建立奈米核/殼粒子的技術是一個倍受重視的研究領域，尤其在醫藥及生技上的潛力更是無限，而近幾年發展中，兩種形態材料的結合所製造而成之「複合型奈米核/殼材料」逐漸受到重視而嶄露頭角，複合型奈米核/殼材料之研究不單是一般奈米材料的結合技術，而更是實現單一顆奈米核/殼材料同時據有「多功能性」於一身之夢想的延伸，其本研究旨在建立一套有機染料與無機材料多功能複合型奈米核/殼材料之技術，並希望藉由此複合型奈米核/殼材料結合技術，能廣泛運用在各領域，研究係以溶膠–凝膠法使二氧化鈦水解縮合選擇性均勻披覆在有機染料表面，實驗利用透析法將Dye自組裝排列製備成奈米層級的染劑且穩定分散於水中，研究顯示Dye適合在酸和中性環境下反應，NH3環境下Dye無法自組裝形成有形狀之奈米粒子，如需添加使用界面活性劑則需要選用不帶電性的界面活性劑，Dye – TiO2成功利用NH3進行合成反應，即提升了TiO2光催化反應範圍，成功達成TiO2激發態波長延伸至可見光區域，研究中也嘗試將此技術衍生至金屬材料奈米金，在Dye–Au複合材料方面，CTAB雖然對奈米金有著強烈吸引，但CTAB卻無法使用在Dye溶液下，需要改用不帶電高分子mPEG-b-P(MEA-co-VIm)使奈米金在Dye表面均勻披覆，而形成Dye–Au核/殼複合材料，這技術是具有相當性的價值，是因為Dye和二氧化鈦以及奈米金，是完全相反條件下卻成功完成核/殼結構之複合材料。

In this study two kind of Core-shell nanoparticles were fabricated. The core materials is based on 5,10,15,20-tetrakis(pentafluorophenyl)-21H,23H-porphine (PF6). Dispersed PF6 nanoparticles were formed in water during dialysis through self-assembly of the PF6 molecules. Therefore, we are trying to coating titanim and gold particle on the suface. The resulting TiO2-modified and gold-modifed particles were characterized using several characteristic methods. In TiO2/PF6 core shell particle, a 10–20 nm thick TiO2 layer on the surface of the PF6 nanoparticles. In Au/PF6 core shell particle, the gold particle was from on the surrounding of PF6. The chemical composition of these core-shell structures was also confirmed. In addition, TiO2/PF6 core shell particle can be utilized as visible photocatalyst. The absorption spectrum of the PF6-TiO2 core-shell nanoparticle was extended to 300–500 nm, which greatly enhanced the photocatalytic efficiency in the visible light spectrum compared to that of bare TiO2.

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