研究生: |
林凡傑 FAN-JIE - LIN |
---|---|
論文名稱: |
新型四胺單體與聚苯并咪唑之合成及在高溫型質子交換膜燃料電池之應用 Synthesis and Characterization of Novel Tetraamine Monomers and Polybenzimidazoles for High Temperature Proton Exchange Membrane Fuel Cell Applications |
指導教授: |
陳志堅
Jyh-Chien Chen |
口試委員: |
劉貴生
Guey-Sheng Liou 蕭勝輝 Sheng-Huei Hsiao 游進陽 Chin-Yang Yu |
學位類別: |
碩士 Master |
系所名稱: |
工程學院 - 材料科學與工程系 Department of Materials Science and Engineering |
論文出版年: | 2017 |
畢業學年度: | 105 |
語文別: | 中文 |
論文頁數: | 94 |
中文關鍵詞: | 四胺 、聚苯并咪唑 、質子交換膜燃料電池 、質子傳導率 |
外文關鍵詞: | tetraamine, polybenzimidazole, proton exchange membrane fuel cell, proton conductivity |
相關次數: | 點閱:468 下載:1 |
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本研究利用三種不同的單體反應得到三種不同官能基之四胺單體以此三種四胺單體分別與二酸聚合出聚苯并咪唑P1~P3。但P3由於關環不完全,無法進行後續比較。P1及P2之固有黏度(inherent viscosity)分別為3.2及2.9 dL/g,且皆成功以溶液澆鑄法塗佈成可饒式的薄膜。P1及P2展現出良好的熱化學穩定性。P1 及 P2 薄膜在室溫下浸泡於不同濃度的磷酸(85、 80、 75 %)後展現出良好的PU。P1與P2在摻雜量最大下,拉伸強度分別為 24.4 和 17.0 MPa。P1及P2薄膜在160 ℃下進行全電池測試,比m-PBI 的 573 mW/cm2還高,證實聚苯并咪唑 P1 及 P2 薄膜可應用於質子交換膜燃料電池。
Three novel tetraamines were synthesized via several steps three different compound. Novel polybenzimidazoles P1~P3 were prepared
from OBA and monomer (5), (10) and (14), respectively. P3 could not be characterized because ofincompleted cyclization. The structures of P1 and P2 were characterized by 1H-NMRand FTIR. The inherent viscosity of P1 and P2, measured in methanesulfonic acid at35 ℃ and 0.2 g/dL, were 3.2 and 2.9 dL/g, respectively. P1 and P2 could be prepared as transparent, flexible, and tough membranes by solution casting. P1 and P2 show
outstanding thermal and oxidative stability. When P1 and P2 membranes were immersed in differentconcentrations of phosphoric acid (85, 80 and 75 %) at room temperature, P1 and P2 show good phosphoric acid uptake (PU, %), respectively. The tensile strength of P1 and P2 membranes
was 24.4 and 17.0 MPa when PU were achieve maxium, respectively. For single fuel cell test at 160 ℃, the peak power density of P1 and P2 are higher than thatof m-PBI at 291% PU (573 mW/cm2). It shows that P1 and P2 are promising proton exchange membranes for HT-PEMFC applications.
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