測器元件穩定度分析 68 4.4 PEI層對PDIN鈣鈦礦光感測器元件穩定度影響 72 4.4.1 有無PEI層對元件穩定度的影響 72 4.4.2 PEI與PDIN間作用力分析 (FT-IR) 74 第五章 結論 75 參考文獻 76

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