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研究生: 顏宛珍
Wan-Jhen Yan
論文名稱: 以人工溼地處理校園化糞池出流水之研究
Treatment of Septic Tank Effluent by Constructed Wetland
指導教授: 劉志成
Jhy-chern Liu
口試委員: 顧洋
Young Ku
張子超
Tzu-chau Chang
張維欽
none
學位類別: 碩士
Master
系所名稱: 工程學院 - 化學工程系
Department of Chemical Engineering
論文出版年: 2006
畢業學年度: 94
語文別: 中文
論文頁數: 150
中文關鍵詞: 人工溼地化糞池出流水風險評估
外文關鍵詞: Constructed wetland, septic tank
相關次數: 點閱:199下載:4
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  • 以人工溼地系統處理校園污水為一自然淨化程序,不需添加化學藥劑,且操作、維護簡單,應用於污染物單純之校園污水的處理;人工溼地系統除具備廢污水處理及再利用功能外,更具教育功能。
    本研究以台灣師範大學校園溼地為研究對象,探討污染物的去除效率。從2005年1月到2006年5月的偵測期間,各污染物的平均去除率:化學需氧量(72.2%)、生化需氧量(68.3%)、氨氮(93.8%)、懸浮固體(65.2%)、正磷酸鹽(88.5%)、大腸桿菌群和糞生大腸桿菌群(98.5%)。與文獻相比,有較高的去除效果,可能是由於水力負荷率較低,水力滯留時間較長,有充裕的時間去除污染物。
    實驗期間以流量大小可區分成兩階段,2005/1-2005/7的平均流量為0.35m3/d,2005/8之後將平均流量調整為2.99m3/d。當污水的平均流量提高時,去除率會有部分的下降。
    人工溼地的負荷率對污染物的去除量呈現高度正相關,提高污染物在溼地中的負荷率,雖然去除率稍降,但單位面積的去除量上升;從溫度對污染物的去除速率常數之影響,推測氨氮去除的主要機制為生物活動,磷主要經由介質吸附和化學沉澱而去除。化學需氧量及生物需氧量大部分組成可能是顆粒態,可經由過濾而去除。
    根據衞生檢驗級分系統,人工溼地放流水中的糞生大腸桿菌分佈較大的區間為10-99,此濃度範圍為中度風險;化糞池出流水經人工溼地處理之排放水水質,根據陸域地面水體分類,符合分類丁,適用於灌溉用水、二級工業用水(冷卻用水)及環境保育。


    As an environmentally friendly wastewater treatment process, constructed wetlands has advantage of easy to operate, low energy input, extra wildlife habitant, and groundwater replenishment.
    In this study, the constructed wetland in National Taiwan Normal University in treating septic tank effluent was monitored. The average removal efficiency during first two-year operation period are: COD (72.2%)、BOD5 (68.3%)、NH4+-N (93.8%)、S.S. (65.2%)、PO43--P (88.5%)、TC and FC (98.5%). Compared with literatures, mostly better removal efficiency may be because of lower loading and longer hydraulic retention time.
    The operation period could be divided into two phases with high and low flow rate. Higher pollutant loading led to higher removal per unit area and lower removal efficiency. The first-order removal rate constant of pollutants depended on temperature. However, removal rate constants of COD、BOD and phosphate were not significantly sensitive to temperature changes. It implied that the main removal mechanism of COD、BOD and phosphate in constructed wetland might be filtration and sediment, not biological activities.
    According to sanitary inspection risk score, fecal coliform in the effluent of constructed wetland was categorized as class C. Further treatment may be needed in case the effluent is for reuse.

    摘要…………….…………………………………………………….......I Abstract……………….……………………………………………….…II 致謝…………….…………………………………………………….....III 目錄…………….…………………………………………………..... ...IV 圖目錄………….……………………………………….…….............VIII 表目錄……………………………………………….………………...XII 第一章 緒 論 1 1.1研究缘起 1 1.2研究目的 2 第二章 理論基礎與文獻回顧 3 2.1溼地的定義與分類 3 2.2人工溼地 6 2.2.1發展背景與應用 6 2.2.2人工溼地的結構 6 2.2.3水生植物 8 2.3氮與磷的傳輸機制 10 2.3.1氮的傳輸機制 10 2.3.2磷的傳輸機制 13 2.4人工溼地去除污染物機制 15 2.4.1懸浮固體和有機物的去除 16 2.4.2氮的去除機制 16 2.4.3磷的去除機制 17 2.4.4致病源的去除機制 17 2.4.5人工溼地的去除率 18 2.5校園人工溼地 21 2.5.1校園人工溼地之特質與優點 21 2.5.2永續校園 21 2.4.3國內人工濕地處理案例 22 2.6風險評估概論 24 第三章 實驗設備與方法 26 3.1人工溼地之系統配置與操作 26 3.1.1污水來源及動線 26 3.1.2人工溼地植栽 31 3.2水質採樣與水質分析 34 3.3實驗藥品 35 3.4實驗設備與裝置 39 3.5實驗項目與步驟 40 3.5.1總懸浮固體濃度(TSS)分析 40 3.5.2總溶解有機碳(DOC)分析 40 3.5.3化學需氧量(COD)測定 41 3.5.4生化需氧量(BOD)測定 42 3.5.5氨氮分析 43 3.5.6凱氏氮(TKN)分析 44 3.5.7正磷酸鹽分析 44 3.5.8硝酸鹽氮分析 45 3.5.9總菌落數(TMC)測定 46 3.5.10大腸桿菌群(Total Coliform, TC)測定 47 3.5.11糞生大腸桿菌群(Fecal Coliform, FC)測定 48 3.6污染物處理效能之評估 49 第四章 實驗結果與討論 51 4.1現場監測 52 4.1.1 酸鹼度 52 4.1.2導電度 54 4.1.3水溫 54 4.1.4溶氧 57 4.2污染物的去除 59 4.2.1懸浮固體 59 4.2.2氨氮 61 4.2.3凱氏氮 63 4.2.4硝酸氮 65 4.2.5總氮 67 4.2.6正磷酸鹽 69 4.2.7化學需氧量 71 4.2.8生化需氧量 73 4.2.9溶解性有機碳 77 4.2.10病原菌 80 4.2.11污染物的去除率 85 4.3污染物負荷率 89 4.3.1懸浮固體 90 4.3.2氨氮 91 4.3.3總氮 92 4.3.4正磷酸鹽 94 4.3.5化學需氧量 95 4.3.6生化需氧量 96 4.3.7大腸桿菌群 97 4.3.8糞生大腸桿菌群 98 4.4污染物速率常數 99 4.4.1氨氮 99 4.4.2正磷酸鹽 101 4.4.3化學需氧量 104 4.4.4生化需氧量 106 4.4.5病原菌 108 4.5風險評估 111 4.5.1 WHO指標 111 4.5.2數據分析 113 4.5.3再利用的評估 115 4.6人工溼地管理 117 4.6.1植栽 117 4.6.2泥土 117 4.6.3有機體 118 第五章 結論與建議 119 參考文獻 122 符號說明 133 附錄A 134 A-1 SSF系統 134 A-2 FWS系統 137 A-3景觀一池 140 A-4景觀二池 142 作者簡介 144

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