簡易檢索 / 詳目顯示
| 研究生： |
黃智偉 CHIH-WEI HUANG |
|---|---|
| 論文名稱： |
石墨烯奈米層板之合成及探討無機二氧化矽/有機高分子核殼型顆粒、矽烷接枝之蒙特納石黏土、及石墨烯奈米層板對不飽和聚酯、乙烯基酯、及環氧樹脂之體積收縮、機械性質及微觀型態結構之影響 Synthesis of functionalized exfoliated graphene nanoplatelets and effects of inorganic silica /organic polymer core-shell particle, silane-grafted montmorillonite, and functionalized exfoliated graphene nanoplatelet on the volume shrinkage, mechanical properties and cured sample morphology for unsaturated polyester, vinyl ester, and epoxy resins |
| 指導教授： |
黃延吉
Yan-Jyi Huang |
| 口試委員: |
陳崇賢
Chorng-Shyan Chern 邱文英 Wen-Yen Chiu |
| 學位類別： |
碩士 Master |
| 系所名稱： |
工程學院 - 化學工程系 Department of Chemical Engineering |
| 論文出版年： | 2014 |
| 畢業學年度： | 102 |
| 語文別： | 中文 |
| 論文頁數： | 289 |
| 中文關鍵詞： | 核殼型顆粒(CSP) 、蒙特納石黏土(MMT) 、熱還原氧化石墨烯(TRGO) 、不飽和聚酯樹脂(UP) 、乙烯基酯(VER) 、體積收縮 、微觀型態結構 、機械性質 |
| 外文關鍵詞： | Core-Shell Particle(CSP), Montmorillonite (MMT), Thermal reduction of graphene oxide, TRGO, unsaturated polyester(UP), vinyl ester resin (VER), volume shrinkage;morphology, mechanical properties |
| 相關次數： | 點閱：412 下載：1 |
| 分享至: |
| 查詢本校圖書館目錄 查詢臺灣博碩士論文知識加值系統 勘誤回報 |
藉由silane偶極劑來接枝二氧化矽或有機改質蒙特納黏土，以增加其添加劑與苯乙烯/不飽和聚酯(或乙烯基酯)之相容性，並利用傅立葉紅外線光譜儀量測silane接枝二氧化矽與silane改質蒙特納黏土之表面特性。
吾人亦利用廣角度X光散射儀(Wide-angle X-ray scattering,WAXS)，測定不同氧化反應時間處理後，其石墨粉、氧化石墨烯、熱還原氧化石墨烯三者之整體層間距離變化。
本研究的目的主要為探討三種特用添加劑，分別為:(1)奈米級核殼型顆粒(core-shell Particle，CSP) (2)有機改質蒙特納黏土(Montmorillonite caly，MMT) 及(3)熱還原氧化石墨烯(Thermal reduction of graphene oxide，TRGO)，其對苯乙烯/不飽和聚酯(或乙烯基酯)/特殊添加劑之三成份系統之反應前相容性、微觀型態結構、抗體積收縮特性及機械性質等之影響研究。
The synthesis of silane-grafted silica nanoparticles size (d = 15 nm) and montmorillonite clay (MMT) with the subsequent characterization of the grafting efficiency, grafting density, as well as the surface silanol groups conversion have been carried out. The silane coupling agents used for the treatment are γ-methacryloxy propyl trimethoxy silane (MPS). The number of silane coupling agents grafted on the MMT or silica surface and their silanol groups conversion were characterized by Fourier Transform Infrared Spectroscopy (FTIR).
The synthesis of graphite oxide(GO) and thermal reduction of graphene oxide(TRGO) with different reaction time have been carried out. The interplanar spacing of graphite oxide(GO) and thermal reduction of graphene oxide(TRGO) with different reaction time was measurement by Wide-angle X-ray scattering.
The effects of three additives, including (1) nano-scale core-shell particle additive, (2) organo- montmorillonite clay, (3) Thermal reduction of graphene oxide, on the cured sample morphology, volume shrinkage characteristics and mechanical properties of the Styrene(St)/Unsaturated polyester (or Vinyl ester resin)/additives ternary systems after the cure have been investigated.
1.R.B. Burn, Polyester Molding Compounds,Marcel Dekker, Inc, New York,
1982.
2.R.E. Young, in “Unsaturated Polyester Technology,“ ed. P.F. Bruins, Gordon
and Breach Science Publishers, 1976.
3.M.E. Kelly, in “Unsaturated Polyester Technology,“ ed. P.F. Bruins, Gordon and
Breach Science Publishers, 1976, P370.
4.F. Fekete, “Unsaturated Polyester Technology,“ ed. P.F. Bruins, Gordon and
Breach Science Publishers, 1976, P28.
5.E. Martuscelli, P. Musto, G.. Ragosta, G. Scarinzi, and E. Bertotti, J.Polym.Sci., Part B：Polym.Phys., 1993. 31, 619.
6.S.B. Pandit and V.M. Nadkarni, Ind. Eng. Chem Res., 1994. 33, 2778.
7.The B.F. Goodrich Co. WO93/21274 Oct. 28,1993.
8.Crc for Polymers Pty. Ltd., WO97/43339 Nov. 20,1997.
9.吳嘉鴻, 碩士論文,台灣科技大學, 2003.
10.黃俊翰, 碩士論文,台灣科技大學, 2009.
10.(a) 戴孟祥, 碩士論文, 台灣科技大學, 2010.
11.陳曉蘭, 碩士論文,台灣科技大學, 2010.
12.許毓倫, 碩士論文,台灣科技大學, 2011.
13.E.J. Bartkus and C.H Kroekel, Appl.Polym.Symp., 1970. 15, 113.
14.K.E.Atkins, in”Sheet Molding Compound :Science and Technology”Ed., H.G.
Kia, Hanser Publishers, 1993. Ch4.
15.V.A. Pattison, R.R. Hindersinn, and W.T. Schwartz,J. , Appl.Polym.Sci., 1974.
18, 2763.
16.V.A. Pattison, R.R. Hindersinn, and W.T. Schwartz,J. , Appl.Polym.Sci., 1975.
19, 3045.
17.L. Suspene, D. Fourquier, and Y. S. Yang, Polymer, 1991. 32, 1593.
18.Y. J. Huang and C. M. Liang, Polymer, 1996. 37, 401.
19.L. J. Lee, W. Li , and K.H. Hsu, Polymer, 2000. 41, 711.
20.C.B. Bucknall, I.K. Partridge, and M.J. Phillips, Polymer, 1991. 32, 636.
21.Y. J. Huang, T. S. Chen, J. G. Huang, and F. H. Lee, J. Appl. Polym. Sci., 2003. 89, 3336.
22.J.P. Dong , J.H. Lee , D.H. Lai, and Y. J. Huang, Appl. Polym.Sci., 2005. 98,
264.
23.C.P. Hsu, M. Kinkelaar, P. Hu, and L.J. Lee., Polym.Eng.Sci., 1991. 31, 1450.
24.Y.J. Huang, C.J. Chu, and J.P. Dong, J. Appl. Polym. Sci., 2000. 78, 543.
25.Y.J. Huang and C.C. Su, J. Appl. Polym. Sci., 1995. 55, 323.
26.J.P. Dong, J.G. Huang, F.H. Lee, J.W. Roan and Y.J. Huang, J.Appl.Polym.Sci.,
2004. 91, 3388.
27.Y.J. Huang and W.C. Jiang, Polymer, 1998. 39, 6631.
28. B. M. Novak, Adv. Mater., 1993. 5, 422.
29.X. Kornmann, L. A. Berghund, J. Sterte, and E. P. Giannelis, Polym. Eng. Sci., 1998. 38, 1351.
30.Y. Kojima, A. Usuki, M. Kawasumi, A. Okada, T. Kurauchi, and Kamigaito,
J.Polym.Sci. Part A: Polym.Chem, 1993. 31, 983.
31.E. P. Giannelis, Adv. Mater., 1996. 8, 29.
32.A. Usuki, Y. Kojima, M. Kawasumi, A. Okada, A. Fujushima, T. Kurauchi, and
O. Kamigaito, J. Mater. Res., 1993. 8, 1179.
33.P. B. Messersmith and E. P. Giannelis, Chem. Mater., 1994. 6, 1719.
34.W. Gilman and T. Kashiwagi, SAMPE Journal, 1997. 33, 42.
35.H. Kim, A.A. Abdada, and C.W. Macosko, Macromolecules,2010, 43, 6515
36.盧天智, 碩士論文,台灣科技大學, 1991.
37.H.R. Allcock and F.W. Lampe, ”Contemporary Polymer Chemistry”, 2nd Ed.,
Prentice Hall, Englewood Cliffs, 1990, 50.
38.Y.S. Yang and L.J. Lee, Polymer, 1988. 29, 1793.
39. K. Horie, I. Mita, and H. Kambe, J.Polym.Sci.PartA-1:Polym. Chem., 1969. 7,
2561.
40.江文慶, 碩士論文,台灣科技大學, 1996.
41.Y.J. Huang and C.C. Su, J. Appl. Polym. Sci., 1995. 55, 305.
42.Y.J. Huang and J.C. Horng, Polymer, 1998. 39, 3683.
43.Y.J. Huang and L.D. Chen, Polymer, 1998. 39, 7049.
44.蘇進成, 碩士論文,台灣科技大學, 1992.
45.林立翔, 碩士論文,台灣科技大學, 1992.
46.Y.J. Huang and C.C. Su, Polymer, 1994. 35, 2397.
47.Y.J. Huang, T.J. Lu, and W. Hwu, Polym. Eng. Sci., 1993. 33, 1.
48.C.B. Bucknall, I.K. Partridge, and M.J. Phillips, Polymer, 1991. 32, 786.
49.T. Mitani, H. Shiraishi, K. Honda, and G.E. Owen, 44th Annual Conference
Composite Institute,SPI,Session 12-F, 1989.
50.W.D. Cook and O. Delatycki, J.Polym.Sci.,Polym.Phys.Ed., 1974. 12, 2111.
51.W.D. Cook and O. Delatycki, J.Polym.Sci.,Polym.Phys.Ed., 1974. 12, 1925.
52.Y.J. Huang, S.C. Lee, and J.P. Dong, J. Appl. Polym. Sci., 2000. 78, 558.
53.Y.J. Huang, T.S. Chen, J.G. Huang, and F.H. Lee, J.Appl.Polym.Sci., 2003. 89,
3347.
54.D.S. Kim, K. Cho, J.H. An, and C.E. Park, J. Mater. Sci., 1994. 29, 1854.
55.J.S. Ullett and R.P. Chartoff, Polym. Eng. Sci., 1995. 35, 1086.
56.M. Abbate, E. Martuscelli, P. Musto, G. Ragosta, and G. Scarinzi, J.Appl.
Polym. Sci., 1995. 58, 1825.
57.M.L.L. Maspochand and A.B. Matinez, Polym.Eng. Sci., 1998. 38, 290.
58.N. A. Miller and C. D. Stirling, Polym. Comps., 2001. 9, 31.
59.K. F. Lin and Y.D. Shieh, J. Appl. Polym. Sci., 1998. 69, 2069.
60.K.F. Lin and Y.D. Shieh, J. Appl. Polym. Sci., 1998. 70, 2313.
61.P. Hazot, C. Pichot, and A. Maazouz,, Macromol Chem. Phys., 2000. 201, 632.
62.B.J.P. Jansen, S. Rastogi, H.E.H. Meijer, and P.J.Lemstra, Macromolecules,
2001. 34, 3998.
63.H.J. Sue, E.I. Garciameitin, and D.M. Picklman, in Polymer Toughening, Ch. 5,
ed., C.B. Arends, Marcel Dekker, 1996.
64.The Dow Chemical Company US Patent 4,778,851 Oct. 18 1998.
65.J.Y. Qian, R.A.Pearson, V.L. Dimonie, and M.S. El-Aasser, J. Appl. Polym.
Sci., 1995. 58, 439.
66.D. J. Suh, Y. T. Lim, and O. O. Park, Polymer, 2000. 41, 8557.
67.R. K. Bharadwaj, A. R. Mehrabi, C. Hamilton, C. Trujillo, M. Murga, R. Fun,
A. Chavira, and A. K. Thompsor, Polymer, 2002. 43, 3669.
68. The Dow Chemical Company US Patent 6,287,922 Sep.11, 2001.
69.A. Al-khanabashi, M. El-Gamal, and A. Moet, J. Appl. Polym. Sci., 2005. 98,
767.
70.梁繼文, 礦物學(下), 1984.
71.T. Lan and T.J Dinnavaia, Chem. Mater, 1994. 6, 2216.
72.H. Kim, Y. Miura, and C.W. Macosko, Chem. Mater., 22, 3441 (2010).
73.H. Kim and C.W. Macosko, Macromolecules, 41, 3317 (2008).
74.W. Huang, X. Ouyang, and L.J. Lee, ACS Nano, 6, 10178 (2012).
75.J.Z. Xu, C. Chen, Y. Wang, H. Tang, Z.M. Li, and B.S. Hsiao, Macromolecules,
44, 2808 (2011).
76.J.R. Potts, O. Shankar, L. Du, and R.S. Ruoff, Macromolecules, 45, 6045
(2012).
77.S. Wang, M. Tambraparni, J. Qiu, J. Tipton, and . Dean, Macromolecules, 42,
5251 (2009).
78. S. Ganguli, A.K. Roy, D.P. Anderson, Carbon, 46, 806 (2008).
79.M. Martin-Gallego, R. Verdejo, M.A. Lopez-Manchado, and M. Sangermanno,
Polymer, 52, 4664 (2011).
80.S. Stankovich, D.A. Dikin, R.D. Piner, K.A. Kohlhaas, A. Kleinhammes, Y. Jia,
Y. Wu, S.T. Nguyen, and R.S. Ruoff, Carbon, 45, 1558 (2007).
81.W.S. Hummers, and R.E. Offeman, J. Am. Chem. Soc., 80, 1339 (1958).
82.H.C. Schniepp, J.L. Li, M.J. McAllister, H. Sai, M. Herrere-Alonso, D.H.
Adamson, R.K. Prud’homme, R. Car, R.A. Savile, and I.A. Aksay, J. Phys.
Chem. B, 110, 8535 (2006).
83.Y. Yang, J. Wang, J. Zhang, J. Liu, X. Yang, and H,. Zhao, Langmuir, 25, 11808 (2009).
84.F. Beckert, C. Friedrich, R. Thomann, and R. Mulhaupt, Macromolecules, 45,
7083 (2012).
85.Patrick W. K. Lam, Polym. Eng. Sci., 1989, 29(10),690-698
86.邱淑微,碩士論文,台灣科技大學,2011.
87.Yuliana Tassia, MS Thesis, National Taiwan University of Science and
Technology, 2013.
88. 林悅蘋,碩士論文,台灣科技大學,2014
89. 鍾孟儒,碩士論文,台灣科技大學,2014.
90. 劉伊姍,碩士論文,台灣科技大學,2011.
91. S.Y. Pusatcioglu, A.L.Fricke., and J.C. Hasseler, J. Appl. Polym. Sci., 24, 937(1979).
92. C. D. Han, and K. W. Lem, J. Appl. Polym. Sci., 28, 749(1983).
93. J. F. Stevenson, Polym. Eng. Sci., 26(11), 746 (1989).
94. J. F. Stevenson, SPE. ANTEC. Papers, 26, 452(1980).
95. L. J. Lee, Polym. Eng. Sci., 21, 483 (1981).
96. Y. J. Huang, and L. J. Lee, AIChE. J., 31, 1585(1985).
97. C. D. Han, and D. S. Lee, J. Appl. Polym. Sci., 37, 2859(1987).
98.C. S. Chern, and D. C. Sundberg, ACS. Polym. PREP, 26(1), 296(1985).
99.G. L. Batch, and C. W. Mocosko, SPE. ANTEC Paper, 974(1987).
100.Y. J. Huang, J. D. Fan, and L. J. Lee, Polym. Eng. Sci., 30（11）, 684(1990)
101.Patrick W. K. Lam, Polym. Eng. Sci., 1989. 29(10), 690-698.
102.K.Horie, I Mita, and H.Kambe, J. Polym. Sci. : Part A1: Polymer Physics,1970, 2839.
103.江昆達, 碩士論文, 台灣科技大學, 2008.
104.S. L. Rosen, Fundamental Principles of Polymeric Materials, 2ed, Wiley, New York, 1993, 321-337.
105.J. Als-Nielsen and D. McMorrow, Elements of Modern X-ray Physics,2nd Ed., Wiley, New York, 2011.
106.B.D Cullity, Elements of X-ray Diffraction. 2nd Ed, Addison-wesley, Reading,
MA, 1978.
107.L.H. Sperling, “Introduction to Physical Polymer Science”, 4th Ed.,Wiley ,
New York, 2006, P.91-101.
108.D.C. Harris, Quantitative Chemical Analysis, 8th Ed., W.H. Freeman and
Company, New York, 2010, Chap. 9.
109.J.W. Robinson, E.M.S. Frame, and G.M. Frame II, Undergraduate Instrumental Analysis, 6th Ed., Marcel Dekker, New York, 2005, p. 227-279.
110.M. Takayanagi, K. Emada, and T. Kajiyama, J. Polym. Sci. Part C, 1966. 15,263.
111.BY William S. Hummers, Jr., and Richard E. Offeman, Preparation Of
Graphitic Oxide, 1958
112.Hannes C. Schniepp, Je-Luen Li, Michasel J. McAllister, Hiroaki Sai, Margarita Herrera-Alonso, Douglas H. Adamson, Robert K. , Roberto Car , Dudley A.Saville, and Ilhan A. Aksay , Journal Of Physical Chemistry B, 2006, 8535-8539.
