無機聚合物是利用鹼溶液將富含Si與Al離子之礦物，經由溶解與聚合反應而形成類似天然沸石之新穎環保材料，此材料研發主要目的在取代高污染之水泥材料，減少耗能與CO2之排放。本研究為相關性研究法，利用樣品中最佳成分與分子莫耳數比例，獲得最佳化之配比設計公式與品質控管三相圖。本研究結果利用樣品中取得主要元素SiO2、Al2O、與M2O 之最佳配比當量 (比例為 0.31:0.33:0.35) S-A-M三相圖，作為品質控管之第一指標。最佳配比公式是將量化後之分子莫耳數帶入結構平衡與離子電價平衡得出。依反應之效益，按比率或權重，求得 SiO2/Al2O, Al2O/M2O, L/S (0.9, 0.93, 0.5) 特性三相圖作為品質控管第二指標。利用SEM/EDS可判讀微結構之型式或殘存之陽離子數。RRS325與RRS875光譜儀皆無法有效激發反應中新生官能基，但在反應後30分鐘出現一組T-O-T之非對稱伸縮振動光譜。由過去文獻資料比對本研究之結果是相當吻合，顯示本研究論點與配比設計公式可供日後運用在最佳配比設計使用。

Inorganic polymer is a natural zeolite-like modern environmental friendly materials synthesized from Si and Al ions dissolved in alkaline solution through hydrolysis and polymerization processes. It is aimed to substitute traditional cement materials, reduce resources consumption, and CO2 emission which are relatively contaminated to environment. This study used the correlational approach to examine the constituents and molecular mole ratio of the samples. Allocated proportion design formulas and a three-phase diagram for quality control are well established.This study suggests that the allocated equivalent of a S-A-M three-phase diagram of SiO2, Al2O, and M2O (ratio 0.31:0.33:0.35) can be served as the first step of quality control. The best allocated formulas were derived by calculating molecular moles, structure balance, and ionic equivalent. A characteristics three-phase diagram (SiO2/Al2O, Al2O/M2O, L/S (0.9, 0.93, 0.5)) derived from reaction efficiency, ratio, and weighting can be implemented as the second step of quality control. The microstructure or residual cations can be interpreted using SEM/EDS instrument. Both RRS325 and RRS875 spectroscopes are unable to excite new radical efficiently but a T-O-T asymmetric stretching vibration was detected for another 30 minutes of reaction. The results of this research agree with former literatures data. The theory and allocated proportion design formulas derived in this research may be implemented in the further optimal allocated proportion designs.

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