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研究生: 蘇煜哲
Yu-Zhe SU
論文名稱: 廢棄咖啡渣製備活性碳及其應用之研究
Activated Carbon Is Prepared From Waste Coffee Grounds and Its Application
指導教授: 蘇舜恭
Shuenn-kung Su
口試委員: 邱士軒
Shih-Hsuan Chiu
黃國賢
Kuo-Shien Huang
學位類別: 碩士
Master
系所名稱: 工程學院 - 材料科學與工程系
Department of Materials Science and Engineering
論文出版年: 2016
畢業學年度: 104
語文別: 中文
論文頁數: 92
中文關鍵詞: 咖啡渣活性碳氫氧化鉀脫色比表面積
外文關鍵詞: coffee grounds, activated carbon, potassium hydroxide, bleaching, specific surface area
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  • 本文利用廢棄咖啡渣在不同溫度下先進行焦化,然後使用不同濃度之氫氧化鉀(KOH)使其活化,再以800oC燒結,製得一系列活性碳。分別經由相關儀器檢測,一方面探討活性碳應用於染料廢水脫色處理之可行性;另方面檢測活性碳分別與染料之間相互作用。由檢測結果可發現活性碳焦化溫度越高及活化時KOH濃度越高,比表面積越大,染料脫色效果越佳,其中以活性碳7003之比表面積為最大且脫色效果為最佳,最高脫色率可達到98%。對於不同染料脫色率之比較,可以發現其脫色效果之順序為酸性染料>反應染料>直接染料。其次活性碳與染料相互作用後,其粒徑以7003吸附時為最大值可達3199nm,而提升吸附溫度對其脫色效果反而越差。透過能量分散式光譜儀(EDS)可以得知,吸附染液後之活性碳具有染料的S元素,造成粒徑變大,而非活性碳自身發生反應而產生團聚造成變大。


    In this paper, the waste coffee grounds was first coked at different temperatures, then it was activated at different concentrations of potassium hydroxide (KOH) , and heated up to 800℃ for sintering to obtain a series of activated carbon. They were measured with relevant instruments, respectively. It was discussed that the feasibility of activated carbon was applied to remove dyeing wastewater. In addition, the interaction between the dye and the activated carbon was also studied. The results show that the higher coking temperature or the higher KOH concentration, the greater the surface area and the better the decolorization effect are. The activated carbon 7003 possesses the largest specific surface area and the best decolorization effect. Its decolorization rate is up to 98%. To compare decolorization rate in various dyes, it can be found in the order as follows: acid dyes> reactive dyes> direct dyes. When the particle size is up to 7003, it has the maximum adsorption at 3199nm. When the adsorption temperature is increased, the decolorization becomes worse. From the analysis of energy dispersive spectrometer (EDS), the activated carbon sample include S element after adsorption of dye. This result leads to form larger particle size. It is an evidence that the larger particle size is not caused by the aggregation of the activated carbon itself.

    摘 要............................I Abstract ..........................II 目錄 ............................III 圖目 錄...........................VII 表目 錄...........................X 第一章 緒 論 1.1 前言...........................1 1.2 研究目的.........................3 第二 章文獻探討 2.1 咖啡...........................4 2.2 咖啡渣..........................9 2.3 廢水處理方法.......................10 2.3.1 概述..........................10 2.3.2 印染廢水的種類.....................11 2.3.3 印染廢水的特點.....................13 2.3.4 印染廢水常用之處理方法.................15 2.4 活性碳..........................21 2.4.1 活性碳來源.......................21 2.4.2 活性碳分類.......................22 2.4.3 活性碳製備原理.....................24 2.4.3.1 碳化.........................24 2.4.3.2 活化.........................25 2.4.3.2.1 物理法.......................25 2.4.3.2.2 化學法.......................25 2.5 活性碳特性........................26 2.5.1 比表面積........................26 2.5.2 孔隙大小........................27 2.6 活性碳應用........................27 2.7 吸附理論.........................27 2.7.1 汙染物吸附理論.....................28 2.7.2 吸附類型........................29 2.7.3 吸附曲線........................30 2.7.3.1 等溫吸附曲線.....................30 2.7.3.2 吸附滯化迴線.....................32 2.7.4 吸附動力模式......................35 2.7.4.1 吸附速率常數.....................35 2.7.4.2 薄膜阻力.......................35 2.7.4.3 孔隙擴散係數.....................36 2.7.5 等溫平衡吸附模式....................37 2.7.5.1 Freundlich等溫吸附方程式................37 2.7.5.2 Langmuir等溫吸附方程式................38 2.7.6 BET等溫吸附方程式...................41 2.8影響活性碳吸附之因素...................43 第三章 實驗設備與研究方法 3.1 實驗...........................45 3.1.1 實驗藥品........................45 3.1.2 染料..........................45 3.1.3 實驗儀器........................46 3.1.4 分析及檢測儀器.....................46 3.2 實驗步驟.........................47 3.2.1 活性碳之製備......................47 3.2.1.1 咖啡渣焦化......................47 3.2.1.2 咖啡渣活化......................47 3.2.1.3 咖啡渣碳化......................47 3.2.1.4 調整酸鹼值......................47 3.2.2 活性碳之檢測與分析...................47 3.2.3 活性碳之應用......................48 3.3 代號列表.........................50 第四章 結果與討論 4.1 B.E.T表面積與孔隙分析...................51 4.2 不同比例比表面積活性碳之SEM...............55 4.3 各種活性碳及其與酸性染料相互作用之元素分析........57 4.4 各種活性碳與酸性染料相互作用之脫色率...........59 4.5 以活性碳7003在不同重量下對不同染料相互作用之脫色率....68 4.6 以活性碳7003對不同染料在不同溫度下之脫色率........70 4.7 各種活性碳與酸性染料相互作用之粒徑............74 第五章 結論.........................75 第六章 參考文獻.......................77

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