中文摘要
富鎳層狀正極材料因具備約 220 mAh/g 的高比電容而備受期待。然而它
的商業化受到一些限制的阻礙，包括熱穩定性低、容量保持率低、電極與電解
質發副反應以及首次循環容量損失。為了增加富鎳層狀陰極材料的真實電位，
最簡單的方法之一是增加陽極和陰極電極之間的電位差。隨著鎳含量的提升，
晶間微裂紋的產生越發嚴重，最終使得性能衰退。
因此，本研究使用單晶 Li(Ni0.83Mn0.06Co0.11)O2 來克服和降低在高電壓
（4.5V）循環時晶間微裂紋的發生。 同時，LiNbO3 的濕法 ALD 塗層將克服其
他問題，如首次容量損失、副反應、熱穩定性和低容量保持率。它作為單晶
Li(Ni0.83Mn0.06Co0.11)O2 表面的納米導電塗層。 本研究著重於兩種不同的煅燒溫
度來形成塗層。 結果表明，較高的煅燒溫度會導致較高的結晶塗層
（ SCNMC@0.7LNO-700 ） ， 較 低 的 煅 燒 溫 度 會 導 致 非 晶 塗 層
（SCNMC@0.7LNO-500）。 兩者都可以在高電壓（4.5V）下實現更好的容量
保持，而較高結晶度的 LiNbO3提供了更好的熱穩定性，並使得高溫下容量保持
率也有所提升。通過濕式 ALD 塗層技術塗覆的導電塗層適用於富鎳層狀正極，
可用作為開發新一代商業 LIB 正極材料的解決方案。

ABSTRACT
Due to their high specific capacitance of roughly ~220 mAh/g, nickel-rich
layered cathode materials are eagerly anticipated. Its commercialization has been
hampered by a few limitations, including low thermal stability, low capacity retention,
a tendency for side reactions with electrolytes, and first cycle capacity loss. In order to
increase the true potential of the nickel rich layered cathode material, one of the
simplest ways is to increase the potential difference between anode and cathode
electrode. However, the higher the nickel content, the more severe the inter-granular
micro crack occurs, and the worse the performance.
Therefore, Single Crystalline Li(Ni0.83Mn0.06Co0.11)O2 is used in this study to
overcome and reduce the potential of the inter—granular microcrack upon cycling at
high voltage (4.5V). Furthermore, other problems such as first capacity loss, side
reaction, thermal stability and low capacity retention will be overcome by wet-ALD
coating of LiNbO3. It acts as a nano-conductive coating layer on the surface of the
Single Crystalline Li(Ni0.83Mn0.06Co0.11)O2. This study focuses on the two different
calcination temperature to form the coating layer. It results that higher calcinations
temperature will lead to higher crystalline coating layer (SCNMC@ 0.7LNO-700) and
lower calcinations temperature leads to amorphous coating layer (SCNMC@
0.7LNO-500). Both can achieve better capacity retention at high voltage (4.5V). The
higher crystalline LiNbO3 offers better thermal stability of cathode in which the
capacity retention is enhanced at elevated temperature. This conductive coating that
coated by wet-ALD coating method is suitable for Nickel rich layered cathode and
can be used as the solution to develop better cathode material in commercial LIBs.

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