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研究生: 劉向陽
Xiang-Yang Liu
論文名稱: 利用化學氣相沉積法合成二維二硫化鋯薄膜
Synthesis of 2D Zirconium Disulfide Thin Films by Chemical Vapor Deposition
指導教授: 蔡孟霖
Meng-Lin Tsai
口試委員: 李權倍
Chuan-Pei Lee
蔡東昇
Dung-Sheng Tsai
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2022
畢業學年度: 110
語文別: 中文
論文頁數: 48
中文關鍵詞: 第四族過渡金屬二硫化物二硫化鋯化學氣相沉積二維材料
外文關鍵詞: group IV transition metal disulfides, zirconium disulfides, chemical vapor deposition, two-dimensional materials
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  • 二維過渡金屬二硫化物在近年來備受矚目,因其半導體的特性以及身為二維材料在厚度上可以達到原子級,被業界認為具有延續摩爾定律的潛力。作為第四族過渡金屬二硫化物,二硫化鋯的研究相對於二硫化鉬、二硫化鎢等仍然較為少見,但由理論計算上也預期其發展的潛力相當大。本研究嘗試利用化學氣相沉積的方法來生長二硫化鋯薄膜,並且藉由調節二硫化鋯材料的生長參數來觀測生長參數的改變對於其最後材料成長厚度、面積及品質等影響,並在此基礎之上意圖長出更薄的二硫化鋯材料。隨後藉由拉曼、光致發光光譜、原子力顯微鏡與掃描式電子顯微鏡來分析所成長材料之光學特性以及其厚度。


    Two-dimensional transition metal disulfides have attracted much attention in recent years. Due to their semiconductor properties and the thickness of twodimensional materials can reach atomic level, they are considered to have the potential to continue Moore’s law. As a group IV transition metal disulfides, the study of zirconium disulfide is still relatively rare compared with molybdenum disulfide and tungsten disulfide, but its potential is also been theoretically expected. In this study, we try to use chemical vapor deposition method to grow zirconium disulfide thin films. By adjusting the growth parameters, the influences on the thickness, area, and quality of the final material have been observed. Subsequently, the optical properties and thickness of the grown materials were analyzed by Raman, photoluminescence, atomic force microscopy, and scanning electron microscopy.

    目錄 摘要.....................................................................................................................................iv Abstract ................................................................................................................................v 目錄.....................................................................................................................................vi 第一章緒論..........................................................................................................................1 1.1 前 言..........................................................................................................................1 1.2 研究動機與目的.........................................................................................................3 第二章文獻探討...................................................................................................................3 2.1 二硫化鋯 ....................................................................................................................3 2.1.1 第四族過渡金屬二硫族化物.......................................................................................3 2.1.2 晶格結構 .....................................................................................................................5 2.1.3 電學性質 .....................................................................................................................6 2.1.4 拉曼光譜 .....................................................................................................................8 2.2 合成方式 ..................................................................................................................10 2.2.1 機械剝離法................................................................................................................10 2.2.2 離子嵌入剝離法........................................................................................................11 2.2.3 原子層沉積................................................................................................................12 2.2.4 化學氣相沉積............................................................................................................14 2.3 二硫化鋯氧化...........................................................................................................17 第三章實驗方法與設備.....................................................................................................19 3.1 製備過程 ..................................................................................................................19 3.1.1 實驗準備 ...................................................................................................................19 3.1.2 材料成長 ...................................................................................................................21 3.2 實驗設備與分析設備 ...............................................................................................23 3.2.1 實驗設備 ...................................................................................................................23 3.2.2 分析設備 ...................................................................................................................24 第四章實驗結果與討論.....................................................................................................28 4.1 二硫化鋯 ..................................................................................................................28 4.1.1 二硫化鋯調整生長參數對比.....................................................................................30 vii 4.1.2 更薄的材料參數最佳化.............................................................................................39 4.1.3 二硫化鋯材料於藍寶石基板上的生長方式..............................................................41 第五章結論與未來展望.....................................................................................................45

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