由於人口迅速地增長，飲用水的需求增加，水資源的汙染成為社會關注的一項
重要議題。近年來，隨著藥物、工業以及醫療行業等的快速發展，抗生素用量
急速增加，使之成為造成水汙染的一項主要因素。而眾多抗生素之中，又因四
環黴素(Tetracycline, TCs)有著高親水性和低揮發性的特點，導致其容易持續存
在於水生環境中，造成嚴重的水污染問題，因此，處理水中四環黴素汙染物這
項議題引起了大家的高度重視。
本研究選用環保且低成本的光催化降解方法結合吸附方法，用於處理水中抗生
素。有機金屬框架是近期最受矚目的觸媒，因其特殊結構以及極大的比表面
積，它有著吸附能力極佳的特性。本研究選用水穩定性高的一種鋯基金屬有機
框架-MOF-808 作為觸媒材料，然而這項材料的缺點是光吸收的波長範圍有限，
在光催化中的應用稍受限制。有機金屬骨架由於其結構可調的特性，使得我們
能透過改質的方式改善其缺陷。本研究選用非金屬摻雜的方式對 MOF-808 進行
改質，並且選用了兩種摻雜物做比較，摻雜對胺基苯甲酸以及多巴胺黑色素膠
體球並尋找摻雜的最佳比例，使之成為可有效吸收可見光源的優良光觸媒，應
用於水中抗生素的降解。根據實驗結果以及儀器分析的鑑定，推斷出多巴胺黑
色素膠體球以及對胺基苯甲酸分別是用來提高可見光吸收能力以及增強吸附能
力。接著，我們以共摻雜的方式改質 MOF-808，將多巴胺黑色素膠體球以及對
胺基苯甲酸共同摻雜入 MOF-808 中，並尋找最佳比例，成功結合了兩項摻雜物
的優勢，並使光催化降解四環黴素之效率提升至 95 %。

Due to the rapid population growth, the demand for drinking water has increased, and water resource pollution has become a major societal concern. In recent years, with the rapid development of the pharmaceutical, industrial, and medical sectors, the use of antibiotics has surged, making them a primary factor in water pollution. Among numerous antibiotics, tetracycline (TCs) is particularly problematic due to its high hydrophilicity and low volatility, which allow it to persist in aquatic environments and cause severe water pollution. Consequently, addressing tetracycline contaminants in water has garnered significant attention.
This study explores the use of an environmentally friendly and low-cost photocatalytic degradation method combined with adsorption techniques to treat antibiotic contamination in water. Metal-organic frameworks (MOFs) have recently gained prominence as catalysts due to their unique structures and large surface areas, which confer excellent adsorption capabilities. In this research, MOF-808, a zirconium-based MOF with high water stability, was selected as the catalyst material. However, a limitation of MOF-808 is its restricted light absorption range, which somewhat limits its application in photocatalysis. Given the tunable nature of MOF structures, modifications can be made to overcome this limitation.
This study employed non-metal doping to modify MOF-808, comparing two dopants: p-aminobenzoic acid and dopamine melanin colloidal spheres, to determine the optimal doping ratio for effective visible light absorption. According to experimental results and instrumental analysis, dopamine melanin colloidal spheres and p-aminobenzoic acid were identified as enhancing visible light absorption and adsorption capacity,
respectively. Subsequently, a co-doping approach was used to modify MOF-808, incorporating both dopamine melanin colloidal spheres and p-aminobenzoic acid to find the optimal ratio. This approach successfully combined the advantages of both dopants, enhancing the photocatalytic degradation efficiency of tetracycline to 95%.

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